• 한국산학기술학회논문지
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• 제15권1호
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• pp.39-46
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• 2014

미얀마 Kayah산 녹색 투어말린의 특성을 X-선 형광분석, 자외선-가시광선 그리고 중적외선 분광분석을 통하여 타산지의 녹색 투어말린과 비교하였다. 화학성분 분류에 의해 미얀마 투어말린이 속한 그룹을 조사 하였다. 미얀마 투어말린은 V 원소를 많이 함유하고 있었고 X 사이트에 Ca 원소를 반 이상 함유한 Calcic 그룹에 속했고 우바이트 (Uvite)로 명명되었다. 자외선-가시광선 분석결과 $V^{3+}$ 이온에 의한 415와 611 nm에 강한 흡수밴드가 나타나 녹색 투어말린의 원인이 되었다. $Fe^{2+}$ 이나 $Cu^{2+}$ 이온에 의해 녹색이 나타나는 타산지의 녹색 투어말린과 차이가 있었다. 중적외선 분석에서는 수산기와 금속들 간의 진동에 의한 흡수가 일어났는데 1100 $cm^{-1}$ 근처에서 스트레칭 모드, 3500 $cm^{-1}$ 주변에서 벤딩 모드 그리고 4600과 4200 $cm^{-1}$ 사이에서 스트레칭과 벤딩 모드의 혼합 밴드가 나타났다.

• 자원환경지질
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• 제29권2호
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• pp.139-150
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• 1996

The Yucheon Bi deposits at Cheongha, Gyeongsangbugdo, is of a middle Paleogene (49 Ma) vein type, and is hosted in sandstone and shale of Banyawal formation in Cretaceous age. Based on mineral paragenesis, vein structure and mineral assemblages, two minera1ization stages were distinguished. The stage I consists of quartz with small amount of chlorite, pyrite, epidote, hal1oysite, vermiculite, serpentine and rutile associated with sericitization. The stage II is characterized by Bi minera1ization such as bismuthinite, Bi-Cu-Pb-S mineral, tetradymite, native gold, pyrite, pyrrhotite, arsenopyrite, wolframite, rutile, hematite, sphalerite, chalcopyrite, galena with alteration of sericite, chlorite, K-feldspar, albite and epidote. Fluid inclusion data indicate that fluid temperature and NaCl equivalent wt.% salinity range from 431 to $150^{\circ}C$ and from 19.2 to 0.18wt.% in the stage II. Evidence of boiling during the base-metal minera1ization indicates pressures 241 to 260 bars. Sulfur fugacity($-log\;f_{S2}$) deduced by mineral assemblages and compositions ranges from 5.1 to 5.7atm in early stage, from > 8.4 atm in middle stage and from 13.5 to 19.3 atm in late stage. It suggests that complex histories of progressive coo1ing, dilution and boiling were occurred by the mixing of the fluids. The ${\delta}^{34}S$, ${\delta}^{18}O$ and ${\delta}D$ data range from 2.5 to 3.9%, -0.5 to -4.1% and -29.7 to -47%, respectively. It indicated that hydrothermal fluids may be magmatic origin with boiling and mixing of meteoric water increasing paragenetic time.

• 한국광물학회지
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• 제19권3호
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• pp.139-151
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• 2006

캐나다 온타리오주 코발트지역에는 시생대의 화산암을 부정합으로 피복하고 있는 원생대의 휴로니안 퇴적암 내에는 황화물이 농집된 광화작용이 발달한다. 황화광물들은 원생대에 발달했던 퇴적분지에 쌓인 기저역암 내에 농집되어 있다. 황화광물은 기저역암과 Coleman 역암에서는 파편형태로, 퇴적암 전체에서는 광범위한 산점상 형태, 그리고 Ag-Co-Ni-As 탄산염맥 주변의 산점상 형태 등으로 산출된다. 황화광물 파편들의 형태가 모가 나있고 사암과 이질암에서 점이적 퇴적구조를 나타내고 있는 것으로 보아 황화광물들이 기계적 운반작용에 의해 이동된 후 퇴적암 내에서 광화작용을 이루었음으로 시사한다. 한편, 탄산염맥 근처에서 발견되는 산점상 광석광물들은 열수작용에 의해 형성된 것으로 추정된다. 기반암인 시생대 화산암에 발달한 대규모의 화산성 황화물 광상이 퇴적암에 존재하는 광석광물의 공급원이었음을 알 수 있다. 사암 및 이질암에 존재하던 광석광물들은 후기에 관입한 휘록암에 수반된 열에 의해 재결정작용을 받았다.

