• Title/Summary/Keyword: metamifop

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Development of a Residue Analysis Method for Metamifop in Paddy Water, Soil, and Rice with HPLC (HPLC를 이용한 농업용수, 논토양, 및 현미 중 metamifop의 잔류분석법 개발)

  • Park, Hee-Woon;Moon, Joon-Kwan
    • The Korean Journal of Pesticide Science
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    • v.21 no.1
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    • pp.68-74
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    • 2017
  • An analytical method for detecting metamifop residue in paddy water, soil, and rice with high performance liquid chromatography (HPLC) was developed. Water was extracted with ethyl acetate before analyzing by HPLC. Soil residues were extracted with acetone under acidic condition and after purifying with $Extrelut^{(R)}$ NT, and silica SPE, the residue was analyzed by HPLC. For residue analysis in rice, the procedure involved extraction with acetone, purification with $Extrelut^{(R)}$ NT, partitioning between acetonitrile/hexane, purification with silica SPE cartridge, and analysis by HPLC. The limit of detection (LOD) was 1.0 ng, limit of quantitation (LOQ) was 3.0 ng, and method limit of quantitation (MLOQ) were 0.001 mg/L for paddy water, 0.01 mg/kg for rice and soil, respectively. Standard calibration curve shows linearity from 0.05 mg/kg to 5.0 mg/kg ($R^2=0.9999$). The recoveries in fortified paddy water were $91.3{\pm}3.5%$ (0.01 mg/L level) and $93.2{\pm}6.3%$ (0.05 mg/L level). The recoveries in fortified paddy soils were $92.5{\pm}4.0%$ (0.1 mg/kg level) and $92.7{\pm}4.0%$ (0.5 mg/kg level) in soil A, while, $102.3{\pm}4.4%$ (0.1 mg/kg level) and $98.9{\pm}7.9%$ (0.5 mg/kg level) in soil B, respectively. The recoveries in fortified rice were $93.0{\pm}6.9%$ (0.1 mg/kg level) and $85.0{\pm}3.5%$ (0.5 mg/kg level). This method was proved to be effective and can be used to determine the metamifop residue in paddy water, paddy soil, and rice.

Effective Weed Control in Direct Seeded Rice on Puddled Paddy Surface of Southern Region (남부지역 무논직파 재배 논에서 잡초 방제)

  • Park, Tae-Seon;Park, Hong-Kyu;Kang, Sin-Koo;Ku, Bon-Il;Choi, Min-Kyu;Lee, Keong-Bo;Ko, Jae-Kwon
    • Korean Journal of Weed Science
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    • v.32 no.1
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    • pp.57-69
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    • 2012
  • This study was conducted to find the effective management of main weeds including herbicide-resistant Echinochloa oryzicola, Scirpus juncoides and Monochoria vaginalis in direct seeded rice on puddled paddy surface. The dominant dominances in direct seeded rice on puddled paddy surface were increased for three years between 2009-2011. In weed distribution in 2011, the occurrence density of S. juncoides decreased greatly, but it of E. oryzicola increased especially as compared with it of 2009. Benzobicyclon, mesotrione and pyrimisulfan were effective to sulfonylurea(SU)-resistant S. juncoides and M. vaginalis at 5 and 12 days after seeding, however, the efficacy of bromobutide to sulfonylurea-resistant M. vaginalis was decreased slightly at 12 days after seeding. And carfentrazon and pyrazolate were ineffective to S. juncoides. In direct seeded rice on puddled paddy surface which ACCase and ALS inhibitor-resistant E. oryzicola was not occurred, benzobicyclon+penoxsulam+pyrazosulfuron-ethyl ET, bromobutide+imazosulfuron+metamifop GR, and flucetosulfuron+mesotrione+pretilachlor GR showed the control effect over 94% to main weeds included sulfonylurea-resistant S. juncoides and M. vaginalis. The E. oryzicola dominating in direct seeded rice on puddled paddy surface were not any affected to the survival by treatment with recommended doses of cyhalofop-butyl and penoxsulam tested. The ACCase and ALS inhibitor-resistant E. oryzicola was effectively controlled by mefenacet and fentrazamide up to the 2nd leaf stage. In direct seeded rice on puddled paddy surface domiating coincidentally by herbicide-resistant E. oryzicola, S. juncoides and M. vaginalis, "one-shot herbicide" included with mefenacet, fentrazamide, penoxsulam and metamifop could't be used because of low control effect or rice injury. The sequential treatment of benzobicyclon+thiobencarb SE and bensulfuron+mefenacet+thiobencarb GR controlled effectively the herbicide-resistant E. oryzicola, S. juncoides and M. vaginalis in direct seeded rice on puddled paddy surface. The days required by the 3rd leaf stage of herbicide-resistant E. oryzicola, S. juncoides and M. vaginalis in direct seeded rice on puddled paddy surface seeded in May 20 shortened by 4 days as compared with it of June 10.

