• Journal of the Korean Chemical Society
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• v.57 no.5
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• pp.574-590
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• 2013

A new solid complexes of Ti(IV), Y(III) and Ce(IV) have been synthesized with ofloxacin. The formulae and structure of the complexes have been proposed in the light of analytical, spectral ($^1H$ NMR, IR and UV-Visible), magnetic, molar conductivities and thermal studies. The complexes are soluble in DMSO-$d_6$ and DMF. The measured molar conductance values indicate that, the three complexes are electrolyte in nature. The results support the formation of the complexes and indicated that ofloxacin reacts as a bidentate ligand chelate to the metal ion through the pyridone oxygen and one carboxylato oxygen. The kinetic parameters of thermogravimetric and its differential have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflect the thermal stability for all complexes. The metal- ligand binding of the Ti(IV), Y(III) and Ce(IV) complexes is predicted using density funcational theory at the B3LYP-CEP-31G level of theory and total energy, dipole moment estimation of different Ti(IV), Y(III) and Ce(IV) ofloxacin structures. The biological activities of the ofloxacin, inorganic salts and their metal complexes were assayed against different bacterial species.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.4
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• pp.74-80
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• 2009

Effect of dye wastewater on heavy metal removal using carboxylated alginic acid bead was performed. When carboxylated alginic acid bead was used as support, effect of dye wastewater on adsorption of $Pb^{2+}$ and $Cu^{2+}$ ions was very small. Also, when $Pb^{2+}$ was coexisted with dye wastewater, adsorption process was almost completed within 2-3 hrs and $Pb^{2+}$ ions (50 ppm) was almost removed with 0.3g of bead. This result means that carboxylated alginic acid bead has effective adsorbent for heavy metal removal in dye wastewater.

• Applied Science and Convergence Technology
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• v.24 no.5
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• pp.172-177
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• 2015

We present disordered moth eye structures on curved surfaces fabricated by dry etching of thermally dewetted metal nanoparticles. This lithography-free fabrication allows the formation of subwavelength scale nanostructures on the strongly inclined surfaces such as ball lens as well as on the microlens arrays with low curvature. In particular, we found that the size and average distance of nanostructures are closely related to the inclined angle of the surface. Experimental results on oblique angle deposition of metal thin films followed by thermal dewetting also support these effects.

• Applied Microscopy
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• v.45 no.4
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• pp.214-217
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• 2015

This study introduces metal coating as an effective sample preparation method to remove charge-up caused by the shadow effect during field emission scanning electron microscope (FE-SEM) analysis of dynamic structured samples. During a FE-SEM analysis, charge-up occurs when the primary electrons (input electrons) that scan the specimens are not equal to the output electrons (secondary electrons, backscattered electrons, auger electrons, etc.) generated from the specimens. To remove charge-up, a metal layer of Pt, Au or Pd is applied on the surface of the sample. However, in some cases, charge-up still occurs due to the shadow effect. This study developed a coating method that effectively removes charge-up. By creating a converted sample stage capable of simultaneous tilt and rotation, the shadow effect was successfully removed, and image data without charge-up were obtained.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.04a
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• pp.196-202
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• 1997

A reinforced hydraulic hoses,caiied a resonator hoses,with fixible metal tube are commonly used in automotive power steering hydraulic systems to attenuate and eliminate the objectionable fluid borne noise(pressure ripple) or vibration produced by a pump or steering gear. To achieve better nose attenuation in automotile vehicles, the investigations on propagation and attenuation characteristics of fluid borne pressure ripple in power steering hydraulic ciruit are required. So, this paper descibes a mathematical model of hydraulic hoses to support design the power steering hydraulic circuit and analyze the attenuation characteristics of flow and pressure ripples. The model is based on the transfer matrix approach. The experimental results show that the pulsation attenuation characteristics of hydraulic house is remarkably affected by the flexible metal tube inserted coaxially inside a hydraulic hose with a finite length as well as viscoelastic properties of house wall. It is also shown that the predicted results bymodel proposed here agree well with the measured results over a wide frequency range. These results will assist in the modeling and design of hydraulic hoses, and hear, should provide a means for designing a quieter automotive power steering hydraulic systems.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.328-334
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• 2008