• 자원환경지질
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• 제26권4호
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• pp.445-454
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• 1993

The Keumseongsan caldera is composed of the Cretaceous sedimentary rocks of the Gyeonesang Supergroup, volcanic rocks of the Yucheon Group and basic dykes. The Keumseongsan caldera is formed by subsidence of volcanic rocks, and arc fault developed late. Also, synistral strike-slip fault ($N60^{\circ}W$) developed. Volcanic rocks belong to subalkaline rocks and calcalkaline magma series. First tuffaceous breccia erupted before 71.4 Ma and cavity of magma chamber caused subsidence, which formed arc fault. Basaltic lava erupted at 71.4 Ma and residual fluids containing Fe, As, Pb, Zn and Cu metal elements built the Ohto deposits, which are dated to be 70.5 Ma based on K-Ar age for sericite. Tuffaceous breccia and tuff erupted between 70.5 and 67 Ma. When volcanic eruption became weakened, cavity in site of magma chamber brought subsidence. Rhyolite intruded and erupted at 67 Ma, and intrusive rhyolite intruded according to arc faults, also. Hydrothermal fluids containing Fe, As, Pb, Zn, Cu, Sb, Bi, Au and Ag formed the Tohyeon deposits. K-Ar age for sericite from the Tohyeon mine gives 66.0 Ma. Results of field exploration, geochemical analyses of volcanic rocks support mineralization possibility by volcanism. Especially, age of volcanism and mineralization are well in coincidence with results of K-Ar age dating. By these results, Ohto Cu mineralization is regarded to be associcated with basaltic rocks, while Tohyeon Cu mineralization with rhyolitic rocks.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.581-589
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• 2003

The variable flotation response ores from different deposits results basically from mineralogical association and their differences. Development of new techniques for analyzing the metallurgical performance of flotation and other concentration processes is demanded even in the treatment of rather simple ores such as porphyry ores. Diagnostic metallurgical analysis can be used to quantify the most possible recovery processes. Several porphyry copper/gold ores around the world were used to examine the responses in flotation, gravity separation and cyanidation in order to define the linkage between the recovery processes for both copper and old values. Laboratory batch flotation, gravity separation and cyanidation tests were carried out on these samples. All results were used to correlate the relative recovery of copper and gold, and to predict the highest possible metal recovery in the system. The metallurgical predictions were made according to the flotation conditions used and gravity separation. The results of various concentration processes on each porphyry ore samples are presented and discussed. All seven samples have shown significantly different gold/copper metallurgy. The grade/recovery relationships of gold and copper in the laboratory batch tests for the best results and the plants are given in the Figures below. The results of laboratory tests show that the copper recoveries converged to about $90\%$, but the gold recoveries were spread over $55-80\%$, except the K S ore. Series of standard cyanidation tests on the flotation concentrate samples and gravity separation using Knelson Separator on heads ores were carried out to cross-link the metallurgy and mineralogy of gold in the porphyry ores.

• 분석과학
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• 제37권1호
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• pp.47-62
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• 2024

Abu Gurdi area is located in the South-eastern Desert of Egypt which considered as volcanic massive sulfide deposits (VMS). The present work aims at investigating the ore mineralogy of Abu Gurdi region in addition to the effectiveness of the hydrometallurgical route for processing these ores using alkaline leaching for the extraction of Zn, Cu, and Pb in the presence of hydrogen peroxide, has been investigated. The factors affecting the efficiency of the alkaline leaching of the used ore including the reagent composition, reagent concentration, leaching temperature, leaching time, and Solid /Liquid ratio, have been investigated. It was noted that the sulfide mineralization consists mainly of chalcopyrite, sphalerite, pyrite, galena and bornite. Gold is detected as rare, disseminated crystals within the gangue minerals. Under supergene conditions, secondary copper minerals (covellite, malachite, chrysocolla and atacamite) were formed. The maximum dissolution efficiencies of Cu, Zn, and Pb at the optimum leaching conditions i.e., 250 g/L NaCO₃ - NaHCO₃ alkali concentration, for 3 hr., at 250 ℃, and 1/5 Solid/liquid (S/L) ratio, were 99.48 %, 96.70 % and 99.11 %, respectively. An apparent activation energy for Zn, Cu and Pb dissolution were 21.599, 21.779 and 23.761 kJ.mol^-1, respectively, which were between those of a typical diffusion-controlled process and a chemical reaction-controlled process. Hence, the diffusion of the solid product layer contributed more than the chemical reaction to control the rate of the leaching process. High pure Cu(OH)₂, Pb(OH)₂, and ZnCl₂ were obtained from the finally obtained leach liquor at the optimum leaching conditions by precipitation at different pH. Finally, highly pure Au metal was separated from the mineralized massive sulfide via using adsorption method.

• 자원환경지질
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• 제23권2호
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• pp.183-199
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• 1990

