• Title/Summary/Keyword: mercaptan

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Interfacial Fracture Behavior of Epoxy Adhesives for Electronic Components (전자부품용 에폭시 접착제의 계면 파괴 거동 연구)

  • Kang, Byoung-Un
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.3
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    • pp.1479-1487
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    • 2011
  • In the field of the entire electronic component industry including mobile IT products, the importance of a versatile package with the multifunctional or high capacity memories is gradually increased. Multi Chip Package which has several chips in a single package is frequently used for that purpose. In MCP, epoxy adhesive films play a major role in adhesion between the chips or between chip and substrate. A series of silane coupling agents with a functional group such as epoxy, amine, mercaptan, and isocyanate were applied to the epoxy adhesives and material properties such as wettability and reliability of the adhesives were investigated. From the results, the silane coupling agent with an epoxy functional group showed highest wettability and peel strength in epoxy adhesive. For those reasons, it lead to a superior reliability in the epoxy adhesive against interfacial fracture behaviors through moisture resistance test.

Development of composite catalyst for hazardrous gas treatment using the heat of aviary heating equipment (계사용 온풍기를 이용한 유해가스처리 복합촉매시스템 개발)

  • Jang, Hyun-Tae;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.10
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    • pp.2779-2785
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    • 2009
  • Among the livestock, chickens are raised because of the merit ingested protein in low-priced cost of production and are primary livestock increased the consumption of meat. The factors of influencing condition, odor is the most important factor. Odor substances are ammonia, amines, hydrogen sulfide and mercaptan which come from night soil. Livestock are prevented from rearing by means of these odor substances. Though the henhouse is heated using hot air type heater in the winter season, it is ventilated for the control of odor because of the increase of odor concentration. In the present work, composite catalytic system combined the existing facilities(hot air type heater) with catalytic system was developed, it could controled odor and hazardous gas using the oxidation/reduction reaction without extra operating cost. Moreover, the purpose of this work is to develop the catalysts which are cost competitive and can maximize energy efficiency. The catalysts are noble metal(Pt-Rh) and composite transition metal(Mn) type.

The Foul Smelling from Sewer Pipe near Large Apartment Complexes and its Countermeasures I: Characteristics of the Foul-Smelling Sewer Pipe in Residential Areas (대규모 아파트 단지주변 하수관로의 악취 발생과 대책 1: 주거지역 하수관로의 악취 발생 특성)

  • Lee, Jang-Hown;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.5
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    • pp.621-629
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    • 2007
  • This study intends to investigate the characteristics of the foul smell of sewer pipes near large apartment complexes as complaints about offensive odors have drastically increased in urban residential areas. Targeting apartments where people actually complained about foul orders, the study result revealed that components in the smell of the water-purifier tank of the target apartment were very similar to those of sewage treatment plants and night soil treatment plants. Measuring components of odors inside the management layer of tank showed that the concentration of hydrogen sulfide was 10ppm, which is approximately 160 times the safety standard of 0.06ppm; the concentration of mercaptan was 0.9ppm, which is about 220 times the safety standard of 0.004ppm. The source materials of foul odors were discharged outside through ducts, and those households living near outlets producing bad smell complain that it gets worse depending on the air pressure or wind direction and strength, and they could not even open windows. As well, these source materials were transferred by discharge pumps to public sewer pipes outside the apartment complex. While discharge pumps starts operating, they remain on the sewer pipe and then begin to spread over to roads through small openings of manholes on the road. Then, the smell offends passers-by and residents near the road, leading to a lot of complaints. The study results suggest that, among the sources of foul odors in sewer pipes of residential areas, especially those from the water-purifier tank of large apartments, hydrogen sulfide should be the main target for follow-up treatment.

Investigation of odor Release from Combined Sewer (합류식 하수도의 악취발생 실태 연구)

  • Gil, Kyung-Ik;Shin, Geon-Cheol;Im, Ji-Yeol
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.6
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    • pp.185-191
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    • 2010
  • This study investigates the odor from combined sewer in urban areas and major odor-causing facilities. Monitorings are conducted in specific areas that have representative characteristics. In combined sewer in urban areas, the real-time monitorings on sulfur, complex odor and specified odor are conducted. And in major odor-causing facilities, the real-time monitorings on complex odor, specified odor are conducted. Odor from combined sewer in urban area is affected by the changes on floating population and the effluent of the septic tank. Also major odor-causing facilities are largely affected by the effluent of the septic tank. The major odor-causing substances are found to be hydrogen sulfide($H_2S$) and methyl mercaptan. To reduce the odor from combined sewer, improvement of effluent from the septic tank and reduction of sulfur compounds have to be done.

