Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A New PVC-Membrane Electrode Based on a Thia-Substituted Macrocyclic Diamide for Selective Potentiometric Determination of Silver Ion

  • Published : 2002.01.20
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Abstract

A new PVC-membrane electrode for $Ag^+$ ion based on a thia-substituted macrocyclic diamide has been prepared. The electrode exhibited a Nernstian response for $Ag^+$ over a wide concentration range $(1.7{\times}10^{-6}-1.0{\times}10^{-1}M)$. It has a response time <15 s and can be used for at least 3 months without divergence. The proposed membrane sensor revealed good selectivities for $Ag^+$ over a variety of metal ions and can be used in a pH range 3.0-7.5. It has been used successfully for direct determination of $Ag^+$ in different real samples and, as an indicator electrode, in the titration of silver ion.

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References

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