• Title/Summary/Keyword: melting temperature ($T_m$)

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Heat Transfer in Heat Storage System with P.C.M. - Inward Melting in a Vertical Tube (상변화 물질을 사용한 축열조에서의 열전달 - 수직원관에서의 내향용융 실험 -)

  • Shon, H.S.;Hwang, T.I.;Lee, C.M.;Choi, G.G.;Yim, C.S.
    • Solar Energy
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    • v.9 no.1
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    • pp.53-61
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    • 1989
  • In the present investigation, experiments on the melting of a phase change material were performed to research heat transfer phenomena generated by means of conduction and natural convection in the vertical tube at inward melting. The phase change material used in the experiments is 99 percent pure n-Docosane paraffin which is measured melting temperature of $42.5^{\circ}C$, latent heat of 37.5 cal/g, heat conductivity of $0.1505W/m^{\circ}C$. Experiments were performed both in the no-subcooling which is initiating it at melting temperature of phase change material, and in the subcooling which means to initiate it under melting temperature of phase change material, in order to compare and investigate the horizontal temperature history, vertical temperature history, ratio of melting and melted mass, figure of the melting front in the vertical tube. In the experimental results, heat transfer from tube wall to phase change material were due to conduction at early stage and due to natural convection with the passage of time, and then occurred melting downward from surface by volumetric expansion. Natural convection affects temperature distribution in the tube, ratio of melting and melted mass, figure of the melting front and then progress rapidly in case of nosubcooling compared to subcooling.

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Numerical Analysis for Thermal Design of Electronic Equipment Using Phase Change Material (상변화 물질을 이용한 전자 장비 방열 설계의 수치 해석적 연구)

  • Lee, Dong Kyun;Lee, Won Hee;Park, Sung Woo;Kang, Sung Wook;Cho, Ji Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.285-291
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    • 2017
  • In this study, a case analysis for thermal design of electronic equipment using a phase change material(PCM) was performed numerically using ANSYS Fluent. Experiments were conducted to find the temperature increase(${\Delta}T_m$), melting temperature($T_m$), and volume expansion of the PCM under the melting process. To verify the accuracy of the Fluent solver model, $T_m$, ${\Delta}T_m$, and the melting time were compared with experimental results. To simulate the temperature stagnation phenomenon under the melting process, the equivalent specific heat method was applied to calculate the thermal properties of the PCM in the solver model. To determine the thermal stability of electronic equipment, we paid special attention to finding a thermal design for the PCM using fins. Further, an additional numerical analysis is currently underway to find an optimum design.

Synthesis of Thermotropic Polyurethanes Containing Imide Units and Their Mesophase Behavior

  • Lee, Dong-Jin;Kong, Ju-Shik;Kim, Han-Do
    • Fibers and Polymers
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    • v.1 no.1
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    • pp.12-17
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    • 2000
  • Thermotropic polyurethanes were synthesized from 1,6-hexane diisocyanate (HDI) as a diisocyanate, 1,6-hexane diol (HD), and rigid diols containing imide unit such as N,N'-bis(4-hydroxyphenyl)-3,4,3',4'-biphenyl-dicarboxyimide (BPDI) or bis-N-(4-hydroxyphenyl)-4,4'-oxydiphthalimide (ODPI). The effects of structure difference between BPDI and ODPI and composition of HD/BPDl (ODPI) on the thermal and liquid crystalline behavior were studied. Thermotropic polyurethanes with an inherent viscosity of 0.59~0.70 were obtained. The melting temperature of BPDI-based polyurethanes were in the range of 150~$290^{\circ}C$, however, those of ODPI-based polyurethanes were in the range of 150~$190^{\circ}C$. All the polyurethanes based on ODPI (25~100 mole %) clearly exhibited a stable liquid crystalline phase, and BPDI-based polyurethane having 5-25% of BPDT showed a mesophase. The melting and isotropization temperatures ($T_m$, $T_i$) and ΔT($T_i$ - $T_m$) increased with increasing BPDI and ODPI content. The polyurethanes based on BPDI has higher melting points and thermal stability compared to ODPI-based polyurethanes.

