• 한국염색가공학회지
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• 제27권1호
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• pp.62-69
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• 2015

To improve the color stability of the bioplastic containing sorghum extract, sorghum extract was chelated by a metal ion. The chelating activity was quantitatively evaluated under the various conditions. Chelation of sorghum extract by Cu(II) was determined by reaction with pyrocatechol violet, whereas Fe(II) chelation was investigated by forming complexes with ferrozine. Chelation of sorghum extract was increased rapidly with increasing concentrations of metal salt and sorghum extract. At a 0.1g/L metal salt addition level, the chelating activity of Fe(II) and Cu(II) were 66.7% and 54.2%, respectively. According to the chelation pH conditions, the sorghum extract was chelated almost 100% by Fe(II) above the pH 6.5. It was confirmed that Fe(II) was a strong chelator of sorghum extract than Cu(II). The sorghum extract chelated with metal salt exhibit higher thermal stability. The bioplastic containing chelated sorghum extract showed relatively less color change than the control.

• 한국식품과학회지
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• 제37권4호
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• pp.519-524
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• 2005

국내산 소금과 수입산 소금의 무기질 및 중금속 함량의 차이와 이들 소금이 새우젓의 무기질 및 중금속 함량에 미치는 영향을 파악하였으며, 실제 시판되고 있는 새우젓을 산지별로 구입하여 무기질 및 중금속 함량을 분석하였다. 국산 천일염과 그것으로 제조한 새우젓은 중국산에 비해 Cu, K, Mg의 함량이 많았으며, 중국산 천일염과 그것으로 제조한 새우젓은 Mn, Na함량이 높은 것으로 나타났다. 그러나 시판새우젓에서는 산지에 따른 무기질의 차이가 나타나지 않았다. 중금속을 분석한 결과 시판 소금은 Pb, Hg 및 As는 검출되지 않았으나, Cd는 식품공전의 규정(<0.5ppm) 이하인 0.07-0.30ppm의 함량으로 검출되었다. 20 종의 시판 새우젓의 경우, Cd가 0.1 ppm(ND-0.5 ppm)의 함량으로 검출되었으며, 실험실 제조 새우젓의 경우, Pb이 0.3ppm(ND-0.8ppm)의 함량으로 검출되었으며, 다른 중금속(As, Hg, and Ni)은 검출되지 않았다.

• 한국식품영양학회지
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• 제22권2호
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• pp.238-245
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• 2009

The principal objective of this study was to investigate the association of variable salts with the hardness of cubed white radish. We analyzed the contents of domestic sun-dried salt, Chinese sun-dried salt, domestic refined salt, Australian rock salt and Australian industrial sun-dried salt in the radish samples. Our assessment of the water content of variable salts showed that domestic refined salt was highest(7.27%) and Australian rock salt was lowest(0.16%). The NaCl contents of variable salts were as follows : 93.23% in refined salt, 93.76% in Australian rock salt, 87.85% in domestic Shinan sun-dried salt and 87.98% in Chinese sun-dried salt. The content of insoluble matter in water were $0.03{\sim}0.05%$ in all salts except 0.85% in Australian industrial sun-dried salt. The pH values of salts were as follows : 8.93 in domestic sun-dried salt, 8.62 in Chinese sun-dried salt, 6.69 in refined salt, 5.83 in Australian rock salt and 6.41 in Australian industrial sun-dried salt. Regarding the mineral component content assays, domestic salt was found to harbor lower Na content but far higher Mg, K, Ca contents than other salts. In our evaluation of the hardness of cubed white radish, we detected a continuous increase in the hardness of cubed white radish soaking in a 4% salt solution of domestic Shinan natural salt, but an initial increase followed by a decrease in the hardness of cubed white radish soaking in a 4% solution of the other salts.

• 자원리싸이클링
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• 제15권2호
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• pp.32-36
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• 2006

마그네슘은 자동차 엔진 경량화재료 및 휴대폰과 노트북 PC케이스 등 기능성 경량재료로서의 용도개발과 함께 수요가 증가하고 있다. 마그네슘 제련법은 원료광의 특성에 따라 달라지는데 크게 용융염전해법과 열환원법 두가지로 구분할 수 있다. 본 연구에서는 염화마그네슘을 사용하여 용융염전해법에 의해 전해 마그네슘을 얻고자 하였다. 흑연양극의 침지깊이를 일정하게 하고 전해전압 7V로 두가지 조성의 염욕을 비교 실험하였다. $760^{\circ}C$에서 전해 실험한 결과 $KCl/NaCl/MgCl_2$ 혼합염욕이 $KCl/NaCl/CaCl_2/CaF_2/MgCl_2$ 혼합염욕보다 전류효율 면에서 더 효과적이었다. 회수된 전해 마그네슘의 순도는 98% 이상이었다. 본 연구를 통하여 용융염 전해장치를 Scale-up 하거나 상용화시 장치설계 등에 필요한 기초자료들을 축적할 수 있었다.

