• Title/Summary/Keyword: maximum absorption

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Effect of nitrogen concentration on the microstructures of AlN thin films fabricated by reactive RF sputtering (반응성 RF 마그네트론 스퍼터링으로 증착한 AlN 박막의 특성에 질소농도 변화가 미치는 영향)

  • Lim, Dong-Ki;Kim, Byoung-Kyun;Jeong, S.W.;Roh, Yong-Han
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.367-367
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    • 2008
  • Aluminum nitride (AlN) thin films have been deposited on Si substrate by using reactive RF magnetron sputtering method in a gas mixture of Ar and $N_2$ at different $N_2$ concentration. It was found that $N_2$ concentration was varied in the range up to 20-100%, highly c-axis oriented film can be obtained at 50% $N_2$ with full width at half maximum (FWHM) $4.5^{\circ}$. Decrease in surface roughness from 7.5 nm to 4.6 nm found to be associated with decrease in grain size, with $N_2$ concentration; however, the AlN film fabricated at 20% $N_2$ exhibited a granular type of structure with non-uniform grains. The absorption peak was observed around 675 $cm^{-1}$ in fourier transform infrared spectroscopy (FTIR). It is concluded that the AlN film deposited at $N_2$ concentration of 50% exhibited the most desirable properties for the application of high-frequency surface acoustic devices.

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Degradation of Phenolic Resin, Resole by Microbial Consortia (미생물 컨소시엄에 의한 페놀수지 Resole의 분해)

  • 오계헌;최원식
    • KSBB Journal
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    • v.13 no.2
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    • pp.220-222
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    • 1998
  • Three microbial consortia were screened for their ability to degrade phenolic resin, resole as a sole carbon source. These microbial consortia were derived from soil samples collected from a phenolic resin manufacturing plant site. Among the consortia, the test consortium, designated as MS2, displayed approximately 70% degradation of the substrate, 100 mg of resole per liter, within the fist twelve days of incubation but the degradation was inhibited. During the incubation period, pH was decreased from 7.0 to 2.7, and the resole degradation became inhibited under the conditions. UV-scans of spent culture showed that the wavelength of maximum absorption was 261 nm for resole.

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A Numerical Study on the Heat Transfer Characteristics of a Metal Hydride Reactor with Embedded Heat Pipes (내부에 히트파이프를 삽입한 메탈 하이드라이드 반응기의 열전달 특성에 대한 수치해석 연구)

  • Park, Young-Hark;Boo, Joon-Hong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2346-2351
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    • 2008
  • This study deals with heat pipes inserted into the metal hydride(MH) reactor to increase the effective thermal conductivity of the system and thus to enhance the thermal control characteristics. A numerical analysis was conducted to predict the effect of inserted heat pipes on the heat transfer characteristics of MH, which inherently has extremely low thermal conductivity. The numerical model was a cylindrical container of O.D. 76.3 mm and length 1 m, which is partially filled with about 60% of MH material. The heat pipe was made of copper-water combination, which is suitable for operation temperature range between $10^{\circ}C$ and $80^{\circ}C$. Both inner -and outer- heat pipes were considered in the model. Less than two hours of transient time is of concern when decreasing or increasing the temperature for absorption and discharge of hydrogen gas. FLUENT, a commercial software, was employed to predict the transient as well as steady-state temperature distribution of the MH reactor system. The numerical results were compared and analyzed from the view point of temperature uniformity and transient time up to the specified maximum or minimum temperatures.

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Fluorescence Enhancement of 7-Diethylamino-4-methylcoumarin by Noncovalent Dipolar Interactions with Cucurbiturils

  • Park, Mee Ock;Moon, Myung Gu;Kang, T.J.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1378-1382
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    • 2013
  • We have investigated the complex forming behavior of cucurbit[6]urils(CB6) and cucurbit[7]urils(CB7) with 7-diethylamino-4-methylcoumarin(C460) in water. The electronic absorption maximum of C460 shows bathochromic shift with the addition of CB7 and fluorescence intensity is greatly increased, while CB6 has no noticeable effects on the spectroscopic properties of C460. It is noted that CB7 interacts more strongly with C460 than CB6 does. Fluorescence lifetime also significantly increased for the CB7 complex, which is attributed to reduced polarity surrounding C460 and/or C460 being in a restricted environment. The stoichiometry for the complex formation determined from the fluorescence titration measurement indicates that 2:1 complex in which two CB7 molecules bind to C460 is formed. Thus, two step equilibrium processes are suggested for the complex formation and the binding constants are estimated. The semi-empirical electronic structures calculations indicate that C460 is not included in the CB7 cavity but interacts noncovalently with the portal carbonyls of CB7.

Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals [(Ni (II), Pb (II), Cd (II)] by Electrocoagulation Method

  • Khosa, Muhammad Kaleem;Jamal, Muhammad Asghar;Hussain, Amira;Muneer, Majid;Zia, Khalid Mahmood;Hafeez, Samia
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.316-321
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    • 2013
  • Electrocoagulation (EC) technique is applied for the treatment of wastewater containing heavy metals ions such as nickle (Ni), lead (Pb) and cadmium (Cd) by using sacrificial anodes corrode to release active coagulant flocs usually aluminium or iron cations into the solution. During electrolytic reactions hydrogen gas evolve at the cathode. All the experiments were carried out in Batch mode. The tank was filled with synthetic wastewater containing heavy metals and efficiency of electro-coagulation in combination with aluminum and iron electrodes were investigated for removal of such metals. Several parameters, such as contact time, pH, electro-coagulant concentration, and current density were optimized to achieve maximum removal efficiency (%). The concentrations of heavy metals were determined by using Atomic Absorption Spectroscopy (AAS). It is found that the electro-coagulation process has potential to be utilized for the cost-effective removal of heavy metals from wastewater specially using iron electrodes in terms of high removal efficiencies and operating cost.

A study on the dielectric dispersion of vulcanized natural rubber (가황에 의한 천연고무의 유전분산에 관한연구)

  • Lee, Joon-Ung;Kim, Hak-Ju
    • Elastomers and Composites
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    • v.18 no.2
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    • pp.51-59
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    • 1983
  • The dielectric properties of polymers are very important when investigating the molecular structure of polymers. The characteristics of the dielectric absorption in vulcanized natural rubber were studied in frequency ranging from 10[KHz] to 32[MHz] at the temperature of 25[$^{\circ}C$]. As a result of the study, it has been confirmed that natural rubber vulcanized below 4phr leads to two kinds of dielectric losses due to the interfacial polarization and the dipole polarization by sulfur, and of above 7[%] was only a loss due to the dipole polarization by sulfur. Futhermore, the dielectric loss maximum $tan{\delta}$ spectrum, removed to the low frequency in accordance with increasing sulfur, depends greatly on sulfur. The volume resistivity of $10^{7}{\sim}10^{11}[{\Omega}{\cdot}cm}]$, regardless of whether the crosslinking of rubber is weakened by sulfur, was observed.

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Characteristics of Photo-conversion Glass with $Eu^{3+}$ and Its Use 1 (Glass Production and Photo-conversion Characteristics) ($Eu^{3+}$가 첨가된 광변환 유리의 특성과 효과연구 1(유리의 제조와 특성))

  • Chung, Hun-S.;Ahn, Yang-K.;Kil, Dae-S.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.4
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    • pp.44-50
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    • 2002
  • Photosynthesis of plants is effective in the range of 550 to 700 nm of the wavelength of solar irradiation. If the conversion of ultraviolet to the above mentioned region is possible, the photosynthesizing ability is expected to be enhanced. $Eu^{3+}$ doped soda-lime bulk and $TiO_2-SiO_2$ sol-gel coated glasses were prepared and their spectroscopic properties were studied. The absorption and emission spectra for the specimens were measured with the changes of wavelength and Eu ion concentration in the range of the wavelength of 300 to 700nm. The transmittance intensity of visible light through the bulk glass and the coated one was unchanged with the addition of Eu element. The emission spectrum intensity of $Eu^{3+}$ was found to be the maximum at 618 nm which is a transition of $^5DO{\rightarrow}^7F_2$. Additionally, it was shown that the intensity was linearly increased up to 10% of the Eu concentration.

