• Title/Summary/Keyword: metaluminous

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Geochemical Characteristics of Granodiorite and Arenaceous Sedimentary Rocks in Chon-Ashuu Area, Kyrgyzstan (키르키스스탄 촌아슈 지역 화강섬록암질암 및 사질원 퇴적암의 지화학적 특징)

  • Kim, Soo-Young;Chi, Sei-Jung;Park, Sung-Won
    • Economic and Environmental Geology
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    • v.44 no.4
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    • pp.273-288
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    • 2011
  • Chon-Ashuu copper mining claim area is located, in terms of the geotectonic setting, in the northern part of the suture line which is bounded with the marginal part of Issik-kul micro-continent on the southern part of North Tien-Shan terrane. The geological blocks of Chon-Ashuu districts belong to the southern tip of Kazakhstan orocline. The rock formation of this area are composed of the continental crust or/and arc collage and the paleo-continental fragments-accretionary wedge complex of pre-Altaid orogenic materials. ASI(Alumina Saturation Index) of Paleozoic plutonic rocks in Chon-Ashuu area belong to the peraluminous and metaluminous rocks which were generated from fractional crystallization of Island and volcanic arc crusts in syn-post collisional plate. The geology of the ChonAshuu area consists of upper Proterozoic and Paleozoic rock formations. According to Harker variation diagrams for Chon-Ashuu arenaceous sedimentary rocks, the silty sandstone of Chon-Ashuu area showing the mineralogical immaturity were derived from Island arc or the marginal environments of active continent in Cambro-Carboniferous period. Numerous intrusive rocks of Chon-Ashuu area are distributed along north east trending tectonic structures and are bounded on four sides by the conjugate pattern. The most common type of the plutonic rocks are granodiorite and monzodiorite. According to the molecular normative An-Ab-Or composition (Barker, 1979), the plutonic rocks in Chon-Ashuu area are classified into tonalite - trondhjemite - granodiorite (TTG) series which are an aggregation of rocks which is the country rock of copper mineralization, that are formed by melting of hydrous mafic crust at high pressure.

Geochemical Characterisation of Magnesian Intrusives within High Grade Migmatite Gneiss Terrain: Insight from Plutons around Iwo Area, Southwest Nigeria

  • Ogungbesan, Gbenga O.;Afolabi, Adegoke O.;Mustapha, Adedamola H.;Jimoh, Razak O.;Ajibade, Olumuyiwa M.;Okunola, Olufemi W.
    • Economic and Environmental Geology
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    • v.57 no.5
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    • pp.609-632
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    • 2024
  • Magnesian granitoids, ranging from quartz-syenite to granodiorites of varied mineralogical composition, are poorly studied in metamorphosed terrains of Proterozoic eon, unlike their ferroan variety. Geochemical traits of magnesian granitoids in southwest Nigeria's Precambrian basement are investigated to understand their chemistry and evolutionary origins, such as continental collision events and tectonic settings. Four intrusive units based on their mineralogical compositions were identified as quartz syenite, porphyritic granodiorite, tonalite-trondhemite-graniodiorite (TTG) component of the high-grade migmatite gneiss, and charnockite (with granodioritic compositions). These rocks contain alkali feldspar, plagioclase, quartz, and biotite, the main mineral phases that are common to them. Pyroxene and garnet were observed in the quartz-syenite and charnockite, while hornblende crystals were found in quartz syenite, porphyritic granodiorite, and TTG. Geochemical analysis showed average silica and alumina concentrations accordingly: quartz syenite (59.28% SiO2, 13.28% Al2O3), porphyritic granodiorite (58.80% SiO2, 16.59% Al2O3), TTG (59.07% SiO2, 15.56% Al2O3), and charnockite (53.43% SiO2, 18.06% Al2O3). The average Fe/Mg ratios were 1.14 (quartz syenite), 1.78 (porphyritic granodiorite), 1.66 (TTG), and 1.80 (charnockite), and total alkali values were 9.98% (quartz syenite), 7.79% (porphyritic granodiorite), 9.11% (TTG), and 6.56% (charnockite). Based on their Fe/Mg ratio, alumina saturation index (ASI) (0.63-0.88), and Modified Alkali Lime Index (MALI) these rocks were characterised as metaluminous magnesian with alkali-calcic to alkalic nature. Variable LREE enrichment and europium anomalies were observed, with the quartz-syenite having the highest LREE enrichment and lowest Eu/Eu* (av.0.67). The plot of Rb vs Y+Nb showed that these intrusives are post-collision plutons, with the quartz syenite samples plotting in the syn-collision granite (syn-COLG) field while the porphyritic granodiorite and the charnockite plotted in the volcanic arc granite (VAG) field. These rocks must have been derived from partially melting the upper continental crust and deeper crust of possible mantle materials and emplaced as Pan-African post-orogenic plutons. The tectonic discrimination diagram for the granitoids implied late orogenic to post-collision uplift, collision arc events, and granite magmatism as the dominant events which characterised the Pan-African orogeny.