Agronomic Characteristics and Herbicidal Response of Barnyard Millet Strains Under Paddy Rice (답리작 적응 조사료용 피의 생육특성 및 제초제 반응)

  • Park, Tae-Seon;Park, Hong-Kyu;Hong, Seong-Woo;Kim, Jeong-Gon;Chung, Nam-Jin;Cho, Hyun-Suk;Seong, Ki-Yeong;Yang, Woon-Ho;Seo, Myung-Chul;Kang, Hang-Won
    • Korean Journal of Weed Science
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    • v.32 no.3
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    • pp.256-262
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    • 2012
  • This experiment was conducted to determine the agronomic characteristics for selection of the excellent barnyard millet and the herbicidal response for their weediness prevention in paddy rice. IT170609, IT195422 and EV2012 have produced more dry matter compared to other barnyard millets tested. In varietal characteristics by heading date, IT170609 showed medium maturing type and IT195422 and EV201 had late maturing type. The germination rate of IT170609, IT195422 and EV2012 on temperature was higher than Echnochloa oryzicola of native species, and it was definitely distinctive at 20 and $25^{\circ}C$. In the herbicidal response for their weediness prevention in paddy rice, imazosulfuron+benzobicyclone+penoxsulam SC showed control effect the extend of over 90% to IT170609, IT195422 and EV2012. Cyhalofop-butyl EC, penoxsulam SC and metamifop EC were very effective by 6~7 leaf stage of barnyard millets tested.

The Occurrence of the Weeds on the Lawn and the Effective Control System (잔디밭잡초 발생현황과 방제기술)

  • Lee, In-Yong;Kim, Chang-Seok;Lee, Jeongran;Park, Nam-Il;Park, Jae-Eup
    • Weed & Turfgrass Science
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    • v.2 no.2
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    • pp.111-121
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    • 2013
  • Literatures were reviewed to understand the weeds occurring on the lawn and the effective control methods of them. Thirty-seven species of 16 families including three species of Cyperaceae for example Cyperus sanguinolentus, nine species of Poaceae including Digitalis ciliaris, Poa repens, etc., and 25 species of broad-leaved weeds such as Artemisia princeps, Draba nemorosa, Hydrocotyle sibthorpioides were occurred on the lawns. One hundred ninety-six weed species of 53 families were occurred on a tomb graveyard adjacent to the mountain. Therefore, it is possible to be infested by the weeds occurring on the graveyard on the golf course adjacent to the mountains. There are 67 items, 32 kinds of the soil treatment herbicides including dichlobenil GR, methiozolin EC, oxaziclomefone SC, imaxaquin GR et al, and 35 kinds of the foliar treatment herbicides including metamifop EC, bifenox flucetosulfuron WG, flazasulfuron WP, trifloxysulfuron-sodium WG et al. registered at the end of May 2012 for efficient management of the weeds occurring on the lawn. For effective management of the weeds, the herbicide can be generally applied twice a year on March to April and August to September for soil treatment and once a year on June to July for the foliage treatment.