• Title/Summary/Keyword: membranes

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Dense Ceramic-metal Composite Inorganic Membranes for Oxygen Separation (산소 분리를 위한 무공성 세라믹- 금속 복합 무기막)

  • 김진수
    • Proceedings of the Membrane Society of Korea Conference
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    • 2002.05a
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    • pp.35-41
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    • 2002
  • Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

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Synthesis and Permeation Characteristics of Zeolite Membranes

  • Kita, Hidetoshi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.5-8
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    • 1997
  • Introduction : Membranes made from inorganic materials are generally superior to organo-polymeric materials in thermal and mechanical stability, and chemical resistance. Among inorganic materials zeolite is a promising candidate for a high performance membrane because of the unique characteristics of zeolite crystals such as molecular sieving, ion exchange, selective adsorption and catalysis. Although there are many recent reportsl on the preparation of zeolitc membranes and the gas permeation through the membranes, only a limited number of publications deal with pervaporation studies. Recently, we have reported a high pervaporation performance of NaA zeolite membrane for the separation of water/organic liquid mixtures. and of NaY zeolite menlbrane for the separation of methanol/MTBE. Here, preparation of zeolite (LTA, ZSM-5 and FAU) membranes and their permeation properties are discussed.

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Rotaxane/Nafion Composite Membranes for Direct Methanol Fuel Cells (직접 메탄올 연료전지용 Rotaxane/Nafion 전해질막)

  • Cho Hyun Dong;Won Jongok;Kang Yong Soo;Ha Heung Yong
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.11a
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    • pp.146-148
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    • 2004
  • Rotaxane/Nafion composite membranes were prepared and characterized. Proton conductivity was .01 S/cm and the methanol ($10\;wt\%$) premeability was $7.88{\times}10^{-7}\;cm^2/sec$ at 5 $wt\%$ of rotaxane/Nafion composite membranes. The characterization of the status of retaxane inside of Nafion membranes is under study.

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Effects of Godulbaegi Extracts on the Stability and Fluidity of Phospholipid Liposomal Membranes (고들빼기 추출물이 인지질막 Liposome의 안정성 및 유동성에 미치는 영향)

  • 배송자;노승배;정복미
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.3
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    • pp.508-517
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    • 1998
  • We investigated the effects of godulbaegi extracts on the physiochemical properties of biological membranes as membrane stability and fluidity employing the phospholipid liposomal membrances as a biomembrane-mimetic system. The addition of the godulbaegi extracts to the phospholipid exterted great effects stagbilized the barrier function of the liposomal membranes in proportion to the concentration of the additive and significantly increased the membranes fluidity. The values of the fluorescence polarization of 1,6-diphenyl 1,3,5-hexatriene (DPH) decreased gradually as the temperature increased, and decreased abruptly near the phase transition temperature (Tm) of the liposome from gel to liquid crystalline state as usual. These results suggest that the activities of the godulbaegi extracts to enhance the stability and fluidity of the liposomal membranes have implication in their biological activities.

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Effect of Asphalt Pavement Conditions on Tensile Adhesive Strength of Waterproofing System on Concrete Bridge Deck (아스팔트 포장 조건이 교면방수 시스템의 인장접착강도에 미치는 영향)

  • 이병덕;박성기;김광우;정해문
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.299-304
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    • 2003
  • In this research, eight waterproofing membranes were selected from commercial market and the tensile adhesive characteristics of the waterproofing system (WPS) on concrete bridge deck were investigated in view of various factor in asphalt pavement. Tensile adhesive strength (TAS) test of different asphalt pavement types showed that TAS of WPS under SMA (Stone Mastic Asphalt) pavement was greater than that under dense asphalt pavement. Tensile adhesive strength (TAS) of sheet membranes was improved as the compaction temperature of asphalt concrete increase, but TAS of liquid membranes were not. TAS of sheet membranes after wheel tracking test were in the order of the sites under wheel path (UWP), before wheel tracking (BWT) and nearby wheel path (NWP), Since TAS of the same WPS of UWP was higher than TAS of BWT, wheel loading had function of pressing WPS resulting in higher adhesive strength, But liquid membranes were variable on types, The feature of detached interface after T AS test showed that sheet types were all detached in between deck concrete and WPS, and liquid types were detached in between asphalt pavement and WPS,

