• Title/Summary/Keyword: membranes

Search Result 3,793, Processing Time 0.027 seconds

The Commercial Use of Ultrafiltration Membranes in the Resolution of Aqueous Problems

  • Layton, R.B.
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1997.06a
    • /
    • pp.175-181
    • /
    • 1997
  • This paper describes the commercial application of custom ultrafiltration (UF) membranes in the resolution of two aqueous-based problems: the recovery and recycling of laundry wash water and the fmal polishing of sodium hydroxide sterilization solution in the dairy and brewing industries. Both applications are currently in the pilot Stage and employ custom-made UF membranes developed by Liumar Technologies Corporation of Ottawa, Canada.

  • PDF

분리막의 종류 및 원리

  • 민병렬
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1993.06a
    • /
    • pp.1-29
    • /
    • 1993
  • 막 분리는 막의 물리화학적 특성, 분리대상 물질의 물리화학적 특성, 그리고 물질의 이동현상을 조절하는 압력차, 농도차 및 전위차 등의 추진력, 이 세가지 요소의 조합에 의해 행해진다. 막은 막을 구성하고 있는 물질의 물성, 구조, 막의 응용분야 및 역할 등에 의하여 세공막(Macroporous membranes), 미세공막(Microporous membranes), 비공성막(Nonporous membranes)등으로 분류된다.

  • PDF

Preparation and Characterization of the Asymmetric Microporous Poly(vinylidene fluoride) (PVDF) Blend Membranes with Hydrophilic Surfaces

  • Hwang, Jeong-Eun;JeGal, Jong-Geon
    • Korean Membrane Journal
    • /
    • v.9 no.1
    • /
    • pp.1-11
    • /
    • 2007
  • To prepare chemically stable asymmetric microporous membranes with a hydrophilic surface, which would be expected to have better antifouling properties, poly(vinylidene fluoride) (PVDF) blend membranes were prepared by the phase inversion process. PVDF mixture solutions in N-methylpyrrolidone (NMP) blended with several polar potential ionic polymers such as polyacrylonitrile (PAN), poly(methylmethacrylate) (PMMA) and poly(N-isopropylacrylamide) (NIPAM) were used for the formation of the PVDF blend membranes. They were then characterized with several analytical methods such as FESEM, FTIR, contact angle measurement, pore size distribution and permeability measurement. Regardless of different polar polymers blended, they all showed a finger-like structure with more hydrophilic surface than the pristine PVDF membrane. For all the PVDF blend membrane, due to the polar potential ionic polymers used, the flux of those was improved. Especially the PVDF blend membrane with NIPAM showed the highest flux among the membranes prepared. Also antifouling property of the PVDF membrane was improved by the use of the polar polymers.

The Effect of Annealing on sSEBS/Polyrotaxanes Electrolyte Membranes for Direct Methanol Fuel Cells

  • Won, Jong-Ok;Cho, Hyun-Dong;Kang, Yong-Soo
    • Macromolecular Research
    • /
    • v.17 no.10
    • /
    • pp.729-733
    • /
    • 2009
  • Solution casting films of sulfonated poly[styrene-b-(ethylene-r-butylene)-b-styrene] copolymer (sSEBS)-based composite membranes that contained different amounts of organic, nanorod-shaped polyrotaxane were annealed at various temperatures for 1 h. The films' properties were characterized with respect to their use as polymer electrolyte membranes in direct methanol fuel cells (DMFCs). Different aspect ratios of polyrotaxane were prepared using the inclusion-complex reaction between $\alpha$-cyclodextrin and poly(ethylene glycol). The presence of the organic polyrotaxane inside the membrane changed the morphology during the membrane preparation and reduced the transport of methanol. The conductivity and methanol permeability of the composite membranes decreased with increasing polyrotaxane content, while the annealing temperature increased. All of the sSEBS-based, polyrotaxane composite membranes annealed at $140^{\circ}C$ showed a higher selectivity parameter, suggesting their potential usage for DMFCs.

UV-assisted surface modification of polyethersulfone (PES) membrane using TiO2 nanoparticles

  • Singh, Shruti;Karwa, Vinay;Marathe, K.V.
    • Membrane and Water Treatment
    • /
    • v.9 no.6
    • /
    • pp.393-403
    • /
    • 2018
  • In this research commercial polyethersulfone (PES) membrane was modified using $TiO_2$ nanoparticles (P-25 Degussa) and further irradiated using UV light to overcome the hydrophobicity and fouling nature of the membrane. Further the membranes were characterized using SEM and FTIR. Contact angle measurements study confirmed the hydrophilic tendency of the modified membrane by decreasing the contact angle from $73^{\circ}$ to $20.28^{\circ}$. The modified membranes showed higher flux and better anti-fouling properties as compared to the unmodified counterparts. The optimum conditions were found to be 0.5 wt% $TiO_2$ loading with 60 min membrane immersion and 10 min UV light illumination. The effect of different pH conditions of feed was analysed. Real wastewater filtration experiments also indicated better performance of modified membranes as opposed to neat PES membranes.

Synthesis and Characterization of Fluorinated Polybenzimidazole Proton Exchange Membranes for Fuel Cell (연료전지용 불소화 폴리벤즈이미다졸 양성자 교환 멤브레인 합성 및 특성평가)

  • KIM, AE RHAN
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.28 no.1
    • /
    • pp.24-29
    • /
    • 2017
  • A fluorinated polybenzimidazole (FPBI) was synthesized from 3,3-diaminobenzidine (DAB) of tetraamine, 2,2-bis(4-carboxyphenyl)hexafluoropropane of aromatic biscarboxylic acid, and 4,4-sulfonyldibenzoic acid of aromatic biscarboxylic acid in polyphosphoric acid (PPA). A FPBI was easily cast and made into clear films. The structure of condensation polymers and corresponding membranes were analyzed using GPC (gel permeation chromatography), $^1H$-NMR ($^1H$ nuclear magnetic resonance) and FT-IR (fourier transform infrared). TGA (thermogravimetric analysis) analysis showed that the prepared membranes were thermally stable, so that elevated temperature fuel cell operation would be possible. The proton conductivity of the FPBI membranes increased with increasing temperatures in the polymer. A FPBI membrane has a maximum ion conductivity of 45 mS/cm at $90^{\circ}C$ and 100% relative humidity.