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Alkaline Weight Reduction and Physical Properties of 0.01d Polyester Ultramicro Fiber (0.01d 폴리에스테르 초극세 섬유의 알칼리 감량과 물성)

  • Park, Jae-Min;Jeong, Dong-Seok;Rho, Hwan-Kown;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.18 no.4
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    • pp.37-42
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    • 2006
  • Two kinds of sea-island type polyester ultramicro fibers (fiber fineness : 0.01 and 0.05 denier) were treated with NaOH varying time and concentration. Surface morphology of the treated fibers with alkaline weight loss was observed by SEM. The treated effects were investigated by measuring density, melting temperature, and X-ray diffraction patterns. The surface morphology of the polyester ultramicro fiber was changed by NaOH concentration. Weight loss of 0.01d fiber was much larger than that of 0.05d fiber. Density and crystallinity were increased with weight loss of fiber. After the weight loss had finished, the density and crystallinity were decreased because of attack of island partition of the fiber. A melting temperature$(T_m)$ is $250^{circ}$ at untreated fiber on the whole and in 0.05d fiber the $(T_m)$ is $252^{circ}$ at untreated. In 0.01d fiber the $(T_m)$ was increased with weight loss of fiber.

¹H NMR Study of the Effect of G-T Mismatches on Dynamics and Stability of d(GCGTGCGC)₂ and Its Berenil Complex

  • 허성호;홍석주;이조웅;정채준
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.1045-1052
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    • 1996
  • The effects of G-T mismatches on thermal stability, the base-pair lifetime and the global structure of a d(GCGTGCGC)2 duplex were studied by using 1H NMR, UV and CD spectroscopy. The existence of G-T mismatches was found to cause a noticeable change in the chemical environment of imino protons associated with significant decrease in the base-pair lifetime at the mismatched site as well as in thermal stability of the duplex itself. The melting transition of d(GCGTGCGC)2 was not cooperative at all at 100 mM or lower concentration of NaCl, but became cooperative at 500 mM or higher NaCl concentration. The melting temperature (Tm) of this duplex was 32℃ at 500 mM concentration of NaCl, which is much lower than that of d(GCGCGCGC)2 at the same NaCl concentration. This suggests that the decrease in stability may be ascribed to the decrease in the base-pair lifetime and the deviation from the normal structure due to the G-T mismatches. Adding berenil to d(GCGTGCGC)2 caused no observable change in the global structure but the large decrease in the base-pair lifetime and the stability of the duplex.

Bead Formation and Wire Temperature Distribution during Ultra-high-speed GTA Welding Using Pulse-heated Hot-wire

  • Shinozaki, K.;Yamamoto, M.;Mitsuhata, Koichi;Nagashima, Toshiharu;Kanazawa, T.;Arashin, H.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.226-234
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    • 2009
  • The purpose of this study was to investigate the melting phenomenon of filler wire in detail and to obtain the precise temperature distribution of filler wire during GTA welding under the ultra-high welding speed condition in order to develop the ultra-high-speed GTA welding process with the pulse-heated hot-wire system by using three kinds of materials. The melting phenomenon of filler wire was observed using a high-speed camera and the temperature distribution of filler wire was measured using a radiation thermometer. From the above result, the adequate welding conditions of each material to make the GTA welding process with the ultra-high welding speed could be obtained. The ultra-high-speed GTA welding process needed the adequate wire current in order to obtain the adequate temperature distribution and the adequate melting position of filler wire. Moreover, the temperature distributions of three kinds of filler wire could be estimated by using the proposed simple estimation method.

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The Effect of Sintering Parameters on the Densification Behavior of PM High Speed Steel (분말 고속도공구강의 소결 조건에 따른 치밀화 거동연구)

  • 김용진
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.190-197
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    • 1994
  • The densification behavior during a sintering of M2 and T15 grade high speed steel powder compacts was reported. Sintered densities over 98% theoretical were achieved by a liquid phase sintering in vacuum for both grades. The optimum sintering temperature range where full densification could be achieved without excessive carbide coarsening and incipient melting was much narrower in M2 than in T15 grade. The sintering response was mainly affected by the type of carbides present. The primary carbides in M2 were identified as $M_6C$ type whereas those in T15 were MC type which provides wider sintering range. The addition of elemental carbon up to 0.3% lowered the optimum sintering temperature for both grades, but had little effect on expanding the sintering range and sintered structure.