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Effect of High-Temperature Spinning and PVP Additive on the Properties of PVDF Hollow Fiber Membranes for Microfiltration

  • Cha, Bong-Jun;Yang, Jung-Mok
    • Macromolecular Research
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    • v.14 no.6
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    • pp.596-602
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    • 2006
  • The effect of high-temperature spinning and poly(vinyl pyrrolidone) (PVP) additive on poly(vinylidene fluoride) (PVDF) hollow fiber membranes was investigated using differential scanning calorimetry, X-ray diffraction measurement, and scanning electron microscopy, together with the corresponding microfiltration performances such as water flux, rejection rate, and elongational strength. Using high-temperature spinning, porous hollow fiber membranes with particulate morphology were prepared through PVDF crystallization. The particulate structure of the membranes was further modified by the addition of miscible PVP with PVDF. Due to these effects, the rejection rate and strength of the fibers were increased at the expense of reduced water flux and mean pore size, which indicates that high-temperature spinning and PVP addition are vary effective to control the morphology of PVDF hollow fiber membranes for microfiltration.

Preparation and Structure of the Synthetic Polymeric Membranes based on Polystyrene and Poly(sodium 4-styrene sulfonate) (Polystyrene과 Poly(sodium 4-styrene sulfonate)를 이용한 합성 고분자 분리막의 제막 및 구조)

  • 변홍식;탁태문
    • Membrane Journal
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    • v.6 no.4
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    • pp.273-283
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    • 1996
  • A cation-exchange membranes were prepared by polystyrene and poly(sodium 4-styrene sulfonate). The degree of crosslinking of polystyrene membranes was controlled by DVB. At the same time, the structure of PS membranes was changed from RO to MF by varying the concentration of PSS in the casting solution. Water flux increased with PS-PSS membranes due to the sulfonate groups, and final membrane cast from the solution containing 5% of DVB and 3% of PSS showed MF structure.

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Blood Compatibility of Hollow Fiber Membranes Treated with Plasma Polymerization (플라즈마 중합 처리된 중공사 막의 혈액 적합성)

  • Kwon O. S.;Lee S. C.
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.521-527
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    • 2005
  • Surface modification of polypropylene hollow fiber membranes was peformed in order to develop blood-compatible biomaterials for use in the blood contacting and oxygenation membranes of a lung-assist device(LAD). Blood compatibility was determined by using anticoagulation blood and evaluating formation of blood clots on their surfaces as well as activation of plasma coagulation cascade, platelet adhesion, and aggregation. It was verified that the number of platelets on the silicone coated fibers was significantly lower than those on polypropylene. It was also found that the polypropylene hollow fiber membranes using plasma treatment exhibited suppression of complement activation in blood compatibility test.

Preparation and Characterization of PVA/SA Blend Nanofiltration membranes

  • Llee, Kew-Ho
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.86-92
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    • 1999
  • The nanofiltration (NF) membranes based on poly(vinyl alcohol) (PVA) and sodium alginate (SA) were prespared. Homogeneous PVA/SA blend membranes were prepared by casting a PVA/SA (95/5 in wi%) mixture solution on an acryl plate followed by drying at a room temperature and by cros-slinking with glutaraldehyde (GA) for 20 minutes PVA/SA blend composite membranes were also prepared by coating a PVA/SA (95/5 in wi%) mixture solution on microporous polysulfone(PSF) supports. The PVA/SA active layer of the composite membrane was crosslinked at room temperature by using an membranes were characterized with a scanning electron microscopy (SEM) a fourier transform infrared spectroscopy (FTIR) and permeation tests. The permeation properties of the composite membrane were as follows: 1.3{{{{ {m }^{2 } }}}}/{{{{ {m }^{2 } }}}}day of flux and >95% of rejection at 200 psi for a 1000 ppm PEG600 solution.

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