• Journal of Mechanical Science and Technology
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• v.18 no.8
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• pp.1375-1387
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• 2004

A solution is given for the elastodynamic problem of a crack perpendicular to the graded interfacial zone in bonded materials under the action of anti plane shear impact. The interfacial zone is modeled as a nonhomogeneous interlayer with the power-law variations of its shear modulus and mass density between the two dissimilar, homogeneous half-planes. Laplace and Fourier integral transforms are employed to reduce the transient problem to the solution of a Cauchy-type singular integral equation in the Laplace transform domain. Via the numerical inversion of the Laplace transforms, the values of the dynamic stress intensity factors are obtained as a function of time. As a result, the influences of material and geometric parameters of the bonded media on the overshoot characteristics of the dynamic stress intensities are discussed. A comparison is also made with the corresponding elastostatic solutions, addressing the inertia effect on the dynamic load transfer to the crack tips for various combinations of the physical properties.

• Journal of Mechanical Science and Technology
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• v.15 no.7
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• pp.823-830
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• 2001

The single fiber pull-out technique has been commonly used to characterize the mechanical behavior of fiber/matrix interface in fiber reinforced composite materials. In this study, an improved analysis considering the effect of thermal residual stresses in both radial and axial directions is developed for the single fiber pull-out test. It is found to have the pronounced effects on the stress transfer properties across the interface and the interfacial debonding behavior.

• Carbon letters
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• v.11 no.2
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• pp.102-106
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• 2010

In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor ($K_{IC}$), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.

• Polymer(Korea)
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• v.27 no.2
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• pp.91-97
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• 2003

The effect of fluorination of nanoscaled silicas on mechanical interfacial properties and thermal stabilities of the silica/polyurethane composites was investigated. The surface properties of the silica were studied in X-ray photoelectron spectroscopy and contact angle measurements. Their mechanical interfacial properties and thermal stabilities of the composites were characterized by tearing energy and decomposition activation energy, respectively. As experimental results, the London dispersive component of surface free energy and fluorine functional groups of silica surfaces were increased as a function of fluorination temperature resulting in improving the trearing energy ($G_{IIIC}$) of the composites. Also, the thermal stabilities of the composites were increased as the treatment temperature increases. These results could be explained that the fluorine functional groups on silica surfaces played an important role in improving the intermolecular interactions at interfaces between silicas and polyurethane matrix in a composite system.

• Composites Research
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• v.15 no.6
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• pp.16-23
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• 2002

In this work, the effect of anodic oxidation on surface characteristics of high strength PAN-based carbon fibers was investigated in mechanical interfacial properties of composites. The surface properties of the carbon fibers were determined by acid-base values, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and contact angles. And their mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). As a result, the acidity or the $O_{ls}/C_{ls}$ ratio of carbon fiber surfaces was increased, due to the development of the oxygen functional groups. Consequently, the anodic oxidation led to an increase in surface free energy of the carbon fibers, mainly due to the increase of its specific (or polar) component. The mechanical interfacial properties of the composites, including ILSS and $K_{IC}$, had been improved in the anodic oxidation on fibers. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between fibers and epoxy resin matrix.

• Elastomers and Composites
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• v.37 no.4
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• pp.258-264
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• 2002

In this work, the influence of thermal treatment on surface properties of silicas and mechanical interfacial properties of silicas/polyurethane composites was investigated. The surface properties of thermally treated silicas were studied in the context of Fourier Transform-IR (FT-IR), solid-state 29Si NMR spectroscopy, and contact angle. And the mechanical interfacial properties of the silica/polyurethane composites were evaluated by composite tearing energy (GIIIC). As a result, it was found that the thermally treated silica surfaces became hydrophobic in nature, due to the condensation of surface hydroxyls and the formation of siloxane bonds, resulting in increasing the London dispersive component of surface free energy. From which, the increase of the London dispersive component of the silicas led to an improvement of the dispersion of silicas in a polyurethane matrix, finally resulting in improving the tearing energy (GIIIC) of the silicas/polyurethane composites.

• Polymer(Korea)
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• v.37 no.1
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• pp.61-65
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• 2013

In this work, the anodic oxidation of carbon fibers was carried out to enhance the mechanical interfacial properties of carbon fibers-reinforced epoxy matrix composites. The surface characteristics of the carbon fibers were studied by FTIR, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Also, the mechanical interfacial properties of the composites were studied with interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and critical strain energy release rate ($G_{IC}$). The anodic oxidation led to a significant change in the surface characteristics of the carbon fibers. The anodic oxidation of carbon fiber improved the mechanical interfacial properties, such as ILSS, $K_{IC}$, and $G_{IC}$ of the composites. The mechanical interfacial properties of the composites anodized at 20% sulfuric/nitric (3/1) were the highest values among the anodized carbon fibers. These results were attributed to the increase of the degree of adhesion at interfaces between the carbon fibers and the matrix resins in the composite systems.

• Textile Coloration and Finishing
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• v.29 no.2
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• pp.77-85
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• 2017

The interfacial adhesion between fiber and matrix affects the physical properties of fiber reinforced composites. In this study, 3-(Methacryloyloxy)propyltrimethoxy silane(MPS) coupling agent was used to increase the interfacial adhesion between polyketone fiber and epoxy resin. The change of surface chemical composition of polyketone fiber treated with MPS was analyzed using a FTIR-ATR. The interfacial bonding between fiber and resin increased with silane coupling agent largely. Consequently, interfacial shear strength(IFSS) was enhanced with increasing concentration of MPS coupling agent and thus, the physical properties of the composites such as flexural properties and dynamic mechanical properties were changed. Flexural strength and modulus increased when the MPS concentration was higher than 0.5wt%. The dynamic storage modulus of Polyketone/Epoxy composites treated with MPS was higher than that of the untreated one. When the MPS concentration of 3wt%, the highest storage modulus was obtained.

• Composites Research
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• v.31 no.5
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• pp.282-287
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• 2018

In this paper, we explore interfacial properties of the mineralized CNTs when they are employed as reinforcing fillers in a polymer nanocomposite using molecular dynamics (MD) simulations. Recently, several studies on mineralizing carbon nanotubes (CNTs) with an aid of nitrogen doping to CNTs have been reported. However, there is a lack of studies on the reinforcing effects of the mineralized CNTs when it is employed as a filler of nanocomposites. Silica ($SiO_2$) is used as a mineral material and poly (methyl metacrylate) (PMMA) is used as a polymer matrix. Pull-out simulations are conducted to obtain the interfacial energy and the interfacial shear stress. It was found that the silica mineralized CNTs have higher interfacial interaction with the polymer matrix. In the future, by examining various thermomechanical properties of the mineralized-CNT-filler/polymer nanocomposites, we will search for potential applications of the novel reinforcing filler.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.108-111
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• 2004

The polypropylene(PP) fiber is poised as a low cost alternative for reinforcement in structural applications in comparison with other high performance fibers, such as the polyvinyl-alcohol(PVA), polyethylene, carbon and aramid fiber. The mechanical properties of the composite are strongly determined by the interfacial behavior of fiber and cementitious matrix. The crack bridging mechanism contribute to composite toughness from activation of the fiber-matrix interface where energy is dissipated through debonding of the interface and fiber pullout. In this study, therefore, the pullout behavior of PP fibers is investigated. Experimental work includes the investigation of the interfacial properties, and the composite property. The quantification of interfacial properties, the frictional bond is achieved through single fiber pullout test. A study on the effect of inclination angle on fiber pullout behavior is also conducted.