• 한국환경농학회지
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• 제34권1호
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• pp.21-29
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• 2015

BACKGROUND: Heavy metal adsorptionnot only depends on biochar characteristics but also on the nature of the metals involved and on their competitive behavior for biochar adsorption sites. The goal of this study was to investigate the competitive absorption characteristics of Cu and Cd in mono-metal and binary-metal forms by biochar derived from Phragmites communis. METHODS AND RESULTS: Batch and column experiments were conducted to evaluate the competitive adsorption characteristics of the biocharfor Cu and Cd. In the batch experiments, the maximum adsorption capacity of Cd(63 mg/g) by biochar was higher than that for Cu (55 mg/g) in the mono-metal adsorption isotherm. On the other hand, the maximum Cu adsorption capacity (40 mg/g) by biochar was higher than that for Cd(25 mg/g) in the binary-metal adsorption isotherm. Cu was the most retained cations. Cd could be easily exchanged and substituted by Cu. The amounts of adsorbed metals in the column experiments were in the order of Cd (121 mg/g) > Cu (96 mg/g) in mono-metal conditions, and Cu (72 mg/g) > Cd (29 mg/g) in binary-metal conditions. CONCLUSION: Overall, the results demonstrated that competitive adsorption among metals increased the mobility of these metals. Particularly, Cd in binary-metal conditions lost its adsorption capacity most significantly.

• 한국식품위생안전성학회지
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• 제17권3호
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• pp.146-151
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• 2002

2001년 1-12월 서울시 가락농수산물시장에서 총 951건의 수산물(어류 34종 468건, 패류 17종 373건, 갑각류 10종 39건 그리고 두족류 등 11종 71건)을 대상으로 중금속 함량[average(minimum∼maximum), Unit:mg/kg]을 분석한 결과, Hg 0.025(N.D.∼0.19), Cd 0.288(N.D.∼l.85), Pb 0.227(ND∼l.68)이었다. Hg의 경우, 패류[0.033(N.D.∼0.19)]>두족류 등[0.026N.D.∼0.11)]>갑각류[0.026(N.D.∼0.09)]>어류[0.018(N.D.∼0.19)]순이었고, 가장 높은 함량은 미꾸라지 (0.19)와 꼬막(0.19)이었으며, Pb의 경우 패류[0.223(N.D.∼1.38)]>어류[0.213(N.D.∼1.68)]>두족류 등 [0.151(N.D.∼0.39)]>갑각류[0.144(N.D.∼0.44)]순이었고, 가장 높은 함량은 미꾸라지 (1.68)>빙어(1.44)>바지락(1.38)>뱀장어(1.35) 순이었다. 한편, Cd의 경우 패류[0.288(N.D.∼1.85)] 중 가장 높은 함량은 꼬막(1.85)이었다.

• 한국어병학회지
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• 제21권2호
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• pp.107-117
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• 2008

The pharmacokinetic properties of oxytetracycline (OTC) were studied after dipping and oral administration to cultured olive flounder, Paralichthys olivaceus (600 g). Plasma concentrations of OTC were determined after oral dosage (50, 100 and 200 mg/kg body weight) and dipping (50, 100 and 200 ppm, 1 h) in olive flounder (average 600 g, 23±1℃). Plasma samples were taken at 3, 5, 10, 15, 24, 32, 48, 72, 120, 168 and 240 h post-dose. In oral dosage of 50, 100 and 200 mg/kg, the peak plasma concentrations of OTC, which attained at 3 h post-dose, were 0.34, 0.44 and 1.18 ㎍/㎖, respectively. In dipping of 50, 100 and 200 ppm, those of OTC which also observed at 5 h post-dose, were 0.43, 0.38 and 0.64 ㎍/㎖, respectively. Plasma concentrations of OTC were not measurable at 240 h post-dose in all experiments. The kinetic profile of absorption, distribution and elimination of OTC in plasma were analyzed fitting to a one-compartment model by WinNonlin program. The following parameters were calculated for a single dosage of 50, 100 and 200 mg/kg body weight, respectively: AUC (the area under the concentration-time curve)=31.40, 28.07 and 32.97 ㎍∙h/㎖; T1/2 (half-life)􀆫0.89, 1.12 and 0.43 h; Tmax (time for maximum concentration)= 5.25, 3.70 and 7.30 h, Cmax (maximum concentration)=0.25, 0.38 and 0.61 ㎕/㎖. Following dipping at 50, 100 and 200 ppm, these parameters were AUC􀆫15.51, 14.63 and 19.72 ㎍∙h/㎖; T1/2= 0.75, 0.41 and 0.74 h; Tmax=4.90, 7.08 and 4.68 h, Cmax=0.40, 0.32 and 0.46 ㎕/㎖.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.233-233
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• 2010

