• Title/Summary/Keyword: maximum absorption

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A Study on Hospital Wasted Plastic by the Pyrolysis over Catalyst (촉매첨가에 의한 병원폐플라스틱의 열분해 처리에 관한 연구)

  • 윤오섭;김수생
    • Journal of Environmental Health Sciences
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    • v.13 no.2
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    • pp.51-63
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    • 1987
  • We identified pyrolysis condition, effect of catalyzer and pyrolysis mechanism through contact decomposed method by adding Bentonite in waste plastic of hospital solid waste. The result from this study were summarized as the followings: 1. The optimum fuel oil were obtained when hospital wasted plastic (P.P) and Bentonite were mixed in the ratio of 30:1. 2. Maximum absorption wave of hospital wasted plastic (P.P) appeared at 2900cm$^{-1}$, 1480cm$^{-1}$, 1360cm$^{-1}$ and 1180 cm$^{-1}$ by FT-IR and the plastics were identified and confirmed. 3. Reaction temperature of hospital wasted plastic started at 360$\circ$C, proceed rapidly at 437.5$\circ$C and finished at 481$\circ$C. The residue was 0.729%. When bentonire was added started at 318$\circ$C, proceed rapidly at 399.5$\circ$C and finished at 449.3$\circ$C, the residue being 4.23%. 4. Pyrolysis products of hospital wasted plastic were about 90 kinds. The Main components were 2-Heptene-3-ethyl-4-trimethyl (27.4%), 1-Heptene-2-isobutyl-6-methyl (8.6%) and 1-Heptene decene (7.7%). There was little component difference at different temperature. This is the result from stability of decomposition product. 5. Pyrolysis efficiency increased by the addition Bentonire. 6. Some of the Environmental and Sanitary problems could be solved by the pyrolysis of hospital wasted plastic and the decomposed products were to be used as fuel oil.

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Evaluation of Total, Water-soluble and Hexavalent Chromium Contents in Construction Materials(Concretes, Cements)

  • Choi, In-Ja;Yoon, Chung-Sik;Choi, Sang-Jun
    • Journal of Environmental Health Sciences
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    • v.33 no.6
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    • pp.497-501
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    • 2007
  • The objective of the study is to determine the contents of total chromium, water-soluble chromium and hexavalent chromium in cements and concretes specimens taken from manufacturing or construction sites. Chromate is an allergen that is widespread in the environment and is richly contained in cements. Metals were extracted with microwave oven and analyzed by atomic absorption spectrometer. Hexavalent chromium was analysed by ion chromatography. The concentrations of total chromium, water-soluble chromium and hexavalent chromium in cements were $36.02{\sim}108.01,\;15.95{\sim}89.01\;and\;26.77{\sim}89.61\;mg/kg$, respectively. The concentrations of hexavalent chromium in cements were higher than 2 mg/kg, a maximum value recommended in Northern European Countries. The concentrations of total chromium, water-soluble chromium and hexavalent chromium in concretes were $17.44{\sim}76.25,\;0.98{\sim}17.71\;and\;ND{\sim}24.13\;mg/kg$, respectively. Especially Hexavalent chromium was detected only from concrete specimens from construction sites. It is oxidized or reduced status by environmental condition or surrounding materials.

Dyeability and Functionality of Chaenomelis Fructus Extract (모과 추출물의 염색성과 기능성)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Fashion & Textile Research Journal
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    • v.14 no.3
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    • pp.478-485
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    • 2012
  • The dying properties of fabrics with Chaenomelis Fructus extract were studied through an investigation of the characteristic of Chaenomelis Fructus colorants, the effect of dyeing conditions (dye temperature, dyeing concentration, and times on dye uptakes), effect of mordant, effect of UV irradiation, and color change in addition, antimicrobial ability and deodorant ability were estimated. In the UV-Visible spectrum, the wavelength of maximum absorption of Chaenomelis Fructus extract was 280 nm and showed that tannin is the major pigment component. From the increase of absorbance by UV irradiation, it was assumed that catechol tannin color was developed through UV irradiation. An increased dyeing concentration resulted in a larger dye uptake. Dye uptake increased as the dyeing time and temperature increased. Chaenomelis Fructus extract showed relatively good affinity to silk than cotton. Mordant, Fe and Cu were effective to increase the dye uptake of cotton fabric in addition, the dye uptake of silk fabric mordanted with Fe and K improved. UV irradiation let the color of dyed fabrics develop regardless of the UV irradiation stage however, UV irradiation on the dyed fabric was more effective than on the extract for the color development. Dyed silk fabric showed very good antimicrobial abilities of 99.9% in addition, deodorant ability improved in the fabric dyed with Chaenomelis Fructus extract.

