• Title/Summary/Keyword: membrane chemistry

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Sythesis of Polyamidesulfamide Acid as a New Proton-Conductive Membrane

  • Tago, T.;Morishita, N.;Nishide, H.
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.121-123
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    • 2004
  • Sulfonamide moiety, RNSO$_2$, has been studied as biologically active compounds such as antibacterials.$^1$ Bissulfonylimide group,-SO$_2$NHSO$_2$-, has been introduced to the side chain of Nafion$^{(R)}$ to be the base moiety for an acid doping.$^2$However, to the best of our knowledge, there has been no report on SULFAMIDE ACID(Scheme 1), one of the sulfonic acid derivatives.(omitted)d)

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Effect of different conditions on pervaporation dehydration in CA/NYL66 blend membrane

  • Kazemzadeh, Akram;Mousavi, Seyed M.;Mehrzad, Jamshid;Motavalizadehkakhky, Alireza;Hosseiny, Malihesadat
    • Membrane and Water Treatment
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    • v.10 no.6
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    • pp.441-449
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    • 2019
  • In this study, cellulose acetate (CA) / nylon66 (NYL66) (95/5) blend membranes with different thicknesses were prepared by a solvent evaporation method. The effects of membrane thickness (almost $7-25{\mu}m$), feed concentration (70-95 wt.% isopropanol), and feed temperature ($30-60^{\circ}C$) were investigated on the performance of membrane in the separation of isopropanol-water mixtures. With regard to the results of sorption experiments, it was found that the increase of feed temperature enhanced the overall sorption while by increasing feed concentration, the overall sorption passed through a maximum value at 70 wt. % isopropanol (IPA). The best separation factor 3080.51 was gained at high isopropanol concentration 95 wt.%, low feed temperature $30^{\circ}C$, and high membrane thickness $24.62{\mu}m$. Regarding the pervaporation separation index, the obtained results showed that proper values for the thickness of membrane, feed temperature, and isopropanol concentration in feed were $24.62{\mu}m$, $40^{\circ}C$, and 70 wt.%, respectively.

A New PVC-Membrane Electrode Based on a Thia-Substituted Macrocyclic Diamide for Selective Potentiometric Determination of Silver Ion

  • Shamsipur, Mojtaba;Kazemi, Sayed Yahya;Niknam, Khodabaksh;Sharghi, Hashem
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.53-58
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    • 2002
  • A new PVC-membrane electrode for $Ag^+$ ion based on a thia-substituted macrocyclic diamide has been prepared. The electrode exhibited a Nernstian response for $Ag^+$ over a wide concentration range $(1.7{\times}10^{-6}-1.0{\times}10^{-1}M)$. It has a response time <15 s and can be used for at least 3 months without divergence. The proposed membrane sensor revealed good selectivities for $Ag^+$ over a variety of metal ions and can be used in a pH range 3.0-7.5. It has been used successfully for direct determination of $Ag^+$ in different real samples and, as an indicator electrode, in the titration of silver ion.

Propagating Spiral Waves Obtained in a Catalyst-Immobilized Gel Membrane by the Belousov-Zhabotinsky Reaction System

  • Kim, Bong-Seong;Jo, Eun-Ae;Basavaraja, C.;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1956-1962
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    • 2010
  • The formation of diverse spiral waves was studied in a polyacrylamide gel membrane with ruthenium(4-vinyl-4'-methyl-2,2'-bipyridine)bis(2,2'-bipyridine)bis(hexafluorophosphate) by a gas-free Belousov-Zhabotinisky (BZ) reaction system containing 1,4-cyclohexanedione (1,4-CHD). The gel membrane was found to be receptive for observing propagating waves since a clearer wave-train is obtained during a long reaction time without any disturbance from the immobilized metal catalyst which can be dissolved into the highly acidic solution of the BZ system. The distinctive waves in the system basically depend on both $BrO_3$ and 1,4-CHD in the initial phase, and are influenced by the intensity of illumination of visible light.

Membrane Formation of Polyacrylonitrile and Its Copolymer

  • Ha, Seong-Yong;Park, Ho-Bum;Nam, Sang-Yong;Lee, Young-Moo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04b
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    • pp.34-35
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    • 1997
  • The phase inversion is a significant phenomena in the preparation of membranes and wet spinning. In both these processes, a viscous dope solution is precipitated in a nonsolvent bath and a porous structure is formed under certain conditions. Such structure could have been considered as a diffusion controlled process. The membrane formation of the polymer solution includes both phase separation and gelation. We have studied the influence of variables on the final structure and tried to control the porosity and ultrafiltration(UF) performance of the polyacrylonitrile(PAN) and its copolymer.

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