• Title/Summary/Keyword: melamine

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Preparation and characterization of melamine resin microcapsules by in-istu polymerization. (In-situ 중합법에 의한 마이크로캡슐의 제조 및 특성분석)

  • 백남중;박연흠;김영준
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.316-319
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    • 2001
  • 기능성 섬유는 원하는 기능을 발휘할 수 있는 기능성 물질을 섬유 또는 직물상에 물리적 혹은 화학적으로 처리함으로써 제조할 수 있다. 그러나 이러한 기능성 물질들이 물리적 혹은 화학적으로 불안정하거나 섬유에 대한 친화력이 약할 경우에는 기능성 물질들의 내구성이 저하되는 문제점이 발생한다. 이러한 문제점을 마이크로캡슐을 이용한 가공기술로 극복하려는 노력이 있었다. (중략)

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난연.기능성 복합성형체 제조 및 특성

  • 현병민;강영구
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.05a
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    • pp.457-460
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    • 2002
  • 현재 건축단열재, 흡음재, 바닥재로 사용되는 panel 성형, 제작하기 위해 다종의 유기고분자 matrix가 사용되고 있으며 polyurethane, vinyl acetate, urea-formaldehyde resin 또는 melamine-formaldehyde, phenol-form aldehyde resin 등을 사용하고 있으나 이러한 고분자 matrix를 사용한 건축용 panel의 경우 화재시 유독 gas와 더불어 급격한 화재전파의 매개체로 사용될 수 있어 난연제 첨가로 이러한 현상을 억제하고 있다.(중략)

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Development of New Fibers Related Sensitivity and comfortability -Preparation of Melamine Microcapsules Containing Fragrant oil and the Their Application- (감성기능 섬유신소재의 개발(I) - 방향성 멜라민 마이크로캡슐의 제조와 응용 -)

  • Hong, Ki Jeong;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.76-83
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    • 1996
  • Fragrant microcapsules were prepared by in situ polymerization using urea-formaldehyde prepolymer. Lemon oil and migrin oil as susceptible materials were used. The diameter and distribution of the microcapsule were controlled by several factors, such as wall material, core material content, emulsion agent and stirring speed, respectively. Susceptible cotton fabrics with fragrant release functionality were successfully produced by using microcapsule containing fragrant materials.

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The Effects of PCM Capsule Sizes on the Properties of Acrylic Coatings (PCM 캡슐의 크기가 아크릴 코팅의 물성에 미치는 영향)

  • Hur, Soon-Ryoung;Lee, Sung-Goo;Choi, Kil-Yeong;Lee, Jae Heung;Hong, Geun-Hye;Kim, Hyung-Joong
    • Journal of Adhesion and Interface
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    • v.6 no.1
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    • pp.11-18
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    • 2005
  • The capsules were prepared from a phase change material (PCM) of octadecane as a core material and melamine formaldehyde resin as a shell material. The PCM capsule size was varied in the range of $3{\sim}25{\mu}m$. The core contents and sizes of the PCM capsule, were determined by DSC and SEM, respectively. An acrylic coating material which contains butyl acrylate (BA), methyl metacrylate (MMA) and acrylic acid (AA) were synthesized by emulsion polymerization. The films were prepared from the acrylic emulsion and PCM capsules which have various capsule sizes. From the results of SEM experiment, it was observed that the PCM capsules were well dispersed inside the film and the surface of the film became less rough when the PCM capsule size was small. The swelling ratio of the films were not significantly affected by the PCM capsule size. However, the tensile strength and elongation of the films were greatly decreased with increasing the PCM capsule size.

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Synthesis of Vinyl-nano Silica Ball Composite : Its Application to Clearcoat (비닐-나노실리카볼 화합물의 클리어코트 특성 연구)

  • Kim, Bong-Gyeom;Park, Gun-Hee;Lee, Yong-Hwa;Noh, Seung-Man;Lee, Jae-Woo;Park, Seung-Kyu
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.670-675
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    • 2010
  • Inorganic-organic hybrid material such as vinyl-nano sized silica ball was synthesized by acrylo-alkoxysilane and nano silica ball with different particle size. And then they were formulated into acrylic-melamine clearcoat. This material is fully characterized with various analytical methods and applied for strength measurement. The glossy effect, matting effect and anti-scratching properties of materials were investigated for further growth and maintenance. When the particle size of nano silica ball is 20~30 nm, the glossy retain effect was increased by 7% compared to bare acrylic-melamine clearcoat. When a commercially available silica Aerosil 200 (Hydrophilic fumed silica, average particle size 12 nm, Degussa) react with vinyl alkoxysilane vinyl-fumed silica complex form. The vinyl-fumed silica along with clearcoat increases only 2% increase at glossy retain. Nano-scratch test results also support the glossy retain effect of vinyl nano-sized silica ball in clearcoat.

Infrared Radiative Heat Transfer Characteristics of Fiber Mat Catalytic Burners (매트촉매 버너의 적외선 복사열전달 특성)

  • Song, Kwang Sup;Choi, Jung In
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1049-1055
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    • 2012
  • The fiber mat catalytic burner that uses infrared radiative heat obtained by flameless catalytic combustion was manufactured and tested to investigate its combustion characteristics. About 9 to 17% of combustion heat was released by sensible heat during the premixed catalytic combustion depend on combustion condition. To find out radiation intensity with distance between catalytic burner and sample, the equation that calculate the receiving surface of radiative energy under the fiber mat catalytic burner was driven. This equation was well correlated with the drying rate of melamine. The drying experiments were carried out to the melamine, wood chip and agricultural pallet by using the fiber mat catalytic burner and the energy efficiency was calculated from drying rate of them. The energy efficiency of the fiber mat catalytic burner reaches to 79% in maximum for drying of the wood chip.