Ore deposits of Dongwon mine are composed of numerous gold and silver veins emplaced in sedimentary rocks of Cambrian Choseon Supergroup and granitoids of Cretaceous age. Ore veins of the mine can be divided into gold and silver veins on the base of vein structure, mineral assemblage and vein trends. Mutual relationships between gold and silver veins are uncertain. Gold veins are simple veins which are composed of base-metal sulfides, and electrum with quartz and ankerite. On the other hand, silver veins are complex veins which reveal three distinct stages of mineral deposition based on vein structure; stage I, deposition of small amounts of oxides and pyrite with quartz; stage II, deposition of base-metal sulfides, small amounts of Ag-bearing minerals, calcite and quartz; stage III, deposition of base metal sulfides, electrum, Ag-sulfosalts, native silver, carbonates and quartz. Homogenization temperature and salinity of fluid inclusion from quartz of gold vein are as follows; $229^{\circ}$ to $283^{\circ}C$, 4.7 to 6.4 wt.% equivalent NaCI. The ore mineralogy suggests that temperature(T) and sulfur fugacity($fs_2$) of the formation of the gold vein and stage III of silver vein are estimated as T ; $294^{\circ}$ to $318^{\circ}C$, $fs_2\;10^{-9.4}$ to $10^{-10.1}$ atm. and T; $240^{\circ}$ to $279^{\circ}C$, $fs_2;10^{-11.1}$ to $10^{-17.3}$ atm. respectively. Pressure condition during gold vein formation estimated from data of ore mineralogy and fluid inclusion range 500 to 750 bar.

• 자원환경지질
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• 제29권5호
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• pp.597-613
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• 1996

The tonnage of copper and tungsten produced at Dalseong mine by Taehan Tungsten Mining Company from 1961 to 1971 was 48,704 tons (M/T) of 4 wt.% Cu and 1,620 tons (S/T) of 70wt.% WO, but the mine was closed in 1974. Kyeongsan mine is a small abandoned cobalt mine with no data of production. To investigate the pollution level of the mine areas, soils, plants (Ohwi and Pampanini), stream waters and stream sediments were taken and Fe, Mn, Cu, Pb, Zn, Ni, Co, Cd and Cr were analysed by ICP. Soils are considerably contaminated by the heavy metals related to ore deposits, The heavy metal contents in plants vary with the species and parts of plants. Stream waters are anomalously high in heavy metals in the vicinity of the mines but the contents decrease downstream in the process of dilution and precipiation. However, heavy metal contents increase very high in stream sediments due to precipiation. To protect environmental damages caused by acid mine drainages wetlands must be constructed outside pits, and it is necessary to fill pits with waters, limestone chips and organic materials, which give reducing and alkaline condition to ores. Under the condition pyrite is protected from oxidation and aqueous iron sulphates precipitate to form stable secondary pyrite.

• 폴리머
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• 제24권1호
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• pp.1-7
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• 2000

방사선 전조사법을 이용하여 아크릴산을 ACF/PP 흔성 부직포에 그라프트 반응시켜 ACF/PP-g-AAc 공중합체를 합성하였다. 합성한 공황합체의 FT-IR 결과 1720, 3600~3100$cm^{-1}$ / 부근에서 C=O, -OH에 대한 피크가 확인되었고, 금속이온 흡착후에 공중합체의 표면은 좁쌀알 등과 같은 작은 조직이 관찰되었다. ACF/PP-g-AAc 공중합체의 금속이온에 대한 흡착능의 최적시간은 24시간이었으며 동일 조건하에서의 흡착능은 $Mn^{2+}$>Cu$^{2+}$>Co$^{2+}$>Ni$^{2+}$의 순서로 $Mn^{2+}$가 최대흡착능을 나타냄으로써 흔합용액에서 금속이온의 흡착에 대한 선택성은 이온반경의 크기에 비례하는 경향을 나타내었으며, 또한 ACF/PP-g-AAc 공중합체는 10회 이상 흡착능의 변화없이 흡탈착이 가능한 흡착제임을 알 수 있었다.

• 자원환경지질
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• 제21권3호
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• pp.257-268
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• 1988

The Mugeug gold deposits is consisted of more than fourteen gold and silver-bearing quartz veins emplaced in Mesozoic granodiorite mass. In the Samhyungje vein, one of the representative vein in the mine, six stages of mineralizatidns are recognized: Stage I, deposition of base-metal sulfides and gray quartz; stage II, deposition of base-metal sulfides, electrum and white quartz with pinkish tint; stage m, deposition of base-metal sulfides and dark gray quartz; stage N, deposition of native silver, argentite, Ag-tetrahedrite, polybasite, arsenpolybasite and quartz; stage V, deposition of nearly barren quartz; stage VI, deposition of transparent quartz veinlets with minor pyrite. Ag contents of electrum increase steadily from stage II to stage N; 57.25-61.44 atom. % for stage II, 62.85-69.66 atom. % for stage m, 69.79-74.12 atom. % for stage N. Homogenization temperatures of fluid inclusions are as follows; stage II, from $194^{\circ}$ to $287^{\circ}C$; stage V, from $137^{\circ}$ to $171^{\circ}C$, stage VI, from $192^{\circ}$ to $232^{\circ}C$. Salinities of fluid inclusions range from 3.7 to 7.9 wt.% equivalent NaCl in stage II and from 0.8 to 4.3 wt.% equivalent Nael in stage V. Ore mineralogy suggest that temperature and sulfur fugacity declined steadily from $290^{\circ}$ to $150^{\circ}C$ and from $10^{-10.5}$ to $10^{-19.0}$atm. through stage II into stage N. Fluid pressure during stage II inferred from data of mineral assemblages and fluid inclusions is 370bar.