• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.317-322
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• 2012

The microstructures were examined by SEM, FT-IR spectra, tensible properties mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly industries have led to the development of solvent-free formulations that can be cured. We had synthesized the polyurethane resin having the ability to protect stainless steel against corrosion. Compared with general packing materials and coatings, this resin is highly stronger in intensity and longer durability. Polyurethane resins were composed of polyols, IPDI, silicone surfactant, catalyst and crosslink agent. Moreover, thermal fillers such as $Al_2O_3$, fume silica and $ZrO_2$ not only accelerated the curing rate but also improved the physical property as thermal barriers. The rigid segments of polyurethane in mechanical properties were due to crosslink agent and the increase of [NCO/OH]. In conclusion, the polyurethane microstructure with crosslink agent can be good material for themoset coating of metal substrates such as stainless steel.

• Applied Chemistry for Engineering
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• v.3 no.2
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• pp.318-326
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• 1992

Vinylester resin was synthesized by reacting epoxy resin with MAA(methacrylic acid) at a equivalent ratio of 1.1/1.0 in the presence of N,N dimethyl benzylamine. Low molecular weight epoxy(DER 331) was used together with higher molecular weight epoxy(DER 662, DER 664) and a novolac epoxy(DEN 439), and the amount of DER 331 was not over 50% of the total epoxy components. Viscosity, cure time and mechanical properties of the vinylester resin were profoundly influenced by the quantity of reacted MAA, and the structure and molecular weight of the epoxy resin. Tensile and flexural strength appeared to be the greatest when DER 331 fraction was 30~40%.

• Polymer(Korea)
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• v.26 no.1
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• pp.71-79
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• 2002

RPP(maleic-anhydride grafted PP)and OPS(oxazoline grafted PS) do not react to each other, and thus show immiscibility. In this study, Nylons was added to RPP/OPS blend systems, as a reactive compatibilizer for enhancing the miscibility of the blends. When Nylon6 was added to the blends of RPP and OPS, RPP/Nylon6/OPS was produced. The effects of the molar ratio of Nylon6 on the RPP-Nylon6-OPS reaction were studied. Torque test and FT-IR analysis have been carried out to investigate the reaction of RPP/Nylon6/OPS system. The reaction torgue ratio and reaction efficiency show the maximum values at 1 : 0.66 : 1 and 1 : 1 : 1 (in moles) for RPP/Nylon6/OPS. In the RPP/Nylon6/OPS blends, their mechanical properties were changed with the molar ratio of Nylon6 and showed the highest value at molar ratio of 1.5. Physical properties and compatibility of RPP/Nylon6/OPS were compared with those of PP/Nylon6/OPS. Consequently, RPP/Nylon6/OPS plays a proper role as a reactive compatibilizer to the PP/PS blend system.

• Journal of Adhesion and Interface
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• v.12 no.4
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• pp.105-110
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• 2011

Polyester/melamine cured coatings had been used for pre-primed coatings and pre-coated metal coatings, because it has good mechanical,chemical properties, and mar resistance. But it has weak points such as stiffness and low formability for making automotive components. Polyester had been synthesized using polycarbonate diol of long alkyl chain which can improve flexibility and formability which is one of the important factors for pre-coated steel sheets (PCM). In this study, strain and tensile strength were examined by the tensile test and formability was examined by the drawing test. Also, Those polyester resins were also measured by DMA to verify flexibility of cured coatings.

• Journal of the Korean Geosynthetics Society
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• v.20 no.4
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• pp.33-41
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• 2021

Feldspar, along with Quartz, are the most frequently produced minerals in Korea; however, the potential value is estimated to be significantly low because of the scarce research on the development and application of material properties, except for their limited use in manufacturing minerals, glass, and paints. In this study, we analyzed the eco-friendly material and reactivity improvement characteristics of weathered feldspar through activation technique. The joint structural features observed on the surface of the weathered feldspar show that the joint arrangements are irregularly distributed, and the cavities are interconnected. Due to the irregularly connected cavities on the surface of weathered feldspar, the reaction area of the weathered feldspar is increased; hence the weathered feldspar is considered as a highly reactive pozzolan material when combined with cement. As a result of applying the thermal, mechanical, and chemical activation techniques to improve the functionality of the weathered feldspar, the cation exchange capacity, density, and uniaxial compression strength characteristics were improved. It is considered that weathered feldspar by these porous characteristics can be used as an eco-friendly construction material with excellent physical and chemical properties.