Dispersion Characteristics of Odorous Elements from Nambu Wastewater Treatment Plant and a Nearby Streams in Busan (부산시 남부하수처리시설과 인근 하천에서 발생하는 악취물질 확산 특성)

  • Mun, Seong-Man;Lee, Hyung-Don;Cho, Sang-Won;Kang, Dong-Hyo;Park, Hae-Sik;Oh, Kwang-Joong
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.953-962
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    • 2011
  • The covered stream of cities are considered an odor source. Also, the public do not want a wastewater treatment plant(WWTP) near their properties due to the emission of odor emanating from such sources, although they play an important role in urban development. The purpose of this study is to analyze the pattern distribution of the odorous compounds from the Nambu WWTP and Youngho stream in Busan. odor sampled four times were analyzed by instrumental analysis method and indirect olfactory method. The kinds of offensive odorous compounds examined are acetaldehyde, propion aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and ammonia. Also, Concentration of air pollutants has been calculated by ISCST3 models. At the result of this study, The Nambu WWTP releases sulfur compounds. And the major odorous were hydrogen sulfide (1,475 ppb) and acetaldehyde (95 ppb) at Youngho stream. The stink which residents feel will point out the Nambu WWTP mainly if the odor is removed with the improvement of a Youngho stream. Accordingly, we should pay more attention to appropriate components to processes in odor reducing plan at Nambu WWTP.

THE EFFECT OF MOUTH RINSE PRODUCTS CONTAINING DEEP SEA WATER (해양심층수를 이용한 구강청정제의 효과)

  • Kim, Seon-Ah;Jang, Hae-Jin;Yoo, Yung-Geun;Chu, Yong-Shik;Park, Yang-Ho;Park, Jun-Woo
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.33 no.6
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    • pp.601-608
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    • 2007
  • The aim of this study was to evaluate the effect of mouthrinse products containing deep sea water. We used original deep sea water(DSW) and processed deep sea water desalinated by reverse osmosis at one time(DDW-1), by reverse osmosis at two times(DDW-2) and concentrated by reverse osmosis(CDW). We made 2 kinds of mouthrinse products containing CDW and other agents for smell and taste and one product without deep sea water. The negative control was distilled water. In vivo study, the dental plaque index scores and the gingival index scores were reduced after 4 weeks mouthrinsing three times daily with 4 kinds of deep sea water and 3 kinds of mouthrinse products(p<0.05). The pH of dental plaque in 1 minute after mouthrinsing was not higher than 5.5 in all solutions, but the pH in 20 minutes after mouthrinsing was higher than 5.7 in DSW, CDW and 3 kinds of products which had higher mineral contents. In vitro study, the mouthrinse solutions containing the higher mineral contents were also the more effective in reduction of methyl mercaptan which is one of the causes of halitosis. The 2 kinds of products containing deep sea water killed Streptococcus mutans(ATCC 25175) in culture plates in one minute. These results indicate the usability of deep sea water in mouthrinses for oral hygiene management.

A Study on Effective Removal Method of Odorant Smell in Natural Gas using Sodium Hypochlorite (차아염소산나트륨을 이용한 천연가스 부취냄새 효과적 탈취방법 연구)

  • Lim, Hyung-Duk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.154-159
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    • 2018
  • Intentional releases occur frequently during maintenance in gas supplying companies, which may result in unpleasant odors, and the possible mistaken belief of a gas accident. Therefore, this study developed a chemical process for effective odorant removal in natural gas using an active chemical that is released intentionally during maintenance and inspection. To develop an effective treatment process for removing the odorant from released natural gas, the effluent concentrations of the odorant in the released gas were measured after a chemical oxidation reaction with a sodium hypochlorite solution in a compact gas scrubbing equipment newly devised in this study. The device was based on a mixed gas vent after the solution inject odorant in the gas through the energy of the venting gas. The cascade combination of a venturi pipe and mixing chamber was developed to remove the odorant effectively from the purposely-released natural gas using an oxidative reaction between the mercaptan compounds (odorant) and the sodium hypochlorite solution. On the other hand, the developed method could be applied limitedly to a relatively small gas release from a low-pressure source. Further studies will be needed to apply the developed process to a large-scale gas release from a high-pressure source.