Pharmacokinetic Changes of Acebutolol after Orall Administration in Rabbits with Diabetes Mellitus Induced by Alloxan

  • Choi, Dong-Hyun;Bae, Hak-Yeon;Choi, Jun-Shik
    • Archives of Pharmacal Research
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    • v.26 no.6
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    • pp.499-503
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    • 2003
  • Because physiological changes that potentially alter pharmacokinetics occurs in diabetes mellitus patients, pharamacokinetics of drugs used in the treatment of hypertension was studied using acebutolol as a model anti-hypertensive drug. Thus, the pharmacokinetics of acebutolol was investigated after oral administration of acebutolol (15 mg/kg) to control rabbits and rabbits with acute or chronic diabetes mellitus induced by alloxan. Kidney and liver functions were documented for acute and chronic diabetes mellitus groups based on plasma chemistry data. After oral administration of acebutolol to acute and chronic groups, the plasma concentrations appeared higher; As a result, area under the plasma concentration-time curve from time zero to time infinity10575 and 8668 $\mu g\cdot$ h/mL for acute and chronic group, respectively. In comparison, the area was apparently smaller in the control group (i.e., 7132 $\mu g\cdot$ h/mL). The half-life in acute groups was significantly prolonged 8.45 h compared with the half-life in the control group (i.e., 6.30 h). Alteration in acebutolol pharmacokinetics was more pronounced in the acute group as evidenced by the significantly higher values the area under the plasma concentration time curve, absorption rate constant and maximum plasma concentration compared with chronic or control group. Therefore, these observations indicate that acebutolol pharmacokinetics may be affected in patients with diabetes mellitus, especially in the early stage of the disease.

Effect of Starter of Flour Ferment by Lactobacillus acidophilus on Physical Properties of Noodle Dough (Lactobacillus acidophilus로 발효시킨 밀가루 발효물의 첨가가 면 반죽의 물성에 미치는 영향)

  • Cha, Wook-Jin;Lee, Si-Kyung
    • Korean Journal of Food Science and Technology
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    • v.37 no.5
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    • pp.801-805
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    • 2005
  • Practical use of wheat flour ferment with L. acidophilus during noodlemanufacturing was investigated. Water absorption decreased and overall mechanical tolerance index increased with ferment addition up to 20%. Amylograph of flour with ferment showed initial gelatinization temperatures of control, and 5% ferment-and ferment-added groups were equal. Maximum viscosity decreased by ferment addition. L, b and a values of dough increased proportionally with added ferment. Color of doughs with ferment was generally ligher. Total color difference of doughs added with ferment was higher than that of control group.

Analysis of naturally Dyed Textile Fabrics by using Aronia Extract (아로니아 추출물에 의한 직물의 천연염색과 염액의 Spectrum 분석)

  • Won, Ah Young;Kim, Jongjun
    • Journal of Fashion Business
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    • v.22 no.1
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    • pp.124-134
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    • 2018
  • This study examined the dyeing characteristics and spectrum of cotton and silk by using dyeing solution extracted from aronia. The value $L^{\ast}$ which indicates the brightness of cotton regardless of mordant increases with increasing pH from pH 3.5 to pH 10.5. The color difference value(${\Delta}E$) of the cotton was generally high in pH 3.5 regardless of mordant existence. The silk showed the highest ${\Delta}E$ value in pH 3.5 dye solution as cotton did. On the other hand, the silk with mordant dyed showed the highest ${\Delta}E$ value in pH 7. Silk fabrics dyed with Aronia solution turns out red in pH 3.5, blue in pH 7 and yellow in pH 10.5. This is because of the amino acid, one of the silk ingredients, combines with a part of anthocyanin to show blue. As the result of the spectrum measurement, the maximum absorption wavelength of Aronia solution was increased in the order of pH 10.5, pH 3.5 and pH 7, regardless of extraction temperature and mordant. The measurement results of color fastness to washing and color fastness to light are generally low. Therefore, there is a need for further study to improve color fatness in the future.