Petrochemical Study on the Cretaceous Granitic Rocks in the Southern Area of Hambaeg Basin (함백분지(咸白盆地) 남부지역(南部地域)에 분포(分布)하는 백악기(白堊紀) 화강암질암류(花崗岩質岩流)의 암석화학적(岩石化學的) 연구(硏究))

  • Yun, Hyun Soo
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.175-191
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    • 1986
  • The Geodo granodiorite intruded into the Joseon Supergroup is fine-grained at the marginal part, and medium-grained and more leucocratic at the central part. The Quartz monzonite porphyry intruded inte Precambrian granite and Geodo granodiorite has abundant plagioclase phenocryst. The Imog granite intruded into the Yulri Group and the Joseon Supergroup is mediumgrained biotite granite with partly pinkish feldspar phenocryst. The K/Ar ages obtained from the biotite of the Geodo granodiorite and Imog granite are Early ($111{\pm}1{\sim}107{\pm}1$ Ma) and Late ($93{\pm}1{\sim}92{\pm}1$ Ma) Cretaceous, respectively. The K/Ar sericite age of the quartz-sericite zone of the lower Jangsan quartzite occuring in the western area gave much younger age (about 170 Ma) than that of the Jangsan quartzite, that might be reset due to the regional metamorphism of the Daebo orogeny. The granitic rocks of the area are felsic to mafic, metaluminous to peraluminous, calc-alkalic (alkali-lime index${\fallingdotseq}$ 57) and I-type (magnetite-series) based on the chemical data_ And they appear to have been fractionated at the order of Geodo granodiorite, Quartz monzonite porphyry and Imog granite. In terms of mineralogy, geochemistry and K/Ar biotite age, a rock suite of monzodiorite, quartz monzodiorite and quartz monzonite-granodiorite in the Geodo stock was fractionally differentiated from a magmatic body from its margin to inward.

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Petrological and geochemical study of the Precambrian granitic gneiss in the Danyang- Yecheon area (단양-예천사이에 분포하는 선캠브리아 화강암질 편마암류의 암석학적 및 지구화학적 연구)

  • Yun Hyon Soo
    • The Journal of the Petrological Society of Korea
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    • v.1 no.1
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    • pp.34-41
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    • 1992
  • The Precambrian granitic gneisses are widely distributed in the Danyang-Yecheon area, eastern part of Korea, where the Ryeongnam massif borders the Ogcheon fold belt. They are composed of migmatitic, biotite granitic, garnet-bearing and granoblastic granitic gneisses. The common joint sets of the granitic gneiss are NE and NS directions, which are probably related to the effects of Daebo orogeny and Bulgugsa disturbance, respectively. Mineral assemblages of the banded gneiss xenolith in the garnet-bearing granitic gneiss are quartz-plagioc1ase-biotite-mus-covite-orthoclase and quartz-plagioc1ase-biotite-garnet, belonging to the amphibolite facies. The granoblastic granitic gneiss is felsic, metaluminous, and granitic, and shows subalkaline trend. The garnet-biotite geothermometry of garnet-bearing granitic gneiss yields 640$^{\circ}$-708$^{\circ}C$ at pressure of 4 kb.

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Occurrence and petrochemistry of the granites in the Pocheon-Euijeongbu area (포천-의정부 일대에 분포하는 화강암류의 산상과 암석화학)

  • 윤현수
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.91-103
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    • 1995
  • The study area is located at the middle part of Daebo granitic batholith in the Gyeonggi massif. The geology of the area is mostly composed of Precambrian gneiss complex, coarse- grained middle Jurassic and fine-grained early Cretaceous biotite granites, and Cretaceous small stocks and dykes. The gneiss complex consists mainly of banded gneiss, granitc gneiss, some schist and quartzite. The coarse-grained granite can be divided into greyish granite(Gg1 in the margin and slightly pinkish granite(Gp) in the center. The former is hornblende biotite granite characterized by basic clot and xenolith. The latter is generally garnet biotite granite containing only poor basic clot. The fine-grained granite intruded the coarse-grained granite. The K/Ar biotite ages from the granites belong to middle Jurassic and early Cretaceous. The K/Ar biotite ages and geochemical compositions indicate that Gg and Gp were differenciated from a single magmatic body. The granites are calc-alkali and metaluminous-peraluminous. They are S-type(i1menite series) and partly I-type granitedmagnetite series) formed by melting of relatively fixed source composition. Their tectonic settings belong to the compressional suits and VAG of continental margin.