Deodorizing Effect of Cheonggugamrosu (청구감로수(淸口甘露水)의 구취억제효과)

  • Eom, Guk-Hyeon;Kim, Jin-Sung
    • The Journal of Internal Korean Medicine
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    • v.28 no.2
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    • pp.354-362
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    • 2007
  • Objective : The aim of this study was to investigate the ability of Cheonggugamrosu. a gargling agent made from herb extracts, to decrease oral malodor in vitro and in clinical research. Methods : For in vitro experiment. samples were Garglin (over-the-counter mouthwash), CheonggugamrosuA and Cheonggugamrosu B. Deodorizing activity of each sample against methyl mercaptan were analyzed by gas chromatography (GC). In clinical examination. subjects were 73 students from the oriental medicine school of Kyunghee University. The concentration of VSC in oral cavity of each subject was measured by Halimeter and subjects were divided into 3 groups that would gargle for 30 seconds with normal saline. Garglin and CheonggugamrosuA. Subsequently, concentration of VSC was measured in same way immediately, 2 hours and 4 hours after gargling. Results : During in vitro experiment by GC, deodorizing activities were 46.77% with Garglin, 80.64% with Cheonggugamrosu A and 82.28% with Cheonggugamrosu B. In clinical examination, at 2 hours after gargling, the concentration of VSC in the Cheonggugamrosu A group was significantly lower than in the normal saline group, but not in the Garglin group. 4 hours after gargling, the concentration of VSC in both CheonggugamrosuA and Garglin wasn't significantly different from the one in the normal saline group. Conclusions : Cheonggugamrosuhad better and longer deodorizing effect than Garglin in this study. Because of the safety of herbal medicine and its efficaciousness, we can use Cheonggugamrosu as a clinical prescription.

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First-principles Study of the Structure and Growth Mechanism of Allyl Alcohol Lines on the H-terminated Si(001)

  • Choi, Yun-Ki;Choi, Jin-Ho;Cho, Jun-Hyung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.184-184
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    • 2011
  • Using first-principles density-functional calculations, we investigate the chain reaction mechanism of allyl alcohol (ALA) molecules on the H-terminated Si(001)-2${\times}$1 surface. Recently, it was reported [1] that allyl mercaptan (ALM) molecules show a self-directed line growth across the dimer rows through a chain reaction involving several reaction processes: (i) The created radical at the C atom is transferred to the S atom, (ii) the resulting S-centered radical easily abstracts an H atom from the neighboring dimer row, and (iii) the generated S-H group further reacts with the neighboring dimer row to produce the Si-S bond on the neighboring dimer row, accompanying the associative desorption of H2. This H2-desorption process creates a new DB on the neighboring dimer row, setting off the chain reaction across the dimer rows. In the present study, we find that although the structure of ALA with -OH functional is analogous to that of ALM with -SH functional, ALA and ALM lines show a difference in their growth direction. We predict that ALA undergoes the chain reaction to show a line growth along the dimer row, contrasting with the ALM line growth across the Si dimer rows. Our analysis shows that the different growth direction of ALA is due to the strong instability of oxygen radical intermediate, which prevents from growing across the dimer rows. Thus, we demonstrate that the stability of the radical intermediate plays a crucial role in determining the direction of molecular line growth.

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The Malodor Decreasing Effect of Saccharomyces cerevisiae on Decomposing Waste Egg (Saccharomyces cerevisiae의 폐달걀 분해과정에서 발생하는 악취 감소효과)

  • Lee, Chang Hoon;Lee, Yong Ho;Yoo, Jae Hong;Park, Jun Young;Shim, Myoung Yong
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.177-182
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    • 2016
  • Malodor emitted while producing fertilizer from hatchery egg waste treated with microorganism is an important limiting factor. To reduce this problem, we attempted to use two yeast strains, Saccharomyces cerevisiae, KACC 30008 and KACC 30068. Both yeast strains reduce ammonia gas emission 35.4% than only treated with bacterium, Bacillus amyloliquefaciens. When both strains were used together, that was reduced as 57.1%. KACC 30008 and 30068 strains reduced hydrogen sulfide 42 and 90.4%, respectively. Both strains together reduced hydrogen sulfide gas as 98.5%. KACC 30008 did not decrease methyl mercaptan emission. However KACC 30068 decreased 40% and both strains together decreased the gas emission as 66.7%. Overall, this study showed that yeast treatment could enhance the effect of B. amyloliquefaciens treatment in the reduction of malodorous gas emission.