• 전기학회논문지
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• 제59권12호
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• pp.2235-2239
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• 2010

In this study, The cation exchange membrane and the anion exchange membrane affect in electrical conduction of metal fuel cell was investigated. Magnesium material as anode electrode and the NaCl solution dissolved with 5~15wt% as electrolyte were used for the metal fuel cell. It was found that magnesium slag where flows toward the air electrode was suppressed by using ion exchange membrane. The open circuit voltage variation during discharge has very flat pattern by using ion exchange membrane, but the case which is not the exchange membrane, the open circuit voltage increased according to time. When using the anion exchange membrane, the electric current was higher case of the cation exchange membrane, as a result of higher equivalent conductivity in anion Cl-. The cation exchange membrane was observed with the fact that the output power is excellent in compared with anion exchange membrane.

• 한국산업융합학회 논문집
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• 제4권1호
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• pp.61-69
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• 2001

Polycarbonate(PC) membranes for oxygen enrichment from air were prepared by the wet phase inversion method. In order to improve oxygen separation performances of the PC membrane, the effect of the added ethanol(nonsolvent) and $CuCl_2$(metal salt) concentration in the casting solution on morphology, oxygen permeability ami $O_2/N_2$ separation factor of the membrane was studied. In addition, tensile strength and elongation at break of the membrane were investigated. An asymmetric membrane with a dense top layer and a porous sublayer was obtained. The thickness of the dense top layer decreased with increasing amount of nonsolvent additive. Compared with pure PC membrane without additive(metal salt), the oxygen permeability and $O_2/N_2$ separation factor of the $PC/CuCl_2$ membrane are significantly improved. The oxygen permeability and $O_2/N_2$ separation factor is $5.25{\times}10^{-9}cm^3(STP){\cdot}cm/cm^2{\cdot}sec{\cdot}cmHg$ and 4.5, respectively. This improvement might be due to good interaction between metal salt and oxygen.

• Elastomers and Composites
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• 제30권3호
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• pp.229-234
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• 1995

Membrane process has been applied widely to petroleum chemistry, fine chemistry, polymer, electronics, food, bioprocessing, and wastewater treatment process. Membrane process has advantage that there's no phase change through separation, energy consumption is smaller than other separation processes. And equipment investment and operation cost are inxpensive too. We prepared the silicone rubber membrane and then separated the heavy metal ion from wastewater. Silicone rubber membrane was prepared using a superitical fluid process and heavy metal ions were separated from the chromium nitrate, ferric sulfate, cupric sulfate, nickel sulfate aqueous solution. The pressure difference between top and bottom of separation apparatus was preserved by vacuum pump, and the removal amount of heavy metal at each separation step were analyzed by instrumental analysis, AAS. The surface and pore of silicone rubber membrane was investigated using SEM, and the capability of wastewater treatment using a silicone rubber membrane was proposed as calculated removal rate of heavy metal after comparing removal amount of heavy metal to amount of heavy metal in mother solution by AAS analysis.

• 상하수도학회지
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• 제29권2호
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• pp.251-259
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• 2015

The main objective of this research is to study feasibility for applying metal membrane to remove particles from air scouring membrane backwash water. Also, the research was conducted to investigate the influence of polyamine coagulation on floc growth in membrane backwash water as pretreatment for removal particles. From the results of experiments for evaluating the influence of polyamine coagulation on floc growth, it was investigated that particles in the rage of $2{\sim}50{\mu}m$ grew up to $30{\sim}5,000{\mu}m$. In addition, all six metal membranes showed lower removal efficiency, which was 0.87~13.89%, in the case of no polyamine coagulant. On the other hand, in the case of injecting polyamine coagulant, those did extremely high efficiency in 56~92%. From the SEM(Scanning Electron Microscope) images of filtered wiremesh and metal foam membrane, sieve effects were predominant for liquid solid separation in wiremesh and adsorption and diffusion capture effects were predominant in metal foam membrane.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.312-313
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• 2006

