• Title/Summary/Keyword: metal electrode

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Analysis of Arc Tube Properties by Degradation in Ceramic Metal Halide Lamp

  • Yang, Jong-Kyung;Jang, Hyeok-Jin;Park, Dae-Hee
    • Journal of Electrical Engineering and Technology
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    • v.6 no.1
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    • pp.123-127
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    • 2011
  • To clarify the relations of optical properties to the main factors responsible for the loss and damage of luminous efficacy, a 20 min turn-on/turn-off test for 2,000 h for a ceramic metal halide lamp is conducted. The corrosion rates of the arc tube wall and electrode are estimated based on thermal stress. Wall blackening is attributed to the tungsten being transported from the hot electrode tips to the relatively cold arc tube wall. Furthermore, the grain boundaries of the arc tube are changed by the degradation. Distortion of the electrode is observed, and the ignition and the driving voltage of the load both increase. Finally, the color rendering index and the color coordinates are changed after the degradation. The luminous flux and the intensity of the luminous distribution are decreased significantly.

Preparation of nano composite metal-oxide electrode and its application for superrcapacitor (나노복합산화물 전극의 제조 및 수퍼커패시터로써의 응용)

  • Kim, Hong-Il;Lee, Ju-Won;Kim, Sang-Gil;Yuk, Gyung-Chang;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.801-804
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    • 2002
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. Both of amorphous cobalt oxide and manganese dioxide were prepared by sol-gel process reported in our previous work. Nanostructured supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) coated metal oxides were successfully prepared by electrochemical oxidation from an acidic non-aqueous medium. We established process parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured metal oxide electrodes using controlled solution chemistry. $CoO_2$ and $MnO_2$-based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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Electrocatalytic Properties of Metal-dispersed Carbon Paste Electrodes for Reagentless L-lactate Biosensors (금속이 첨가된 탄소전극의 전기화학적 특성과 이를 이용한 L-lactate 바이오센서의 개발)

  • 윤현철;김학성
    • KSBB Journal
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    • v.11 no.4
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    • pp.489-496
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    • 1996
  • Metal dispersed carbon paste electrodes were fabricated, and their electrochemical properties were investigated. Among various metal dispersed carbons, platinum-dispersed carbon paste electrode showed most efficient electrocatalytic characteristics. The overpotential for the oxidation of NADH was significantly lowered in the platinum-dispersed carbon paste electrode, and catalytic current was also enhanced. Based on these electrocatalytic observations, L-lactate biosensor using L-lactate dehydrogenase was constructed to evaluate its performance in terms of sensitivity and stability.

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Characterization of Ionic-Polymer Metal Composite Actuators Varying Electroless Plating Method of Platinum (백금 무전해 도금 방법의 변화에 따른 이온성 고분자 및 금속 복합체 액추에이터의 특성 분석)

  • 차승은;김병목;조성환;이승기;박정호;김병규
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.12
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    • pp.601-607
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    • 2002
  • IPMC(Ionic Polymer Metal Composite)actuators were optimized for producing improved forces by changing multiple parameters including repetition of number of plating, surface electroding and additive(PVP)-treatment on reduction. The platinum electrode is deposited on the surface of the material where platinum particle stay in a dense form that appears to introduce a significant level of surface electrode resistance. Actuation tests were performed for such IPMC actuators under a low voltage. The test results show that the lower surface-electrode resistance generates higher actuation capability in the IPMC actuators. In order to investigate relaxation behavior of bending and repeatability in dry condition, the IPMC was coated by$rubber(KRATON^{TM})$to minimize the effect of water evaporation from IPMC. This actuator can be used in air with surface coating to avoid membrane drying.

Electrochemical Properties of Novel Metal Powder Electrodes for Polymer Electrolyte Membrane Electrolysis

  • Kim, Chang-Hee;Kang, Kyung-Soo;Park, Chu-Sik;Hwang, Gab-Jin;Bae, Ki-Kwang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1227-1228
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    • 2006
  • The electrochemical properties of novel metal powders were investigated for the electrode materias of polymer electrolyte memebrane electrolysis. Two types of Pt black and $IrO_2$ powder electrodes were hot-pressed on the polymer electrolyte membrane to form membrane electrode assembly. The galvanodynamic polarization methode was used to characterize the electrochemical properties of both electrodes. From the experimental results, we concluded that the $IrO_2$ powder electrode exhibits better electrochemical performance than Pt black as cathode material for the electrolysis.

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The conductive characteristic of oil-immersed paper (유침절연지의 도전특성)

  • 성영권;이헌용
    • 전기의세계
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    • v.25 no.2
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    • pp.87-91
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    • 1976
  • Experimentally to investigate the conductive characteristic of oil-immersed paper, we observed the leakage current-voltage characteristic of oil-immersed paper, the temperature dependence of ionization rate and the effect of metal electrode on the leakage current. The results showed that the leakage current-voltage characteristic generally followed the experimental equation i=i$_{0}$ exp (K.root.E) and the slope K did not change by the temperature and electric strength, but only when the direct voltage was applied. And also the leakage current seemed to depend on the work function of metal electrode. From the above results we concluded that the deterioration of oil-immersed paper was not only caused by the thermionic emission from the cathode but also by the conductive property of oil-immersed paper in itself and the work function of metal electrode.e.

