• 제목/요약/키워드: metal content

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금속 Ca증기에 의한 고체 Nd 금속의 탈산 (Deoxidation of Solid Nd Metal by the Metal Calcium Vapour)

  • 최영진;김상욱;전병서;송창빈;오윤석;이영주
    • 한국재료학회지
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    • 제27권5호
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    • pp.237-241
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    • 2017
  • As a basic study for the removal of oxygen in solid Nd metal by metal Ca vapour, by using the thermodynamic data such as ${\Delta}G-T$ diagrams and Nd-O and Nd-Ca equilibrium diagrams, the amount of residual oxygen in solid Nd metal formed based on deoxidation reaction by Ca vapour, instead of by direct contact of solid Nd metal and Ca solution, was determined. Deoxidation experiments were carried out for solid Nd metal in a temperature range of $890{\sim}970^{\circ}C$ for 1h to 4h and content of addition Ca of 0.6~1.8 g (5~15 wt% of solid Nd metal). As a result, it was found that as deoxidation temperature increased, dissolved oxygen decreased. Especially, it was observed that a small amount of Nd-Ca alloy liquid was formed on the surface of the solid Nd metal sample deoxidized at $970^{\circ}C$ for approximately 1 hour. Also, it was found that if the content of addition Ca was 1.8 g (15 wt% of solid Nd metal) the amount of produced Nd-Ca alloy increased slightly. However, for the Nd sample with which the deoxidation reaction was performed at $930^{\circ}C$ for 4h with content of addition of Ca of 1.5 g (13 wt% of Nd metal), the residual oxygen was found to decreased to 12.00 ppm.

과일통조림 중에 함유된 중금속의 함량변화 (Changes of Heavy Metal Contents of Commercial Canned Fruits)

  • 위성언;김순희
    • 한국식품영양학회지
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    • 제6권4호
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    • pp.276-280
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    • 1993
  • Analytic data on the content of Pb and Sn from twenty five samples of fruit canned In the open market is as follows. The content of Pb and Sn from twenty five samples of fruit canned In the open market was less than Korean laws of food hygiene. The content of Pb and Sn increased In the long time of self life. In comparison with fruit flesh and nectar, nectar showed a tendency to less content.

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오스나이트계 및 이상계스테인레스강 용착부의 산소가 충격인성에 미치는 영향 (Effect of oxygen content on impact toughness of austenitic-and duplex stainless steel weld metal)

  • 문영훈;김환태;허성도
    • Journal of Welding and Joining
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    • 제5권3호
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    • pp.38-45
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    • 1987
  • An investigation was conducted to find out the factors influencing on the impact toughness of austenitic-and duplex stainless steel weld metal. Various welding process with commerically available consumables was adopted to get weld doposited metal. The oxygen content of each weld metal was very sensitiive to welding process, involving flux composition, shielding gas and structural features. The results of this study show tat the content of oxygen as an oxide inclusion significantly affects impact toughness, and .delta.-ferrite distribution is also correlated with resultant toughness value.

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금속피막에 의한 건축 마감 의장 기법 개발에 관한 연구 (Study on the Development of Finishing Design Methods for Building Structures Using the Metal Films)

  • 임지택;정화랑
    • 한국구조물진단유지관리공학회 논문집
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    • 제22권1호
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    • pp.183-189
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    • 2018
  • 본 연구에서는 용사기법에 의해 콘크리트 표면에 금속피막을 형성하는 새로운 마감 의장기법의 가능성을 검토하기 위하여, 콘크리트의 함수율 변화에 따른 금속피막의 부착성능에 대하여 실험적인 연구를 수행하였다. 그 결과, 선재의 색은 용사 후에도 변하지 않는 것을 알 있었고, 콘크리트 부착강도 기준인 2.5 MPa를 확보하기 위한 하지 콘크리트의 함수율을 10% 이하로 관리하면 금속피막의 부착강도눈 확보되는 것으로 판단된다. 또한, 콘크리트와 금속피막의 부착강도를 증진시키기 위해서는 표면강화제에 의한 콘크리트 표면강화와 함께 금속피막을 봉공처리제로 봉공하는 것이 매우 유효한 것을 알 수 있었다.