• Journal of Mechanical Science and Technology
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• v.16 no.7
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• pp.966-974
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• 2002

An analytic approach has been employed to study condensate film thickness distribution inside cave-shaped cavity of a flat plate heat pipe. The results indicate that the condensate film thickness largely depends on mass flow rate and local velocity of condensate. The increasing rate of condensate film for circular region reveals about 50% higher value than that of vertical region. The physical properties of working fluid affect significantly the condensate film thickness, such as the condensate film thickness for the case of FC-40 are 5 times larger than that of water. In comparison with condensation on a vertical wall, the average heat transfer coefficient in the cave-shaped cavity presented 10∼15% lower values due to the fact that the average film thickness formed inside the cave-shaped cavity was larger than that of the vertical wall with an equivalent flow length. A correlation formula which is based on the condensate film analysis for the cave-shaped cavity to predict average heat transfer coefficient is presented. Also, the critical minimum fill charge ratio of working fluid based on condensate film analysis has been predicted, and the minimum fill charge ratios for FC-40 and water are about Ψ$\_$crit/=3∼7%, Ψ$\_$crit/=0.5∼1.3% respectively, in the range of heat flux q"=5∼90kW/㎡.

• Journal of the Korean Society for Nondestructive Testing
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• v.13 no.4
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• pp.9-17
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• 1994

It is well recognized recently that ultrasonic technique is one of the most widely used methods of nondestructive evaluation to characterize material properties of nonconventional engineering materials. Therefore it is very important to understand physical phenomenon on propagation behavior of elastic wave in these materials, which is directly associated with ultrasonic signals in the test. In this study, the theoretical analysis on multi-scattering of harmonic elastic wave due to the particulate with interface between matrix and fiber in metal matrix composites(MMCs) was done on the basis of Lax's quasi-crystalline approximation and extinction theorem. SiC particulate (SiCp) reinforced A16061-T6 composite material was chosen for this analysis. From this analysis, frequency dependences of phase velocity and amplitude attenuation of effective plane wave due to the change of volume fraction of SiC particulate were clearly found. It was also shown that the interface condition between matrix and fiber in MMCs gives a direct effect on the variation of phase velocity of plane wave in MMCs.

• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.5
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• pp.579-589
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• 1985

The storage tank of the natural-circulation-solar-hot-water system equipped with flat-plate solar collectors is located at higher elevation than the solar collectors. Therefore, the heat loss from the system due to a reversed flow during the night-time is an important factor as well as the day-time thermal performance of the system. The thermal performance of the natural-circulation-solar-hot-water system with flat-plate solar collectors during the day-time depends mainly on the heat collecting efficiency of the solar collectors, whereas its thermal performance during the night-time depends on the system configuration , such as the elevation of the water storage tank with respect to the solar collectors and the piping connections between the storage tank and the solar collectors, as well as thermo-physical properties of the circulating fluid. In the present work, a computer program has been developed to simulate a typical natural-circulation-solar-hot-water-system, and a series of simulation tests have been carried out with the computer program to examine the thermal performance of the system during the day-time as well as the hight-time. In addition , a series of experiment have been conducted under a real sun condition using a natural-circulation-solar-hot-water-system constructed and installed at the KAIST building to compare with the results obtained from computer simulations.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.5 s.248
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• pp.405-412
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• 2006

In order to realize a stably propagating flame in a narrow channel, flame instabilities resulting from flame-wall interaction should be avoided. In particular flame quenching is a significant issue in micro combustion devices; quenching is caused either by excessive heat loss or by active radical adsorptions at the wall. In this paper, the relative significance of thermal and chemical effects on flame quenching is examined by means of quenching distance measurement. Emphasis is placed on the effects of surface defect density on flame quenching. To investigate chemical quenching phenomenon, thermally grown silicon oxide plates with well-defined defect distribution were prepared. ion implantation technique was used to control defect density, i.e. the number of oxygen vacancies. It has been found that when the surface temperature is under $300^{\circ}C$, the quenching distance is decreased on account of reduced heat loss; as the surface temperature is increased over $300^{\circ}C$, however, quenching distance is increased despite reduced heat loss effect. Such abberant behavior is caused by heterogeneous surface reactions between active radicals and surface defects. The higher defect density, the larger quenching distance. This result means that chemical quenching is governed by radical adsorption that can be parameterized by oxygen vacancy density on the surface.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.308-312
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• 2022

3D printing technology, which creates a physical object by various material deposition, has been widely used in recent years in the manufacturing field because of its advantages. Among the various printing technologies, droplet-based 3D printing technology (e.g., Polyjet^®) enables a high-resolution printing using photocurable materials such as hydrogels. Depending on the degree of light exposure, ejected photocurable droplets may have different properties (e.g., viscosity) until they collide with the substrate and it leads to the different spreading behaviors of the droplets (i.e., impact, spreading, and recoiling) during deposition on the substrate. In this study, experimental observation and analysis of the changes in hydrogel droplet viscosity and spreading behavior according to the light exposure were carried out based on high-speed image processing.