In situ reduction of gold nanoparticles in PDMS matrices and applications for large strain sensing

  • Ryu, Donghyeon;Loh, Kenneth J.;Ireland, Robert;Karimzada, Mohammad;Yaghmaie, Frank;Gusman, Andrea M.
    • Smart Structures and Systems
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    • v.8 no.5
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    • pp.471-486
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    • 2011
  • Various types of strain sensors have been developed and widely used in the field for monitoring the mechanical deformation of structures. However, conventional strain sensors are not suited for measuring large strains associated with impact damage and local crack propagation. In addition, strain sensors are resistive-type transducers, which mean that the sensors require an external electrical or power source. In this study, a gold nanoparticle (GNP)-based polymer composite is proposed for large strain sensing. Fabrication of the composites relies on a novel and simple in situ GNP reduction technique that is performed directly within the elastomeric poly(dimethyl siloxane) (PDMS) matrix. First, the reducing and stabilizing capacities of PDMS constituents and mixtures are evaluated via visual observation, ultraviolet-visible (UV-Vis) spectroscopy, and transmission electron microscopy. The large strain sensing capacity of the GNP-PDMS thin film is then validated by correlating changes in thin film optical properties (e.g., maximum UV-Vis light absorption) with applied tensile strains. Also, the composite's strain sensing performance (e.g., sensitivity and sensing range) is also characterized with respect to gold chloride concentrations within the PDMS mixture.

Dyeing properties and colorimetric characteristics for cellulose fabrics dyed with indigo by different reducing conditions (쪽 염료의 환원조건에 따른 섬유소 직물의 염색성과 색채특성)

  • Shin, Judong;Choi, Jongmyoung
    • The Research Journal of the Costume Culture
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    • v.24 no.6
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    • pp.777-787
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    • 2016
  • This study was carried out in order to provide useful data for planning fabrics of summer eco-friendly fashion products. The fabrics used in this study were four cellulose fibers: cotton, cotton/mulberry blended, flax, and flax/lyocell blended. Dyeing with natural indigo was carried out under three different reducing conditions (i.e., general, eclectic, and eco-friendly) that have different reducing agent and pH levels, and hydrosulfite and glucose were used as a reducing agent. The dye uptake (K/S value) of fabrics dyed with natural indigo by a reducing condition was the highest at 660nm. Regardless of the fabrics, dye uptake was the highest under the general reducing condition and the lowest under the eco-friendly reducing condition. Under different reducing conditions, the dye uptake of natural indigo fabrics with the maximum absorption wavelength indicated a difference. The colorfastness of cellulose fabrics that were dyed with natural indigo had a rate of 4 to 5 except for rubbing fastness, which indicated good colorfastness. Additionally, natural indigo-dyed cotton and flax fabrics had good antibiosis. When the color characteristics of fabrics dyed with natural indigo were measured, all of the three reducing conditions created purple blue (PB) colors, and the color characteristics of dyed fabrics by reducing condition and fabric showed significant differences.

Mid-infrared Continuous-wave Optical Parametric Oscillator with a Fan-out Grating MgO:PPLN Operating Up to 5.3 ㎛

  • Bae, In-Ho;Yoo, Jae-Keun;Lim, Sun Do;Kim, Seung Kwan;Lee, Dong-Hoon
    • Current Optics and Photonics
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    • v.3 no.6
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    • pp.577-582
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    • 2019
  • We report on a continuous-wave (cw) optical parametric oscillator (OPO) optimized for mid-infrared emission above 5.0 ㎛. The OPO is based on a magnesium-oxide-doped periodically poled LiNbO3(MgO:PPLN) crystal with a fan-out grating design. A linear two-mirror cavity resonating both at the pump and signal wavelengths is stabilized to the pump laser by using the modified Pound-Drever-Hall (PDH) method. The idler wavelength is continuously tunable from 4.7 ㎛ up to 5.3 ㎛ by varying the poling period of the fan-out grating crystal. Pumped by a diode-pumped solid state (DPSS) laser with a power of 1.1 W at 1064 nm, the maximum idler output power is measured to be 5.3 mW at 4.8 ㎛. The output power above 5.0 ㎛ is reduced to the hundreds of ㎼ level due to increased absorption in the crystal, but is stable and strong enough to be measured with a conventional detector.

