• Title/Summary/Keyword: metal stability

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Surface Modification of Ag Coated Cu Conductive Metal Powder for Conductive Silicone Sealant Gasket Paste

  • Park, Seong-Yong;Yoon, Tae-Won;Lee, Chung-Ho;Jeong, In-Bum;Hyun, Sang-Hoon
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1076-1077
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    • 2006
  • Conductive pastes consist of conductive fillers( Au, Ag, Ni, Cu etc.), organic binders, solvents and additives. Meanwhile, there are some metal powders such as copper, nickel etc that are used for pastes which have serious surface corrosion problems. This problem leads to change of the color and decrease in conductivity and affect storage stability of conductive pastes. By using silane coupling agent and dispersion agent, we can ensure both the corrosion stability and long term storage stability, and enhance the high performance electrical and mechanical properties of EMI shielding silicone sealant.

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Hole Transfer Layer p-doped with a Metal Oxide for Low Voltage Operation of OLEDs

  • Shin, Won-Ju;Lee, Je-Yun;Kim, Jae-Chang;Yoon, Tae-Hoon;Kim, Tae-Shick;Song, Ok-Keun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.435-438
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    • 2007
  • $V_{2}O_{5}$ was tested as a p-dopant for lower operating voltage and higher stability of OLEDs. Low voltage and high stability were achieved using this doping layer. It can be separated to bulk and interface contributions and the latter is a more dominant factor both of operation voltage and stability.

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Investigation of Influence of Pulse-periodical Laser Radiation Power on Stability of Liquid-metal Contacts between Powder Particles during Selective Laser Sintering

  • Beljavin, K.E.;Minko, D.V.;Bykov, R.P.;Kuznechik, O.O.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.518-519
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    • 2006
  • A connection between pulse-periodical laser radiation power and stability of liquid-metal contacts between powder particles during selective laser sintering (SLS) is determined based on analysis solving the problem of stability of liquid column in the gravity and capillary forces field. On the grounds of obtained relationships the optimization of pulse-periodical laser radiation power and SLS-process duration is realized, that allows to produce voluminous powder porous materials with pre-determined physical and mechanical properties and surface geometry. Results of metallographic investigations of powder porous materials of titanium powder produced with technological regimes calculated by means of obtained relationships are given in the work

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PVC의 저온 열안정성 향상에 관한 연구 (Improvement of low temperature thermal stability on PVC)

  • 정광보;전인기;안성환
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.440-450
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    • 2009
  • Metal(Zinc) soap and mixed metal(Zn/Ba) soap were synthesized with good structures and characterized by IR and H-NMR. The H-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. The mixed metal soaps with various costabilizers(acid or metal content effect), which added in order to investigate the thermal stabilization effect at low and high temperature, were investigated the thermal stabilization effect. The temperature effect is relation to the metal content effect than acid effect. In case of mixed metal soap, the high thermal stabilization effect improved with increasing Barium content. As the Zinc content increase the low temperature thermal stabilization effect improved, but the high temperature thermal stabilization effect showed an opposite tendency.

POLYVINYLPYRROLIDONE METAL COMPLEXES. FORMATION STABILITY AND THEIR BIOLOGICAL ACTIVITY

  • Lee, V. A.;S. Sh. Rashidova
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.463-465
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    • 1998
  • The peculiarities of the polyvinylpyrrolydone (PVP) interaction with transition metal ions of the first row in solution were studied. It was shown that PVP macromolecules due to their swelling conformation in organic solvents form the stable metal complexes. Metal ions were bond with oxygen and nitrogen atoms of PVP lactam rings. In water solution every metal ion interacts with one or two oxygen atoms out of 10-12 monomer units of the polymer. The additional contraction of PVP macromolecule coils in water have been found out by dissolving of the polymer metal complexes (PMC) synthesized in organic media. Toxicity, blood forming and immune stimulating activity and pharmaco-kinetic too of obtained polymers and their metal completes have been investigated. The factors and effects that responsible fur changing of PMC physical-chemical and biological properties have been estimated.

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Development of nano-and meso- inorganic membrances for the environmental applications

  • Yi, Jong-Heop
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 첨단 분리막 연구동향
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    • pp.37-59
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    • 2004
  • Advantages : - Multi-functionality of inorganic surface ㆍMetal chelating ligand $\longrightarrow$ metal recovery .Alkylation $\longrightarrow$ hydrophobicity control - Enhanced stability ㆍThermal, mechanical and chemical stability ㆍSeparation in high temperature and pressure (omitted)

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저에너지 충돌 탄뎀 질량분석법을 이용한 올리고당의 연결부위 연구: 금속양이온의 첨가가 미치는 영향 (Linkage Positions of Oligosaccharides by Low Energy Collision Tandem Mass Spectrometry: Effect of the Addition of Metal Cations)

