• Title/Summary/Keyword: metallic structure

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Half-metallic and Magnetic Properties of (001) Surfaces of KCaN2 Compound in full-Heusler Structure

  • Bialek, Beata;Lee, Jae Il
    • Journal of Magnetics
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    • v.18 no.4
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    • pp.375-379
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    • 2013
  • The electronic and the magnetic properties of (001) surface of $KCaN_2$ half-metallic compound with full-Heusler structure are studied with the use of a full-potential linearized augmented plane wave method. Two possible terminations of the surface are considered and only the one with N atoms in the topmost layer is found to retain the half-metallic properties of the bulk. The magnetic properties of N-terminated surface are enhanced compared with the properties of the bulk. The calculated magnetic moments on the N atoms in the $KCaN_2$ are 1.26 ${\mu}_B$ in the bulk and 1.90 ${\mu}_B$ at the surface. The subsurface metal atoms are also slightly polarized. In the surface terminated with metal atoms, not only the half-metallicity is destroyed, but also the magnetic properties of the system are weakened.

Micro-deformation behavior of Brittle Hf-based Metallic Glass during Mechanical Milling (기계적 합금화 공정에 의한 Hf계 비정질 분말의 미세변형거동 관찰)

  • Kim, Song-Yi;Lee, A-Young;Cha, Eun-Ji;Kwon, Do-Hun;Hong, Sung-Uk;Lee, Min-Woo;Kim, Hwi-Jun;Lee, Min-Ha
    • Journal of Powder Materials
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    • v.25 no.3
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    • pp.246-250
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    • 2018
  • In this study, we investigate the deformation behavior of $Hf_{44.5}Cu_{27}Ni_{13.5}Nb_5Al_{10}$ metallic glass powder under repeated compressive strain during mechanical milling. High-density (11.0 g/cc) Hf-based metallic glass powders are prepared using a gas atomization process. The relationship between the mechanical alloying time and microstructural change under phase transformation is evaluated for crystallization of the amorphous phase. Planetary mechanical milling is performed for 0, 40, or 90 h at 100 rpm. The amorphous structure of the Hf-based metallic glass powders during mechanical milling is analyzed using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Microstructural analysis of the Hf-based metallic glass powder deformed using mechanical milling reveals a layered structure with vein patterns at the fracture surface, which is observed in the fracture of bulk metallic glasses. We also study the crystallization behavior and the phase and microstructure transformations under isothermal heat treatment of the Hf-based metallic glass.

Metallic FDM Process to Fabricate a Metallic Structure for a Small IoT Device (소형 IoT 용 금속 기구물 제작을 위한 금속 FDM 공정 연구)

  • Kang, In-Koo;Lee, Sun-Ho;Lee, Dong-Jin;Kim, Kun-Woo;Ahn, Il-Hyuk
    • Journal of Internet of Things and Convergence
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    • v.6 no.4
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    • pp.21-26
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    • 2020
  • An autonomous driving system is based on the deep learning system built by big data which are obtained by various IoT sensors. The miniaturization and high performance of the IoT sensors are needed for diverse devices including the autonomous driving system. Specially, the miniaturization of the sensors leads to compel the miniaturization of the fixer structures. In the viewpoint of the miniaturization, metallic structure is a best solution to attach the small IoT sensors to the main body. However, it is hard to manufacture the small metallic structure with a conventional machining process or manufacturing cost greatly increases. As one of solutions for the problems, in this work, metallic FDM (Fused depositon modeling) based on metallic filament was proposed and the FDM process was investigated to fabricate the small metallic structure. Final part was obtained by the post-process that consists of debinding and sintering. In this work, the relationship between infill rate and the density of the part after the post-process was investigated. The investigation of the relationship is based on the fact that the infill rate and the density obtained from the post-processing is not same. It can be said that this work is a fundamental research to obtain the higher density of the printed part.