Characteristics of Er-Doped Fiber Laser on Resonator Reflectivities and Pump Power (공진기 반사율과 펌프 파워에 따른 어븀 광섬유 레이저의 특성)

  • 박서연;이학규;김경헌;이동한
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.286-290
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    • 1994
  • Lasing characteristics of an Er-doped fiber laser have been investigated at various conditions of resonator reflectivities and pump powers. Variation of the laser wavelength with various mirror reflectivities has been compared with the theoretical analysis based on absorption, gain spectra, and resonator parameters. The maximum slope efficiency of 38% was obtained with the resonator's mirror reflectivities of 100% and 4% on both sides, and the threshold powers were varied from 7.8 mW to 5.6 mW, and lasing wavelengths were varied $1.532\mum to 1.563\mum and 1.558 \mum to 1.570 \mum$ for 6 and 15.8 mlong Er-doped fiber, respectively, as the resonator reflectivities were changed from 0.0016 to 0.9.to 0.9.

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A Study on the Bleaching and Dyeing Properties of Cotton Fabrics Treated with Ozone($O_{3}$) (Ozone($O_{3}$)을 이용한 선직물의 표백과 양색성에 관한 연구)

  • Cho, Hwan;Woo, Hyun-Seok;Jung, Hee-Chun
    • Textile Coloration and Finishing
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    • v.7 no.1
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    • pp.32-42
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    • 1995
  • In order to reduce the amount of waste water generated from textile dyeing process and processing water, cotton fabric was bleached with ozone in ozone/water contact system, and dyed. The results obtained from the measurement of whiteness, reflectance, tensile strength, color difference, and K/S value of treated samples were as follow : 1) In ozone bleaching, factors affect whiteness most are treatment time and ozone dosage. As treatment time is lengthened, whiteness increases. Futhermore, bleaching effect is high in acidic treatment, but low in alkaline treatment. 2) As bleaching goes on, maximum absorption wave length shifts to shoter wavelengths. 3) As treatment time is lengthened or pH of treatment is low, tensile strenth of treated fabric decrease. 4) In all cases, color difference of dyed cotton fabrics in above 2% o.w.f. dyestuff concentration don't go beyond 1∼2 AN unit, compared with standard.

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Spectrometric determination of Nicotine alkaloid with barbituric acid buffer (바르비트릭산 완충액에 의한 니코틴 알카로이드의 비색 정량)

  • 김신일;김찬호
    • Journal of the Korean Society of Tobacco Science
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    • v.2 no.2
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    • pp.14-19
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    • 1980
  • The spectrophotometric determination of nictotine content with barbituric acid buffer solution was carry out. Absorption maximum for the proposed solution appeared at 505 nm and the absorbance remained stable for 15 minute at pH 4.2. Lambert-Beer law was proved to be applicable in the range of nicotine concentration of $7.5\mu{g}/ml$~$25\mu{g}/ml$. According to the analysis of nicotine contents in Burley and Flue-cured tobacco leaves by this method, the relative deviation was obtained to be 2.8% in comparision with the Griffith method.

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Determination of Mercury Ion in Contaminated Soil by Rhodamine B Hydrazide (형광화학센서를 이용한 용출기반 토양 수은 오염조사)

  • Kim, Kyungtae;Park, Junboum
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.1-5
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    • 2016
  • Rhodamine B Hydrazide as a novel fluorescent and colorimetric probe exhibiting remarkably selective fluorescence enhancement toward Hg2+ ion over other 16 metal ions is herein introduced. The probe reacts with Hg2+ ion followed by its spirolactam ring-opening to give a remarkable enhancement of absorption maximum at 550 nm as well as an enhanced fluorescence intensity at 580 nm in aqueous media. Upon titration with Hg2+ ion in various concentration of 10~200 uM, we found that the probe shows a marked color change from colorless to pink, enabling naked-eye detection toward mercury ion. In addition, in the presence of Hg2+ ion, the probe gave rise to change from non-florescence to strong orange fluorescence (Off-On) with a good linearity of R2=0.97. This preliminary results demonstrate that the fluorescent chemosensor we herein introduced can open a new strategy for marked selective and sensitive detection of mercury ions in contaminated soil containing various metal ions.