The primary aim pursued by the preparation of separation membrane is the preparation of the membrane thin as well as with no defect. The field-flow fractionation deposition is a new molding technology which can overcome the traditional disadvantages such as multi-preparation to the preparation of great area of separation membrane with no defect. Therefor the mainly ingredients which influence the appearance and performance of titanium membrane layer are investigated by scanning electricity mirror (SEM) as well as porous material testing instrument: powder performance prepared and confected; selection of supporting body; sintering system such as temperature and time. It is shown that the membrane thickness can be controlled at $50{\mu}m$ or so; the filtration precision mainly rests with powder performance and selection of supporting body and little sintering system

• Korean Membrane Journal
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• 제7권1호
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• pp.67-70
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• 2005

It is well known as the role of ion exchange membrane with functional group in membrane matrix. Recently, we were reported that the charged mosaic membrane within parallel array of negative and positive charge groups. In this study we are reported the properties for the various transport coefficients of metal and heavy metal ions across charged mosaic membrane based on non-equilibrium thermodynamics is not based on equilibrium state.

• 한국분말재료학회지
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• 제27권1호
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• pp.63-71
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• 2020

It is necessary to fabricate uniformly dispersed nanoscale catalyst materials with high activity and long-term stability for polymer electrolyte membrane fuel cells with excellent electrochemical characteristics of the oxygen reduction reaction and hydrogen oxidation reaction. Platinum is known as the best noble metal catalyst for polymer electrolyte membrane fuel cells because of its excellent catalytic activity. However, given that Pt is expensive, considerable efforts have been made to reduce the amount of Pt loading for both anode and cathode catalysts. Meanwhile, the atomic layer deposition (ALD) method shows excellent uniformity and precise particle size controllability over the three-dimensional structure. The research progress on noble metal ALD, such as Pt, Ru, Pd, and various metal alloys, is presented in this review. ALD technology enables the development of polymer electrolyte membrane fuel cells with excellent reactivity and durability.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2005년도 춘계학술대회 논문집
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• pp.229-232
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• 2005

This paper presents the design and fabrication of backflow prevented Micropump using the metal membrane. The Micropump is consisted of the lower plate, metal membrane, upper plate and the piezoelectric-element. The lower plate includes the micro channel and the inlet, outlet of the Micropump. The upper plate includes the micro channel and connects the piezoelectric-element. These plate are fabricated on the Pyrex glass wafer by sandblasting process. The metal membrane does roll of check valve that is prevented backflow of the Micropump. The metal membrane is fabricated on the stainless steel by laser machining. Piezoelectric-element is actuated the Micropump and controlled flowing of fluid. The Micropump is fabricated by bonding process of these multi-layer.

• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 추계 총회 및 학술발표회
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• pp.96-101
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• 2005

A theory for the material transports through ion exchange membrane has been developed on the basis of nonequilibrium thermodynamics by removing the assumption of solvent flow in the previous paper and applied to a detailed study of the ionic transport properties of new charged mosaic membrane(CMM) system. The CMM having two different fixed charges in the polymer membrane indicated unique selective transport behavior then ion-exchange membrane. The separation behavior of ion transport across the CMM with a parallel array of positive and negative functional charges were investigated. It was well-known the analysis of the volume flux and solute flux based on nonequilibrium thermodynamics. Our suggests preferential salt transport across the charged mosaic membranes. Transport properties of heavy metal ions, $Mg^{2+}$, $Mn^{2+}$and sucrose system across the charged mosaic membrane were estimated. As a result, we were known metal salts transport depended largely on the CMM. The reflection coefficient indicated the negative value that suggested preferential material transport and was independent of charged mosaic membrane thickness.

• 공업화학
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• 제4권2호
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• pp.416-422
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• 1993

성능이 우수한 킬레이트막을 개발하고자 chitosan에 글루타르알데히드를 가교시켜 막을 제조하였으며, 이 막을 통한 금속 이온의 투과 특성을 조사하였다. 막을 통한 이온의 투과는 downstream 용액의 pH의 영향을 크게 받았으며, 이 현산에 대하여 proton pump 메카니즘을 제안하였다. 막 표면에서의 착물형상에 의한 선택흡착성이 선택투과성에 영향을 미친다고 생각되며, $Mg^{2+}$과 $Cu^{2+}$의 혼합 용액에서 $Cu^{2+}$의 선택도는 9.5이었다.