  • 육은순
    • 대한화학회지
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    • 제40권8호
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    • pp.557-564
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    • 1996
  • 각기 다른 양이온$(Na^+, Li^+, K^+, NH_4^+)$을 구조이성질체인 일련의 합성 올리고당에 첨가함으로써, 양이온의 결합정도가 올리고당의 연결위치에 따라 달라지리라는 것을 FAB CAD MS/MS(Fast Atom Bombardment Collision Activated Dissociation Mass Spectrometry/ Mass Spectrometry)를 이용하여 안정성 측면에서 연구하였다. 알카리 양이온화된(cationized) 올리고당들은 양성자화(protonated)된 형태보다 더 큰 안정성을 나타내어 -40 eV의 충돌 에너지 수중에서 연결부위와 작용기들이 분절된 스펙트럼형태를 보인 반면, 양성자화된 올리고당은 -10 eV에서 에서 같은 정도의 분절을 보였다. 첨가된 양이온 중, 칼륨 양이온이 첨가된 올리고당이 다른 것에 비해 안정화되어 triple quadrupole기종의 허용에너지 조건하에서는 분절이온을 생성하지 않는다. 다른 양이온화된 올리고당들은 충돌기체인 argon의 압력이 0.8mTorr 상태에서 양이온의 종류에 따라$Nap^+>Li^+>NH_4^+$순으로 안정성을 나타내었다. 올리고당과 결합하는 금속양이온들은 질소를 포함하고 있는 아미노당에 위치하며, 이는 아미노당을 포함하는 분절이온마다 각 양이온에 해당하는 만큼의 질량이 이동된 분절피크들이 나타나는 것으로 설명 가능하다. 또한 양이온화된 것이 양성자화된 것보다 더 큰 안정성을 지니는 이유는 금속 양이온과 아미노당의 N-acetyl 작용기 및 fucose의 산소 사이에 크라운에테르 형태의 결합을 형성하는 것으로 설명할 수 있다. 이 때 참여한 금속 양이온의 크기 및 연결위치-이성질 부분의 구조적 형태에 따라 결합정도의 차이를 보여 각기 다른 분절스펙트럼의 형태를 나타내며 안정성면에서도 1-6>1-4>1-3 연결위치의 순으로 나타났다.

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GMA용접에서 콘택트 팁 재질에 따른 용접특성 평가 (Evaluation of Gas Metal Arc Welding Characteristics according to Contact Tip Materials)

  • 김동윤;황인성;김동철;강문진
    • Journal of Welding and Joining
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    • 제32권6호
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    • pp.35-40
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    • 2014
  • The contact tip for gas metal arc welding has important functions to transmit the welding current to the wire and to guide the wire to molten pool. If the contact tip is damaged, it is a cause of lowering the welding productivity due to removal of welding defects and replacement of contact tip. In case of the use of a contact tip for a long time the arc is unstable because the processed hole in the contact tip center is larger, and the variation of aiming position of the welding wire causes a seam tracking error. In this study, gas metal arc welding experiments using contact tip of three different materials were performed. The contact tips with Cu-P, Cu-Cr, and Cu-ODS were used at the experiments, and the welding characteristics by each contact tip were evaluated. After welding contact tip appearance, welding spatter adhesion amount of the nozzle, and weld bead appearance were evaluated. The welding current and welding voltage were measured to verify arc stability during arc welding.

이미다졸-금속 이온 착체를 포함하는 고분자 LB막의 기체 투과성 (Gas Permeability of Polymeric LB Films Containing Imidazole-Metal Ion Complexes)

  • 김병주;이범종
    • 폴리머
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    • 제24권4호
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    • pp.453-458
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    • 2000
  • 이미다졸-금속 이온 구조를 갖는 고분자 Langmuir-Blodgett (LB)막과 이들의 캐스트막을 다공성막 필터 위에 제조하여 산소와 질소의 투과성을 비교 검토하였다. 양친성 고분자 폴리 (N-(2-(4-이미다졸일)에틸)말레이미드-alt-1-옥타데센) (IM-O)은 폴리 (무수말레산-alt-1-옥타데센)과 히스타민의 반응으로 합성되었다. IM-O 단분자층은 철(III) 이온을 갖는 하층액 위에서 매우 안정하였다. LB막의 분자 구조는 FT-IR을 통하여 결정하였으며, LB막내에 존재하는 금속 이온의 농도는 XPS 측정으로 분석하였다. LB막의 균일성과 안정성을 SEM 관찰을 통하여 간접적으로 평가하였다. 본 LB막과 캐스트막의 기체 선택성은 산소보다 질소가 약간 높게 나타났으며, 두 기체에 대하여 모두 고투과성을 나타냈다.

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