Improvement of Metallic Micro-Structure Precision Employing Two-photon Induced Photoreduction Process (이광자 흡수 광환원 공정을 이용한 마이크로 금속형상 제작의 정밀화에 관한 연구)

  • Son, Yong;Lim, Tae-Woo;Yang, Dong-Yol;Prem, Prabhakaran;Lee, Kwang-Sup
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.9
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    • pp.754-760
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    • 2008
  • A two-photon induced photoreduction process suggests a possibility for fabricating complicated metallic microstructures which can be applied to 3-D micro-circuits and optical devices, etc. The process employs the photoreduction of silver ions in a metallic solution which is composed of metallic salt ($AgNO_3$) and watersoluble polymer ((poly(4-styrenesulfonique acid) 18wt. % in $H_2O$, $(C_8H_8O_3S)_n$)). In this process, the improvement of the resolution and the uniformity of fabricated metallic structures are important issues. To address these problems, continuous forming window (CFW) is obtained from a parametric study on the conditions of laser power and scanning velocity and the direct seed generation (DSG) method is proposed. Silver nano particles are uniformly generated in a metallic solution through the DSG method, which enables the decrease of a laser power to trigger the photoreduction of silver ions as well as the increase of metal contents in a metallic solution. So the two-photon induced photoreduction property of a metallic solution is improved. Through this work, precise silver patterns are fabricated with a minimum line width of 400 nm.

Microforming of Bulk Metallic Glasses : Constitutive Modelling and Applications (벌크비정질합금의 미세성형 : 구성모델과 적용)

  • 윤승채;백경호;김형섭
    • Transactions of Materials Processing
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    • v.13 no.2
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    • pp.168-173
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    • 2004
  • Microforming can be a good application for bulk metallic glasses. It is important to simulate the deformation behaviour of the bulk metallic glasses in a supercooled liquid region for manufacturing micromachine parts. For these purposes, a correct constitutive model which can reproduce viscosity results is essential for good predicting capability. In this paper, we studied deformation behaviour of the bulk metallic glasses using the finite element method in conjunction with the fictive stress constitutive model which can describe non-Newtonian as well as Newtonian behaviour. A combination of kinetic equation which describes the mechanical response of the bulk metallic glasses at a given temperature and evolution equations fur internal variables provide the constitutive equation of the fictive stress model. The internal variables are associated with fictive stress and relation time. The model has a modular structure and can be adjusted to describe a particular type of microforming process. Implementation of the model into the MARC software has shown its versatility and good predictive capability.

Synthesis of Ni-based Metallic Glass Composite Fabricated by Spark Plasma Sintering (방전플라즈마소결을 이용한 Ni계 비정질 복합재의 제조)

  • Kim, Song Yi;Guem, Bo Kyeong;Lee, Min Ha;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.33-36
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    • 2013
  • A bulk metallic glass-forming alloy, $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ metallic glass powders was used for good commercial availability and good formability in supercooled liquid region. In this study, the Ni-based metallic glass was synthesized using by high pressure gas atomized metallic glass powders. In order to create a bulk metallic glass sample, the $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ metallic glass powders with ball-milled Ni-based amorphous powder with 40%vol brass powder and Cu powder for 20 hours. The composite specimens were prepared by Spark Plasma Sintering for the precursor. The SPS was performed at supercooled liquid region of Ni-based metallic glass. The amorphous structure of the final sample was characterized by SEM, X-ray diffraction and DSC analysis.

Metallic Structure of Iron Relics of Chosun Dynasty Excavated from Gangsun Tower, Chengpyeong Temple (청평사 강선루 출토 조선시대 철제유물의 금속조직에 대하여)

  • Kim, S. K.;Lee, C. H.
    • Journal of Conservation Science
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    • v.17 s.17
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    • pp.57-64
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    • 2005
  • In the course of examining the micro structure of Iron chisel and Iron arrowhead, a relics of the 16th or 17th of Chosun Dynasty unearthed at near Gangsun-tower, Chengpyeong temple. Collected un-eroded samples from the relics were looked into the metallic structure through optical metallography. Non-metallic inclusions were-analysed by SEM and EDS. The micro structure examination and SEM-SDS analysis revealed that Iron chisel and Iron arrowhead had been produced from the sponge iron close to pure iron made by low temperature reducing in a solid and then the surface carbon content was increased by carburizing treatment. It was also found that Iron chisel had been hardened through the repetitive processes of quench hardening and heat treatment, after increasing carbon content to a certain level. Up to now, there have been a number of studies in the domestic academia which were studied mainly on the structure of metallic relics in the period of the Three Kingdoms or before. Although this research was limited in type and number of the relics, it turned out to be interesting in that it revealed the 16th or 17th century way of processing iron, even in fragments. It is thought to be fruitful that iron had been made even in the Chosun Dynasty from the sponge iron.