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Geochemical Study of the Cretaceous Granitic Rocks in Yeosu Area (여수 지역에 분포하는 백악기 화강암류에 대한 지화학적 연구)

  • Wee, Soo-Meen;Kim, Eun-Hyo
    • Journal of the Korean earth science society
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    • v.30 no.3
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    • pp.267-281
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    • 2009
  • Cretaceous intrusive and extrusive rocks are widely distributed in the southern part of the Korean peninsula, possibly the result of intensive magmatism which occurred in response to subduction of the Pacific plate beneath the northeastern part of the Eurasian plate. Geochemical and petrological study on the Cretaceous granitic rocks of the Yeosu area were carried out in order to constrain the petrogenesis of the granitic rocks and to establish the paleotectonic environment of the southwestern part of the Korean peninsula. Igneous rocks of the Yeosu area consist of diorite, hornblende biotite pite and micrographic granite. Chondrite normalized REE patterns show generally enriched in LREE ($(La/Lu)^{cN}$=4.2-13.3). Diorites show flat to slight negative Eu anomalies while micrographic granites have strong negative Eu anomalies. The ${\Sigma}REE$ of the granites are 76.2-235 ppm, which corresponds to the range of the continental margin granite. Whole rock chemical data of the granitic rocks from the Yeosu area indicate that the rocks have characteristics of calc-alkaline series in the subalkaline field. On the A/NK vs. A/CNK and tectonic discrimination diagrams, parental magma type of the granites corresponds to I-type and volcanic arc granite (VAG). Interpretations of the chemical characteristics of the granitic rocks favor their emplacement in a compressional tectonic regime at continental margin during the subduction of Pacific plate.

Petrology of the Syenites in Hapcheon, Korea (경남 합천 지역의 섬장암에 관한 암석학적 연구)

  • Ok, Eun-Young;Kim, Jong-Sun;Lee, Sang-Won
    • The Journal of the Petrological Society of Korea
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    • v.26 no.1
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    • pp.13-43
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    • 2017
  • In the Hapcheon area, hypersthene-bearing monzonite (mangerite) and syenite are recognized. The main minerals of syenite are alkali feldspar, plagioclase, amphibole, biotite, and quartz. Anhedral hornblende and biotite are interstitial between feldspar and quartz, indicating that the hydrous minerals were crystallized later on. Based on petrochemical studies of major elements, syenite is alkaline series, metaluminous, and I-type. The variation patterns in the trace and rare earth elements of mangerite and syenite show the features of subduction-related igneous rock such as depletion of HFSE, relative enrichment in LILE to LREE, and negative Nb-P-Ti anomalies. Based on the experimental data and petrographic characteristics of the syenite, Hapcheon syenitic magma is considered to be formed by partial melting in a dry system. SHRIMP U-Pb zircon data yield the Triassic age as $227.4{\pm}1.4Ma$ in mangerite, $215.3{\pm}1.2Ma$ in syenite, and $217.9{\pm}2.6Ma$ in coarse-grained syenite, respectively. The mangerite age is similar to those of post-collisional plutonic rocks in Hongseong (226~233 Ma), Yangpyeong (227~231 Ma), and Odaesan (231~234 Ma) areas in the Gyeonggi Massif. Syenites were intruded after about 10 Ma. The features seen in the mangereite and syenite rocks can be explained by models such as the continental collision and slab break-off and the lithosphere thinning and asthenosphere upwelling model.

Petrochemical Characteristics of the Granites in the Jeomchon area (점촌일대에 분포하는 화강암류에 대한 암석화학적 연구)

  • 최원희;좌용주
    • The Journal of the Petrological Society of Korea
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    • v.7 no.1
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    • pp.37-52
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    • 1998
  • The granites in the Jeomchon area can be divided into hornblende biotite granite (Hbgr), deformed biotite granite (Dbgr), deformed pinkish biotite granite(Dpbgr), biotite granite (Btgr), and granite porphyry(Gp). These granites show metaluminous, 1-type and calc-alkaine characteristics from their whole-rock chemistry. Hbgr and Dbgr belong to ilmenite-series granitoids, but Gp to magnetite-series. Dpbgr and Btgr show the intermediate nature between ilmenite- and magnetite-series. Tectonic discriminations indicate that Hbgr and Dbgr were formed in active continental margin environment, whereas Dpbgr, Btgr, and Gp in post-orogenic and/or anorogenic rift-related environment. From the Harker diagrams major oxide contents of Hbgr and Dbgr show a continuous variation with $SiO_2$, indicating that they are genetically correlated with each other. On the other hand, any correlation of major oxides variation cannot be recognized among Dpbgr, Btgr and Gp. It seems like that Hbgr and Dbgr were derived from a same parent granitic magma, judging from their occurrence of outcrop, mineral composition as well as whole-rock chemistry. Variation trends of major oxide contents between Hbgr and Baegnok granodiorite are very similar and continuous. If the two granites were derived from a cogenetic magma, there exists a possibility that the granitic bodies had been separated by Btgr and Gp of Cretaceous age. Three stages of the granitic intrusions are understood in the Jeomchon area. After the intrusion of Hbgr and Dbgr during middle to late Paleozoic time, Dpbgr emplaced into the area next, and finally Btgr and Gp intruded during Cretaceous time. Tectonic movement accompanying shear and/or thrust deformation seems likely to have occurred bewteen the intrusions of Dpbgr and Btgr.