The effects of catalyst preparation on the reaction route and the mechanism of biphenol (BP) hydrogenation, which consists of a long series-reaction, were studied. Pd/C catalysts were prepared by incipient wetness method and precipitation and deposition method. The reaction behaviors of the prepared catalysts and a commercial catalyst along with the final product distributions were very different. The choice of the catalyst preparation conditions during precipitation and deposition including the temperature, pH, precursor addition rate, and reducing agent also had significant effects. The reaction behaviors of the catalysts were interpreted in terms of catalyst particle size, metal distribution, and support acidities.

• Advanced Composite Materials
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• v.17 no.2
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• pp.177-190
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• 2008

As the first step in discussing the reliability of composite structures, a fundamental study was performed to obtain the scattering characteristics of glass-fiber reinforced plastics (GFRP) and woven carbon fiber reinforced plastics (WCFRP) as well as a reference metal. The Euler buckling load was obtained experimentally for each material. The experiments were conducted for specified rectangular specimens with simply supported edges. A new attachment to realize the simply support boundary conditions for composite materials have been prepared before these experiments. The scattering data in the results for GFRP and WCFRP composites were compared with those of a typical metal of aluminum alloy. The experimental data were also compared with numerical simulations including the uncertainties.

• Smart Structures and Systems
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• v.6 no.7
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• pp.867-887
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• 2010

An energy-based variational approach is used for structural dynamic modeling of the IPMC (Ionic Polymer Metal Composites) flapping wing. Dynamic characteristics of the wing are analyzed using numerical simulations. Starting with the initial design, critical parameters which have influence on the performance of the wing are identified through parametric studies. An optimization study is performed to obtain improved flapping actuation of the IPMC wing. It is shown that the optimization algorithm leads to a flapping wing with dimensions similar to the dragonfly Aeshna Multicolor wing. An unsteady aerodynamic model based on modified strip theory is used to obtain the aerodynamic forces. It is found that the IPMC wing generates sufficient lift to support its own weight and carry a small payload. It is therefore a potential candidate for flapping wing of micro air vehicles.

• Structural Engineering and Mechanics
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• v.56 no.3
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• pp.443-460
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• 2015

This paper presents the analysis of mechanical behavior of metal wall panels of storehouses and industrial buildings subjected to differential settlements. The storehouses considered are representative of those used in the agricultural activity. A small-scale model was built and tested in order to have evidence of the behavior and to validate computational models. The numerical investigation is carried out through finite element analysis using a general-purpose software, by modeling buildings with different geometries and evaluating different settlements of the ground. To obtain an adequate model, geometric non-linearity has to be taken into account. Models that represent the most usual geometric typologies were investigated under support settlements. The deflected shape of the wall panel and the relationship between the horizontal displacements and the settlement of the foundations are evaluated. The results show that there are large out-of-plane displacements caused by settlements that would be admitted by design recommendations.

• Journal of the Korean Ceramic Society
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• v.43 no.11 s.294
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• pp.703-709
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• 2006

We report on the synthesis of highly uniform, single phase zinc and cobalt thin films prepared by the Liquid Phase Deposition (LPD) method. X-Ray diffraction, TGA and EDX measurements support the assumption that the as deposited films are constituted by a mixture of crystallized FeOOH and amorphous M(OH)$_2$ (M=Co, Zn) which is converted upon heat treatment in air at 600?C into the corresponding zinc ferrites. The films with adjustable chemical compositions are identified with a crystal structure as spinel-type and present a spherical or rod-like microstructure, depending on the both the nature and concentration of the divalent transition metal ions. Zinc ferrite thin films present a superparamagnetic behavior above blocking temperatures which decrease with increasing the Zn content and are ferromagnetic at 5 K with coercivities ranging between 797.8 and 948.5 Oe, whereas the cobalt ferrite films are ferromagnetic at room temperature with magnetic characteristics strongly dependent on the chemical composition.