• 제목/요약/키워드: mesoporous silica

검색결과 186건 처리시간 0.033초

Pretreatment Effect on CO Oxidation over Highly Ordered Mesoporous Silver Catalyst

  • Shon, Jeong-Kuk;Park, Jung-Nam;Hwang, Seong-Hee;Jin, Mingshi;Moon, Ki-Young;Boo, Jin-Hyo;Han, Tae-Hee;Kim, Ji-Man
    • Bulletin of the Korean Chemical Society
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    • 제31권2호
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    • pp.415-418
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    • 2010
  • Highly ordered mesoporous silver material was successfully synthesized from a mesoporous silica template (KIT-6) with 3-D channel structure using the nano-replication method. The effects of $H_2$ or $O_2$ pretreatments on the catalytic performance of the mesoporous silver were investigated using a temperature programmed CO oxidation technique in a fixed bed reactor. The mesoporous silver material that was pretreated with $H_2$ exhibited an excellent catalytic activity compared to the as-prepared and $O_2$-pretreated catalysts. Moreover, this present mesoporous silver material showed good catalytic stability. For the CO oxidation, the apparent activation energy of the $H_2$-pretreated mesoporous silver catalyst was $61{\pm}0.5\;kJ\;mol^{-1}$, which was also much lower than the as-prepared ($132{\pm}1.5\;kJ\;mol^{-1}$) and $O_2$-pretreated ($124{\pm}1.4\;kJ\;mol^{-1}$) catalysts.

구형 메조포어 MCM-41의 합성에 관한 연구 (A Study on the Synthesis of Spherical Mesoporous MCM-41)

  • 유성구;이두형;서길수;이태진
    • 공업화학
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    • 제10권7호
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    • pp.1096-1098
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    • 1999
  • MCM-41형의 메조포러스 구형 실리카 재료를 염기성 조건에서 양이온 계면활성제를 templating species로 사용하여 합성하였다. 본 실험에서 사용한 계면활성제로는 octyltrimetylammonium bromide, dodecyltrimetylammonium bromide, cetyltrimethylammonium bromide, octadecyltrimethyammonium bromide 및 cetylpyridium bromide이었다. 구형 MCM-41의 비표면적은 $1500m^2/g$나 되었으며 계면활성제의 알킬 사슬의 길이가 길어질수록 기공 크기는 증가하였다.

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탄소지지체의 화학적 변형에 따른 연료전지용 백금-루테늄 촉매의 전기화학적 활성의 영향 (Effect of Chemical Modification of Carbon Supports on Electrochemical Activities for Pt-Ru Catalysts of Fuel Cells)

  • 김병주;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.94.1-94.1
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    • 2011
  • In this work, ordered mesoporous carbons (OMCs) were prepared by the conventional templating method using mesoporous silica (SBA-15) for Pt-Ru catalyst supports in fuel cells. The influence of surface modification on carbon supports on the electrochemical activities of Pt-Ru/OMCs was investigated with different pH. The neutral-treated OMCs (N-OMCs), base-treated OMCs (B-OMCs), and acid-treated OMCs (A-OMCs) were prepared by treating OMCs with 2 M $C_6H_6$, 2 M KOH, and 2 M $H_3PO_4$, respectively. The surface characteristic of the carbon supports were determined X-ray photoelectron spectroscopy (XPS). The electrochemical activities of the Pt-Ru catalysts had been enhanced when the OMCs supports were treated by basic or neutral agents, while the electrochemical activities had been decayed for the A-OMCs supported Pt-Ru.