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Petrochemistry and magma process of Jurassic Boeun granodiorite in the central Ogcheon belt (중부 옥천대에 분포하는 쥬라기 보은 화강섬록암의 암석화학과 마그마과정)

  • 좌용주
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.188-199
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    • 1996
  • Boeun granodiorite, which intruded into the metasedimentary rocks of the Ogcheon Group, show chemical natures of metaluminous and calc-alkaline. Generating and emplacing environment of the Boeun granodiorite would have been a active continental margin. Comparing to the contemporaneous Inje-Hongcheon granodiorite in the Gyeonggi massif, the Boeun granodiorite seems likely to have formed under more immature continental arc environment. Compositional changes of major, trace and rare earth elements in granodiorite and felsic dyke are not certain to indicate crystallization differentiation. From this fact, the simple fractional crystallization model would be in question to explain the magma process which controlled the formation of the Boeun granitic mass. The model calculations for Rayleigh fractionation, fractionation with variable major-component composition, assimilation-fractional crystallization (AFC) were carried out to examine the magma process of the mass. The results of former two models do not agree with the compositional variations in the mass. The AFC model can be, however, applied to the magma process. The conditions for AFC process are (1) composition of assimilated wallrock is similar to that of primary magma. (2) assimilating rate is similar to crystallizing rate, and (3) mass of assimilated wallrock is about 10% of that of the magma. These conditions deny a possibility that the assimilated wallrock was the metasedimentary rocks of the Ogcheon Group. This indicates that after having experienced the assimilation process in deeper crust, the granodiorite magma intruded into the Ogcheon group. Every model calculating suggests that the felsic dyke was differentiated not from the granodiorite magma, but from a different source magma.

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Mineralogy, Geochemistry, and Evolution of the Mn-Fe Phosphate Minerals within the Pegmatite in Cheolwon, Gyeonggi Massif (경기육괴 철원지역 페그마타이트 내 망간-철 인산염광물의 광물-지화학적 특징 및 진화과정)

  • Kim, Gyoo Bo;Choi, Seon Gyu;Seo, Jieun;Kim, Chang Seong;Kim, Jiwon;Koo, Minho
    • Economic and Environmental Geology
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    • v.50 no.3
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    • pp.181-193
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    • 2017
  • Mn-Fe phosphate mineral complexes included within the pegmatite are observed at Jurassic Cheolwon two-mica granite in Gyeonggi Massif, South Korea. The genetic evolution between the Cheolwon two-mica granite and pegmatite, and various trend of Mn-Fe phosphate minerals is made by later magmatic, hydrothermal, and weathering process based on mineralogical, geochemical analysis. The Cheolwon two-mica granite is identified as S-type granite, considering its chemical composition (metaluminous ~ peraluminous), post-collisional environment, low magnetic susceptibility, and existence of biotite and muscovite. The K-Ar age (ca. 153 Ma) of pegmatite is well coincident with age of the Cheolwon two-mica granite ($151{\pm}4Ma$). It indicates that these two rocks are originated from the same magma. Pegmatite indicates the LCT geochemical signature, and was classified as muscovite-rare element class / Li subclass / beryl type / beryl-columbite-phosphate subtype pegmatite. The triplite $\{(Fe^{2+}{_{0.4}},Mn_{1.6})(PO_4)(F_{0.9})\}$ is dominant phosphates in later magmatic stage which partly altered to leucophosphite $\{KFe^{3+}{_2}(PO_4)_2OH{\cdot}2H_2O\}$ and jahnsite $\{(Fe^{3+}{_{0.7}},Mn_{2.3})(PO_4)_2OH{\cdot}4H_2O\}$ by hydrothermal alteration. In particular, near fractures, the triplite has been separatelty replaced by the phosphosiderite ($Fe^{3+}PO_4{\cdot}2H_2O$) and Mn-oxide minerals during weathering stage.