Bonding Performance of Adhesives with Lamina in Structural Glulam Manufactured by High Frequency Heating System

  • Kim, Keon-Ho;Kim, Se-Jong;Yang, Sang-Yun;Yeo, Hwanmyeong;Eom, Chang-Deuk;Shim, Kugbo
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.682-690
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    • 2015
  • The bonding performance of two types of wood adhesives, namely phenol-resorcinol-formaldehyde (PRF) resin and melamine-urea-formaldehyde (MUF) resin for glued laminated timber manufactured by high frequency (HF) heating was evaluated. The HF heating system consists of HF oscillator with dielectric heating system for curing adhesives, and hydraulic press system for clamping glued laminated timber. The designed frequency and output power of the HF system was as 5 MHz and 60 kW, respectively. To verify dielectric heating mechanism under HF oscillation, the heat loss factors of laminae and adhesives were measured. The results show that it is possible to selectively heat adhesives for their curing due to the remarkably higher loss factor of the adhesives than those of wood laminae. The temperature of adhesive in the bonding line reached up to the set temperature within a few seconds by high frequency oscillating, which advanced the curing of adhesive afterwards. The bonding performance, such as shear strength of bonding line, water soaking delamination, and boiling water soaking delamination of PRF resin met the requirement of Korean Standard (KS), however the MUF resin did not meet the KS requirement of boiling water soaking delamination. These results indicate that the HF heating system is successful to manufacture glued laminated timbers with PRF resins to meet the bonding requirements.

Preparation and Properties of PVP (poly-4-vinylphenol) Gate Insulation Film For Organic Thin Film Transistor (유기박막 트랜지스터용 PVP (poly-4-vinylphenol) 게이트 절연막의 제작과 특성)

  • Baek, In-Jae;Yoo, Jae-Hyouk;Lim, Hun-Seung;Chang, Ho-Jung;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.4 s.37
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    • pp.359-363
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    • 2005
  • The organic insulation devices with MIM (metal-insulator-metal) structures as PVP gate insulation films were prepared for the application of organic thin film transistors (OTFT). The co-polymer organic insulation films were synthesized by using PVP(poly-4-vinylphenol) as solute and PGMEA (propylene glycol monomethyl ether acetate) as solvent. The cross-linked PVP insulation films were also prepared by addition of poly (melamine-co-formaldehyde) as thermal hardener. The leakage current of the cross-linked PVP films was found to be about 300 pA with low current noise. and showed better property in electrical properties as compared with the co-polymer PVP insulation films. In addition, cross-linked PVP insulation films showed better surface morphology (roughness), showing about 0.11${\~}$0.18 nF in capacitance for all PVP film samples.

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Dyeing Properties Resin Treatment Effects of the Lyocell Fabrics (리오셀 직물 수지가공 효과와 염색성)

  • Yoo, Hye-Ja;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.7
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    • pp.1095-1103
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    • 2008
  • The effects of resin finish and dyeabilities of four kinds of Iyocell fabrics that were manufactured by four kinds of pulps were investigated. The dyeabilities of Iyocell fabrics were similar, but differed from cotton fabric. In early stage of 30 minutes, cotton fabric was shown higher dye exhaustion ratio than Iyocell fabrics, however after then cotton fabric did not increase dye exhaustion, Iyocell fabrics increased continuously. At last, the dye exhaustion ratio of Iyocell fabrics were about 75% and that of cotton fabric was 65%. Two kinds of experimental procedures were applied for Iyocell fabrics. One was what the fabrics were treated with resins and washed with cellulase, and then dyed with reactive dyes. The other procedure was the fabrics were dyed with reactive dyes, and then applied the resin treatments and cellulase washing. After fibrillation and washing the undyed Iyocell fabric and the Iyocell fabric that was dyed with C.I.Reactive Red 120, their weight loss ratios were 3.5% and 2.8%, respectively. Dyeing with reactive dyes caused the crosslinking between cellulose and dyes and the crosslinking decreased fibrillation. The weight loss by enzyme washing of Iyocell fabrics decreased by the glyoxal and melamine resin treatments. The reduction of weight loss can be caused by fibrillation decrease. Dyeing and resin treating can be showed the synergic effect on the reduction of fibrillation. The effect of glyoxal resin on the reduction of fibrillation was a little better than that of melamine resin.

Study on Self-Healing Asphalt Containing Microcapsule (마이크로캡슐이 내재된 자기치유 아스팔트에 관한 연구)

  • Kwon, Young-Jin;Hong, Young-Keun
    • Elastomers and Composites
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    • v.48 no.3
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    • pp.232-240
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    • 2013
  • Microcapsules having healing agent were prepared in which 2,6-dimethylphenol (DMP) as a healing agent forms the core and melamine/formaldehyde resin forms the shell. Microcapsule-contained asphalts showed better mechanical properties than non-contained ones. And as the rest time passed the impact strength of microcapsule-contained asphalt was getting higher than that of asphalt without the microcapsule. As the rest time of 15 days passed, the original strength was restored. This tells that microcapsule-contained asphalt had the ability of self-healing. X-ray photos proved that DMP on asphalt fracture surface, which were burst out of the microcapsules when cracks occurred on asphalt, were polymerized to polyphenyleneoxide and this PPO covered the crack and healed the damage.