저농도 메탄 연소에서 상용 금속촉매의 활성 (Catalytic Activity of Commercial Metal Catalysts on the Combustion of Low-concentration Methane)

  • 이경환;박재현;송광섭
    • 한국대기환경학회지
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    • 제21권6호
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    • pp.625-630
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    • 2005
  • This study was focused on the catalytic activity for the combustion of low-concentration methane using various commerical catalysts (six transition metal catalysts in Russia and one rare earth metal (Honeycomb) catalyst in Korea). Catalytic activity was strongly influenced by the type and loading content of metal supported in catalyst. Catalytic performance showed the highest activity in Honeycomb catalyst including rare earth metal, which was the most expensive catalyst, while the next was the catalyst supported Cu with high content (AOK-78-52) and also that supported Cr and Co (AOK-78-56). However, both AOK-78-52 and AOK-78-56 catalysts that were very cheap had lower activation energy than Honeycomb catalyst. In the economical field, both AOK-78-52 and AOK-78-56 catalysts with transition metals showed a good alternative catalyst on the combustion of methane.

Establishment of Process of Manufacture of Ti-6Al-4V Alloy Sintering Body by MIM

  • Otsuka, A.;Suzuki, K.;Achikita, M.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.759-760
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    • 2006
  • Ti-6Al-4V has low specific gravity, high corrosion resistance and superior mechanical properties but it is very difficult to control oxygen content in MIM process. It is necessary to use powders with coarse particle size to decrease oxygen content of powders, so feedstocks with poor fluidity and sintered bodies with lower density are obtained in such cases. Fine titanium hydride-dehydride powders were blended with atomized powders to accomplish higher fluidity and sintered density. Sintered bodies had higher sintered density and mechanical properties equivalent to those of wrought materials by controlling oxygen content less than 0.35mass%.

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하수 슬러지 건조장치 운전시 하수슬러지 함수율 및 조성 분석연구 (The study of sewage sludge moisture content and composition analysis for sewage sludge dryer)

  • 이건주
    • 유기물자원화
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    • 제22권3호
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    • pp.53-59
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    • 2014
  • 본 연구에서는 A 지역의 하수슬러지 건조장치가 설치되기 전과 후 탈수슬러지의 조성 및 성상, 중금속함유량 등을 측정 및 조사 분석을 하였다. 분석결과 건조로 설치전보다 약 95.7%의 제거효율을 보였으며, 설계값으로 1차건조로 35%, 2차건조로 10% 함수율을 제거하지만, 측정해본결과 1차건조로 20.8%, 리본 3.3%로 실제 운전효과가 더 좋은 것으로 나타났다. 중금속 함유량은 건조장치 설치 전 Cu : 352~614ppm, Hg : 1.3~1.44ppm, Cd : 1.1~1.86ppm, Pb : 17.25~ 28.93 ppm, As : 1ppm 이고 설치 후 Cu : 340~350 ppm, Hg : 0 ppm, Cd : 0~0.021 ppm, Pb : 0 ppm, As : 0~0.043 ppm으로 건조장치설치 전과 후 모두 법정 기준치에 초과하지 않음을 확인하였다. 또한 건조장치를 통과한 하수슬러지는 평균적으로 ${\frac{1}{4}}$의 건조슬러지가 발생하였다.

중금속(重金屬) 이온의 토양(土壤) 흡착에 관한 연구 -(제1보) CEC 및 유기탄소 함량이 낮은 광물토양에의 Cd, Cu, Ni, 및 Zn의 흡착과 이에 미치는 pH 및 인산의 효과- (Studies on Heavy Metal Ion Adsorption by Soils. -(Part 1) PH and phosphate effects on the adsorption of Cd, Cu, Ni and Zn by mineral soils with low CEC and low organic carbon content)