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Adsorption Behavior of Environmental Hormone Bisphenol A onto Mesoporous Silicon Dioxide

  • Fan, Xianghong;Tu, Bing;Ma, Hongmei;Wang, Xuefen
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2560-2564
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    • 2011
  • Mesoporous silicon dioxide (meso-$SiO_2$) was prepared using cetyltrimethylammonium bromide as the structure-directing reagent and tetraethyl orthosicate as the silicon source. The influence of pH value on the adsorption behavior of bisphenol A (BPA) was investigated. The adsorption capacity of BPA onto meso-$SiO_2$ increases slightly with pH value from 2 to 6, and then gradually decreases as further improving pH value. The effect of temperature was also studied, and the adsorption capacity of BPA gradually declines with increasing temperature. The adsorption kinetics and thermodynamics of BPA were examined. It is found that the adsorption of BPA onto meso-$SiO_2$ is in good agreement with Langmuir adsorption model. The rate constant of adsorption is $5.17{\times}10^{-3}g\;mg^{-1}\;min^{-1}$, and the maximum adsorption capacity is as high as 353.4 $mg\;g^{-1}$ at 20 $^{\circ}C$.

Thermally Induced Mesophase Development in Ethanesilica Films via Macromolecular Templating Approach

  • Cho, Whirang;Char, Kook-Heon;Kwon, Su-Yong
    • Macromolecular Research
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    • 제17권9호
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    • pp.697-702
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    • 2009
  • Mesoporous ethanesilica thin film was prepared using PEO-PLGA-PEO triblock copolymers as structure-directing agents and (1,2-bis(triethoxysilyl) ethane BTESE; bridged organosilicates) as inorganic precursors via one-step sol-gel condensation of ethanesilica precursors. The mesostructure of ethanesilica films is critically dependent on the processing experimental parameters after the hydrolyzed silica sol mixture was spin-cast. This study examined the effects of the block copolymer template/organosilica precursor ratio in the casting solution and aging period before calcination of the mesostructure. It was further demonstrated that mesoscopic ordering of organosilicate thin films is induced by the rearrangement of block copolymer template/organosilica hybrid during thermal decomposition of the PEO-PLGA-PEO triblock copolymer. The mesoporous structure and morphology were characterized by SAXS, TEM and solid-state NMR measurement.

Structural Transcription of Organogels to Mesoporous Silicas: A Chain-length Dependent Morphology and Pore Texture

  • Huang, Yaqun
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3711-3718
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    • 2012
  • Here, we report a chain-length dependent morphology and pore structure tailing of mesoporous silica templated from organogels, which is formed by primary alkylamine and ethylene glycol at room temperature. As the chain length of alkylamine changes from 12 to 18, the resulted materials exhibit a morphology change from layers to spheres and platelets, respectively. SEM and TEM observation revealed that these shapes appear to be inherited from their parent organogels. Further pore structure characterization by nitrogen sorption analysis demonstrates that all the resulted silicas exhibit typical IV isotherms indicative of uniform mesopores, and their pore sizes are dependent on the chain length of alkylamine used.

EDTA-functionalized KCC-1 and KIT-6 mesoporous silicas for Nd3+ ion recovery from aqueous solutions

  • Ravi, Seenu;Zhang, Siqian;Lee, Yu-Ri;Kang, Kyoung-Ku;Kim, Ji-Man;Ahn, Ji-Whan;Ahn, Wha-Seung
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.210-218
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    • 2018
  • Ethylenediaminetetraacetic acid (EDTA)-functionalized KIT-6 and KCC-1 mesoporous silicas were prepared via post-synthesis grafting and examined for their ability to promote the recovery of rare earth metal ions such as $Nd^{3+}$ from an aqueous medium. The obtained adsorption isotherms were fitted to the Langmuir model, which gave a maximum adsorption of $Nd^{3+}$ ions of 109.8 and 96.5 mg/g for KIT-6-EDTA and KCC-1-EDTA, respectively, at $25^{\circ}C$ and pH 6. The adsorption kinetic profile of KIT-6 was faster than KCC-1. KIT-6 was also proved to be more stable against desorption under acidic regeneration conditions.