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Pulsed Amperometric Detection of Metal Ions Complexing with EDTA in a Flow Injection System

  • 이준우;여인형;편종홍
    • Bulletin of the Korean Chemical Society
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    • v.18 no.3
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    • pp.316-318
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    • 1997
  • A general and universal detection method, which can be used in high performance liquid chromatography (HPLC) and flow injection analysis (FIA) system for the determination of any metal ions complexing with ethylenediaminetetraacetic acid (EDTA), is demonstrated. Pulsed amperometric detection scheme is applied in a flow-through thin layer electrochemical cell at an Au working electrode. Fluctuation of peak current level at the same flow rate of carrier solution is minimized at this solid working electrode, whereas not at a dropping mercury electrode. Removal of dissolved oxygen can be omitted with this detection method, which is a required step for cathodic detection methods. Also, a group of metal ions can be determined selectively and indirectly with this detection scheme.

A Study on the Preparation of the Silver Selenide Electrode and Its Properties (Silver Selenide 전극의 제조 및 그 특성에 관한 연구)

  • Gwon-Shik Ihn;Tae-Won Min;Soo-Hyung Lee
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.280-289
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    • 1976
  • The silver selenide electrode has been prepared and its properties as an indicating electrode for silver ion have been investigated. Epoxy resin was used as a filler of silver selenide electrode. Silver metal plate was directly connected with the membrane of the electrode and the silver paste was used as its binder. The sintered electrode was more sensitive and stable than the pressed electrode, and the silver selenide electrode more sensitive than the silver sulfide electrode to silver ion. The linear relationship between the electrode potential and logarithmic concentration of silver ion has been observed down to 10-6 M for the electrode. Several heavy metal ions except mercuric ion did not interfere this linearity, but halide, cyanide, and thiocyanate ions did intensively interfere owing to the formation of silver compounds and complexes. This electrode has been applied to the potentiometric titration for determining halide ion. It is concluded that interferences from ,$CN^-, SCN^-, S^-, I^-, Br^-, Cl^- and Hg^{2+}$ ions are detrimental to the practical use of the electrodes for measuring pAg.

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A Study on the Electrode Effect of As-Te-Si-Ge Non-Crystalline Thin film Switching Devices (As-Te-Si-Ge 비정질박막 스위칭 소자의 전극영향에 관한 연구)

  • 박창엽;정홍배
    • 전기의세계
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    • v.25 no.1
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    • pp.104-107
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    • 1976
  • The switching characteristics of Non-crystalline As-Te-Si-Ge thin film device using Ag, In and Al metal for electrode, has been investigated. Threshold voltage and holding current of each sandwich type device varied due the to formation of the potential barrier in between non crystalline solid and electrode interface.

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Study of the Carrier Injection Barrier by Tuning Graphene Electrode Work Function for Organic Light Emitting Diodes OLED (일함수 변화를 통한 그래핀 전극의 배리어 튜닝하기)

  • Kim, Ji-Hun;Maeng, Min-Jae;Hong, Jong-Am;Hwang, Ju-Hyeon;Choe, Hong-Gyu;Mun, Je-Hyeon;Lee, Jeong-Ik;Jeong, Dae-Yul;Choe, Seong-Yul;Park, Yong-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.111.2-111.2
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    • 2015
  • Typical electrodes (metal or indium tin oxide (ITO)), which were used in conventional organic light emitting devices (OLEDs) structure, have transparency and conductivity, but, it is not suitable as the electrode of the flexible OLEDs (f-OLEDs) due to its brittle property. Although Graphene is the most well-known alternative material for conventional electrode because of present electrode properties as well as flexibility, its carrier injection barrier is comparatively high to use as electrode. In this work, we performed plasma treatment on the graphene surface and alkali metal doping in the organic materials to study for its possibility as anode and cathode, respectively. By using Ultraviolet Photoemission Spectroscopy (UPS), we investigated the interfaces of modified graphene. The plasma treatment is generated by various gas types such as O2 and Ar, to increase the work function of the graphene film. Also, for co-deposition of organic film to do alkali metal doping, we used three different organic materials which are BMPYPB (1,3-Bis(3,5-di-pyrid-3-yl-phenyl)benzene), TMPYPB (1,3,5-Tri[(3-pyridyl)-phen-3-yl]benzene), and 3TPYMB (Tris(2,4,6-trimethyl-3-(pyridin-3-yl)phenyl)borane)). They are well known for ETL materials in OLEDs. From these results, we found that graphene work function can be tuned to overcome the weakness of graphene induced carrier injection barrier, when the interface was treated with plasma (alkali metal) through the value of hole (electron) injection barrier is reduced about 1 eV.

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