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Turning and Metallic Characterization for Piston Materials of Automobile (자동차용 피스톤소재의 금속적 특징 및 선삭 가공 특성)

  • 채왕석;김경우;최현민;김동현
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2001.10a
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    • pp.202-206
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    • 2001
  • The purpose of this research was to study the influence of machining characteristics for aluminum alloys. The effect of metallic microstructural variables on the measures of machinability of aluminum alloys has no been adequately investigated. Machining Characteristics are influenced significantly by mechanical characteristics, composition and structure of material etcs. For improvement of machining characteristics, various studies are reported. In this paper, composition elements add to aluminum alloys within the limit of sustaining mechanical characteristics of metallic material. We have analyzed dynamic characteristics of cutting resistance, tensile strength value, hardness value etcs.

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Fabrication of Metallic Sandwich Plates with Inner Dimpled Shell Structure and Static Bending Test (딤플형 내부구조 금속 샌드위치 판재의 제작 및 정적 굽힘 실험)

  • Seong Dae-Yong;Jung Chang-Gyun;Yoon Seok-Joon;Lee Sang-Hoon;Ahn Dong-Gyu;Yang Dong-Yol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.6 s.249
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    • pp.653-661
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    • 2006
  • Metallic sandwich plates with various inner cores have important new features with not only ultra-light material characteristics and load bearing function but also multifunctional characteristics. Because of production possibility on the large scale and a good geometric precision, sandwich plates with inner dimpled shell structure from a single material have advantages as compared with other solid sandwich plates. Inner dimpled shell structures can be fabricated with press or roll forming process, and then bonded with two face sheets by multi-point resistance welding or adhesive bonding. Elasto-plastic bending behavior of sandwich plates have been predicted analytically and measured. The measurements have shown that elastic perfectly plastic approximation can be conveniently employed with less than 10% error in elastic stiffness, collapse load, and energy absorption. The dominant collapse modes are face buckling and bonding failure after yielding. Sandwich plates with inner dimpled shell structure can absorb more energy than other types of sandwich plates during the bending behavior.

Improvement of the mechanical properties of titanium carbonitride-metal composites by modification of interfaces (계면 개선을 통한 타이타늄 탄/질화물 금속 복합재료의 기계적 물성 향상)

  • Kwon, Hanjung
    • Ceramist
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    • v.23 no.2
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    • pp.114-131
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    • 2020
  • Fracture in the titanium carbonitride-metal composites occurs by crack propagation through the carbonitride grains or in the interfaces. Thus, intrinsic properties of the carbonitride need to be enhanced and the interfaces should be also modified to coherent structure to strengthen the composites. Especially, interfacial structure can be the main factor to determine the mechanical properties of titanium carbonitride-metal composites because the interfaces between carbonitride grains and metallic phase are weak parts due to heterogeneous nature of carbonitride and metallic phase. In this paper, methodologies for improving the interfacial structure of titanium carbonitride-metal composites are suggested. Total area of the interfaces can be reduced using solid solution type carbonitrides as raw materials instead of a mixture of various carbonitrides in the composites. Also, synthesis of titanium carbonitride-metal composite powders and the low-temperature sintering of the composite powders for short time can be the way for formation of coherent interfaces. The sintering of the composite powders for short time at low temperature can reduce the potential of formation of interfaces by dissolution and precipitation of carbonitride in the liquid metal. As a result of formation of coherent boundaries due to low-temperature and short-time sintering, interfaces between titanium carbonitride grains and metallic phase have the favorable structure for the enhanced fracture toughness. It is believed that the low-temperature sintering of solid solution type composite powders for short time can be the way to improve the low toughness of the titanium carbonitride-metal composites.