• 대한화학회지
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• 제40권2호
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• pp.148-151
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• 1996

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2003년도 춘계학술강연 및 발표대회
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• pp.54-55
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• 2003

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2017년도 춘계학술논문요약집
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• pp.83-83
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• 2017

Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. The solid cathode processing is necessary to separate the salt from the cathode since the uranium deposit in a solid cathode contains electrolyte salt. Distillation process was employed for the cathode processing. It is very important to increase the throughput of the salt separation system due to the high uranium content of spent nuclear fuel and high salt fraction of uranium dendrites. In this study, a mesh-covered crucible was investigated for the sat distillation of electrorefiner uranium deposits. A liquid salt separation step and a vacuum distillation step were combined for salt separation. The adhered salt in uranium deposits was efficiently removed in the mesh-covered crucible. The salt distiller was operated simply since repeated cooling - heating step was not necessary for the change of the crucible. The operation time could be reduced by the use of the mesh-covered crucible and the combined operation of the two steps. A method to preserve a vacuum level was proposed by double O-rings during the operation of the distiller with the mesh-covered crucible. After the salt distillation, the salt content was measured and was below 0.1wt% after the salt distillation. The residual salt after the salt distillation can be removed further during melting of uranium metal.

• 한국주조공학회지
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• 제20권1호
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• pp.38-45
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• 2000

The remelting for recycling or thin aluminum scrap, such as aluminum chip generally involves melting of these pieces submerged in molten salt flux. In this study, the effects of salt flux compositions and alloying elements on the aluminum dropletscoalescence and oxide film removal were studied in 99.8%Al, Al-1.01%Cu, Al-1.03%Si, and Al-1.38%Mg alloys as a function of holding time at $740^{\circ}C$ Salt fluxes based on NaCl-KCl(1:1) with addition of 5wt.% fluorides(NaF, $Na_3AlF_6$, $CaF_2$) or 5 wt.% chloride($MgCl_2$, $AlCl_3$) were used. The experimental results show that NaCl-KCl(1:1) with addition of 5 wt.% fluorides exhibits better coalescence ability than that with chlorides. The oxide film is not removed by NaCl-KCl(1:1) with addition of 5 wt.%chlorides, while it is removed by NaCl-KCl(1:1) with addition of 5 wt.% fluorides. The aluminum droplets coalescence and oxide film removal by salt fluxes are related to interfacial tension tension between metal and salt flux.

• 한국응용과학기술학회지
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• 제13권2호
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• pp.85-92
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• 1996

Chitosan itself has been prepared using chitin, one of the most abundant compounds in nature, as a starting material. We have synthesized the water-soluble chitosan derivative, N-dithiocarboxy chitosan sodium salt, through the reaction of water-soluble chitosan with carbon disulfide in the presence of alkali metal hydroxide. To elucidate this natural polymer capacity of adsorbing heavy metal ions, we have performed adsorption experiments using the water-soluble chitosan derivative various average molecular weight and of different percent contents of sulfur. The effect of pH, adsorption time and temperature on adsorption efficiency was also studied. The adsorbent derived from water-soluble chitosan of average molecular weight ranging $9,000{\sim}120,000$ was shown to have the highest capacity of adsorbing heavy metal ions. On the whole, adsorbing efficiency was increased as the reaction time goes longer and also increased as the reaction temperture goes higer in temperture range of $15^{\circ}C{\sim}45^{\circ}C$. The adsorption capacity at various pH, however, was appeared to vary depending on the heavy metal ions studied Judging from these finding, water-soluble N-dithiocarboxy chitosan sodium salt, a derivative of a biodegradable nature polymer, is believed to be a potential adsorbent for heavy metal ions since it not only is shown to lower the concentration of heavy metal ions to below the drainage quality standard, but also it would not cause acidification and hardening of soil which is one of the detrimental effects of synthetic macromolecular adsorbents present.

• 방사성폐기물학회지
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• 제16권2호
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• pp.165-172
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• 2018

용융염-액체금속 추출공정에서 형성되는 액적 크기를 추정하는 방안으로 용융염-액체금속 계를 상온에서 유사한 물-수은 계로 대체하여 액적 형성 실험을 노즐의 종류에 따라 수행하여 Scheele-Meister 모델의 적용성을 평가하였다. 실험에서 액적의 크기 측정은 디지털카메라와 이미지분석 소프트웨어를 사용하였으며 노즐은 0.018 cm과 0.025 cm의 구멍 크기를 가지며 수은의 통과 길이가 1.3 cm인 상용 니들과 두께가 0.5 cm이며 0.0148 cm 구멍 2개, 0.0135 cm 구멍 3개, 0.0135 cm 구멍 4개인 것을 제작하여 사용하였다. 각각의 노즐에서 형성된 액적은 노즐 아래 20 cm까지 안정적인 구형을 유지하였다. 액적 크기의 측정치를 Scheele-Meister 모델의 추정치와 비교하였을 때 10% 오차 범위 안에서 일치하였다. 실험 결과는 물-수은 계에서 액적을 안정적으로 형성시키는 노즐에 대해 액적 크기 추정을 위한 Scheele-Meister 모델이 적용될 수 있음을 보였다.