Mesoporous Carbon Additives for Long Cycle Life Sulfur Cathodes of Li-S Batteries

  • Koh, Jeong Yoon;Kim, Tae Jeong;Park, Min-Sik;Kim, Eun Hee;Kim, Seok;Kim, Ki Jae;Yu, Ji-Sang;Kim, Young-Jun;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • 제35권11호
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    • pp.3331-3335
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    • 2014
  • We examine the potential use of disordered mesoporous carbon as a functional additive for confining dissolved Li-polysulfides and improving the cycling performance of Li-S batteries. To promote a better understanding of the correlation between the total pore volume of disordered mesoporous carbon and the cycling performance of Li-S batteries, a series of disordered mesoporous carbons with different total pore volumes are successfully synthesized using a commercial silica template. Based on the electrochemical and structural analyses, we suggest that the total pore volume of disordered mesoporous carbon is a predominant factor in determining its capability for either the absorption or adsorption of Li-polysulfides, which is primarily responsible for enhancing the cycling performance. The addition of disordered mesoporous carbon is also effective in enhancing the homogeneous distribution of active sulfur in the cathode, thereby affecting the cycling performance.

Catalytic Combustion of Toluene Over NiO Supported on Mesoporous Silica Catalysts Prepared by Atomic Layer Deposition

  • Jeong, Myung-Geun;Jeong, Bora;Seo, Hyun Ook;Kim, Kwang-Dae;Park, Eun Ji;Sim, Jong Ki;Kim, Dae Han;Cho, Youn Kyuong;Yoon, Hye Soo;Lim, Dong Chan;Kim, Young Dok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.165-165
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    • 2013
  • Nickel oxide was deposited on mesoporous silica by atomic layer deposition (ALD) consisting of sequential exposures to Ni(cp)2 and $H_2O$. NiO/silica samples were characterized by inductively coupled plasma-mass spectroscopy (ICP-MS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), etc. The flow-type reactor was used to measure activity of NiO/silica catalyst for catalytic combustion of toluene. The activity of NiO/silica catalyst was evaluated in terms of toluene removal efficiency and selectivity to $CO_2$ and compared with those of bare nickel oxide nanoparticles. In order to investigate influence of reaction temperature on combustion aspect, the catalytic combustion experiments were carried out at various temperatures. We show that both bare and supported NiO can be efficient catalysts for total oxidation of toluene at a temperature as low as $250^{\circ}C$.

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술폰산으로 표면개질된 메조기공 실리카 촉매의 제조 및 Octamethylcyclotetrasiloxane 개환중합에서의 촉매 활성 (Mesoporous Silica Catalysts Modified with Sulfonic Acid and Their Catalytic Activity on Ring Opening Polymerization of Octamethylcyclotetrasiloxane)

  • 이연송;황하수;이지영;로누호앙티엔;느윙티엔지앙;이동현;박인
    • 공업화학
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    • 제31권4호
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    • pp.383-389
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    • 2020
  • 프로필 술폰산으로 개질된 메조기공 실리카 고체 산 촉매를 octamethylcyclotetrasiloxane (D4)의 양이온 개환중합을 위해 합성하였다. 서로 다른 기공 크기를 갖는 두 세트의 MCM-41 (1.7 및 2.8 nm) 및 SBA-15 (8.1 및 15.9 nm)을 촉매의 지지체로 사용하였고, 이를 (3-mercaptopropyl)trimethoxysilane으로 표면개질하고 산화시켜 술폰산으로 개질된 고체 산촉매를 제조하였다. 제조된 촉매는 기공 크기와 비표면적, 기공 부피가 약간씩 감소하였음을 X선 회절, 질소흡탈착을 통하여 확인하였다. 또한 적외선분광법과 핵자기공명법의 분광학적 방법을 이용하여 술폰산이 개질되었음을 확인하였다. 입도의 촉매 활성에 대한 효과를 관찰하기 위하여 주사전자현미경으로 관찰하였다. D4의 개환중합을 통한 PDMS 합성을 위하여 촉매를 사용하였으며, 중합 반응의 전환율과 중합 속도는 촉매의 기공 크기, 비표면적, 입자크기 및 입자의 응집도에 의존하였다. 중합 속도의 순서는 8.1 nm의 SBA-15으로 제조한 촉매가 가장 반응속도가 빨랐으며, 가장 좋은 촉매 활성을 보였다.