  • 김명종;해리.엘.마토
    • Applied Biological Chemistry
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    • 제20권3호
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    • pp.300-309
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    • 1977
  • The information related to the heavy metal pollution in the environment was obtained from studies on the effects of pH, phosphate and soil properties on the adsorption of metal ions (Cd, Cu, Ni, and Zn) by soils. Three soil materials; soil 1 with low CEC (8.2 me/100g) and low organic carbon content (0.34%); soil 2 with high CEC (36.4 me/100g) and low organic carbon content (1.8%) and soil 3 with high CEC (49.9 me/100g) and high organic carbon content (14.7%) were used. Soils were adjusted to several pH's and equilibrated with metal ion mixtures of 4 different concentrations, each having equal equivalents of each metal ion (0.63, 1.88, 3.12 and 4.38 micromoles per one gram soil with and without 10 micromoles of phosphate per one gram soil). Reported here are the results of the equilibrium study on soil I. The rest of the results on soil 2 and soil 3 will be repoted subsequeutly. Generally higher metal ion concentration solution resulted in higher final metal ion concentrations in the equilibrated solution and phosphate had minimal effect except it tended to enhance removal of cadmium and zinc from equilibrated solutions while it tended to decrease the removal of copper and nickel. In soil 1, percentages of added metal ions removed at pH 5.10 were; Cu 97, Ni 69, Cd 63, and Zn 55, while increasing pH to 6.40, they were increased to Cu 90.9, Zn 99, Ni 96, and Cd 92 per As initial metal ion concentration increased, final metal ion concentrations in the equilibrated solution showed a relationship with pH of the system as they fit to the equation $p[M^{++}]=a$ pH+b where $p[M^{++}]=-log$[metal ion concentration in Mol/liter]. The magnitude of pH and soil effects were reflected in slope (a) of the equation, and were different among metal ions and soils. Slopes (a) for metal ions in the aqueous system are all 2. In soil 1 they were; Zn 1.23, Cu 0.99, Ni 0.69 and Cd 0.59 at highest concentration. The adsorption of Cd, Ni, and Zn in soil 1 could be represented by the Iangmuir isotherm. However, construction of the Iangmuir isotherm required the correction for pH differences.

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Toxicity evaluation based on particle size, contact angle and zeta potential of SiO2 and Al2O3 on the growth of green algae

  • Karunakaran, Gopalu;Suriyaprabha, Rangaraj;Rajendran, Venkatachalam;Kannan, Narayanasamy
    • Advances in nano research
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    • 제3권4호
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    • pp.243-255
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    • 2015
  • In this investigation, ecotoxicity of nano and micro metal oxides, namely silica ($SiO_2$) and alumina ($Al_2O_3$), on the growth of green algae (Porphyridium aerugineum Geitler) is discussed. Effects of nano and micro particles on the growth, chlorophyll content and protein content of algae are analysed using standard protocols. Results indicate that $SiO_2$ nano and micro $SiO_2$ particles are non-toxic to P. aerugineum Geitler up to a concentration of 1000 mg/L. In addition, $Al_2O_3$ microparticles are less toxic to P. aerugineum Geitler, whereas $Al_2O_3$ nanoparticles are found to be highly toxic at 1000 mg/L. Moreover, $Al_2O_3$ nanoparticles decrease the growth, chlorophyll content, and protein content of tested algae. In addition, zeta potential and contact angle are also important in enhancing the toxicity of metal oxide nanoparticles in aquatic environment. This study highlights a new insight into toxicity evaluation of nanoparticles on beneficial aquatic organisms such as algae.

아아크 용접봉 피복제 의 함수량 이 용접금속 의 기계적 성질에 미치는 영향 (Effect of Moisture in Arc Welding Electrode on Mechanical Properties of Weld Metal)

  • 윤희만;김연식;박종은
    • Journal of Welding and Joining
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    • 제2권1호
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    • pp.30-40
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    • 1984
  • Moisture content in the coating of an electrode is known to cause defects such as porosities, fish eyes and cracks in the weld metal, however, quantitative relationship between them is not clearly understood. In this study widely consumed and the most common type of arc welding rods such as ilmenite and low hydrogen type were chosen for the investigation, and attempts were made to correlate the relationship between the mechanical properties and gas contents when welding was carried out with electrodes of various moisture contents. As the relative humidity changed from 70% to 92%, it was determined that moisture content to reach saturation was in the range of 0.6~6.8%. As the moisture content in the electrode coating was increased, the amount of gaseous components (H, O, N) in the weld metal was accordingly increased, especially diffusible hydrogen showed prominent effect, i.e. it increased proportionally to the increase of the moisture content. The mechanical properties of the weld metal was observed to become more inferior as the diffusible hydrogen was greater. It was determined for ilmenite type of electrode that the increase of hydrogen content was approximately 1.8ml per unit weight percent increase of moisture and also tensile strength resulted lowering from $45.3kg/\textrm{mm}^2$ to $42.7kg/\textrm{mm}^2$ as moisture content increased from 0.7% to 6.8%. For low hydrogen type the increase of the hyrogen was about 2.4ml per unit percent of moisture and tensile strength decreased from $63.0kg/\textrm{mm}^2$ to $53.8kg/\textrm{mm}^2$ particularly in the region of moisture content 0.1~4.2%.

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