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Instability and Transition of Nonparallel Bouyancy-Induced Flows Adjacent to an Ice Surface Melting in Water (얼음 벽면의 융해율을 고려한 비평행 자연대류에서 유동의 불안정성과 천이에 관한 연구)

  • Hwang, Y.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.3
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    • pp.437-450
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    • 1996
  • A set of stability equations is formulated for natural convection flows adjacent to a vertical isothermal surface melting in cold pure water. It takes account of the nonparallelism of the base flows. The melting rate is regarded as a blowing velocity at the ice surface. The numerical solutions of the linear stability equations which constitute a two-point boundary value problem are accurately obtained for various values of the density extremum parameter $R=(T_m-T_{\infty})/(T_0-T_{\infty})$ in the range $0.3{\leq}R{\leq}0.6$, by using a computer code COLNEW. The blowing effects on the base flow becomes more significant as ambient temperature ($T_{\infty}$) increases to $T_{\infty}=10^{\circ}C$. The maximum decrease of heat transfer rate is about 6.4 percent. The stability results show that the melting at surface causes the critical Grashof number $G^*$ and the maximum frequency of disturbances to decrease. In comparision with the results for the conventional parallel flow model, the nonparallel flow model has a higher critical Grashof number but has lower amplification rates of disturbances than does the parallel flow model. The spatial amplification contours exhibit that the selective frequency $B_0$ of the nonparallel flow model is higher than that of the parallel flow model and that the effects of melting are rather small. The present study also indicates that the selective frequency $B_0$ can be easily predicted by the value of the frequency parameter $B^*$ at $G^*$, which comes from the neutral stability results of the nonparallel flow model.

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Cyclic Creep Strain of Cu Pure Metal (CU 순금속의 사이클릭 크리프 변형)

  • Jeong, S.U.;Lee, H.S.
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.194-199
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    • 2000
  • The creep rate is affected by the temperature and in fact. if the temperature above $T_M/2(T_M:melting\;point)$. The aim of the present investigation is to study the relationship of static creep and cyclic creep behavior of pure copper and the formulation of these phenomena with the special attention to the instantaneous strain. strain rate from time and number of cycles have the same inclination Steady state creep rate depend upon maximum stress and can be expressed as linear function according to Power law creep equations Creep rupture time has relation with creep rate. and it make a group represented as the same direct line regardless of max stress, stress ratio and the temperature. Initial strain effect on continuous creep deformation. and have guantitative relationship between elastic and Plastic strain. LMP have similar tendency than OSDP and MHP according to temperature

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Thermal Behavior of Hwangto and Wood Flour Reinforced High Density Polyethylene (HDPE) Composites

  • Lee, Sun-Young;Doh, Geum-Hyun;Kang, In-Aeh
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.5
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    • pp.59-66
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    • 2006
  • The thermal properties of wood flour, Hwangto, and maleated polyethylene (MAPE) reinforced HDPE composites were investigated in this study. The thermal behavior of reinforced wood polymer composites was characterized by means of thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. Hwangto and MAPE were used as an inorganic filler and a coupling agent, respectively. According to TGA analysis, the increase of wood flour level increased the thermal degradation of composites in the early stage, but decreased in the late stage. On the other hand, Hwangto reinforced composites showed the higher thermal stability than virgin HDPE, from the determination of differential peak temperature ($DT_p$). Decomposition temperature of wood flour and/or Hwangto reinforced composites increased with increase of heating rate. From DSC analysis, melting temperature of reinforced composites little bit increased with the addition of wood flour or Hwangto. As the loading of wood flour or Hwangto to HDPE increased, overall enthalpy decreased. It showed that wood flour and Hwangto absorbed more heat energy for melting the reinforced composites. Hwangto reinforced composites required more heat energy than wood flour reinforced composites and virgin HDPE. Coupling agent gave no significant effect on the thermal properties of composites. Thermal analyses indicate that composites with Hwangto are more thermally stable than those without Hwangto.