CdS thin films were deposited on glass substrates by R.F. magnetron sputtering method and some of the samples were treated by rapid thermal annealing (RTA) process. Effects of thermal annealing on structural and optical properties were investigated at different temperatures ranging from 100 to $600^{\circ}C$. The crystallographic structure of the films and the size of the crystallites in the films were studied by X-ray diffraction. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by annealing. Optical properties of the films were calculated using the envelope method and the photoluminescence measurements. The optical properties of the films were seen to be dependent on the film thicknesses. The energy gap of the films was found to decrease by annealing. The band edge sharpness of the optical absorption was seen to oscillate by thermal annealing. Annealing over $400^{\circ}C$ was seen to degrade the optical properties of the film. The best annealing temperature for the films was found to be $400^{\circ}C$ from the optical properties. It is observed that the CdS film annealed at $400^{\circ}C$ reveals the strongest UV emission intensity and narrowest full width at half maximum among the temperature ranges studied. The enhanced UV emission from the film annealed at $400^{\circ}C$ is attributed to the improved crystalline quality of CdS thin film due to the effective relaxation of residual compressive stress and achieving maximum grain size. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

• Toxicological Research
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• 제35권4호
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• pp.295-301
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• 2019

In this review, we describe the absorption rates (Caco-2 cell permeability) and hepatic/plasma pharmacokinetics of 53 diverse chemicals estimated by modeling virtual oral administration in rats. To ensure that a broad range of chemical structures is present among the selected substances, the properties described by 196 chemical descriptors in a chemoinformatics tool were calculated for 50,000 randomly selected molecules in the original chemical space. To allow visualization, the resulting chemical space was projected onto a two-dimensional plane using generative topographic mapping. The calculated absorbance rates of the chemicals based on cell permeability studies were found to be inversely correlated to the no-observed-effect levels for hepatoxicity after oral administration, as obtained from the Hazard Evaluation Support System Integrated Platform in Japan (r = -0.88, p < 0.01, n = 27). The maximum plasma concentrations and the areas under the concentration-time curves (AUC) of a varied selection of chemicals were estimated using two different methods: simple one-compartment models (i.e., high-throughput toxicokinetic models) and simplified physiologically based pharmacokinetic (PBPK) modeling consisting of chemical receptor (gut), metabolizing (liver), and central (main) compartments. The results obtained from the two methods were consistent. Although the maximum concentrations and AUC values of the 53 chemicals roughly correlated in the liver and plasma, inconsistencies were apparent between empirically measured concentrations and the PBPK-modeled levels. The lowest-observed-effect levels and the virtual hepatic AUC values obtained using PBPK models were inversely correlated (r = -0.78, p < 0.05, n = 7). The present simplified PBPK models could estimate the relationships between hepatic/plasma concentrations and oral doses of general chemicals using both forward and reverse dosimetry. These methods are therefore valuable for estimating hepatotoxicity.

• 한국전기전자재료학회논문지
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• 제32권1호
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• pp.86-92
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• 2019

Although perylene bisimide derivatives have advantages such as excellent thermal stability and high luminance efficiency, they have poor solubility characteristics in organic solvents. In this research, in order to improve the solubility characteristics, we prepared perylene bisimide derivatives (1C) and (2C) with swallow-tail substituted imide, which is known to lead to excellent solubility. The structures and properties of swallow-tail perylene bisimide (1C) and (2C) were analyzed by $^1H-NMR$, FT-IR, UV/Vis spectroscopy, and thermogravimetric analysis (TGA). The maximum absorption wavelengths of (1C) and (2C) in the UV/Vis spectrum were 558 nm and 556 nm, respectively, and the maximum emission wavelengths were 602 nm and 600 nm, respectively. In the TGA, (1C) demonstrated good thermal stability with less than 5 wt% weight loss up to $242^{\circ}C$. In the solubility test, (1C) and (2C) exhibited solubilities of more than 5 wt% in chloroform, ethyl acetate, and dimethylformamide, but not in methanol. When the compounds (1C) and (2C) were mixed with PMMA (polymethyl methacrylate), thin films showed peaks at 679 nm and 677 nm, respectively, in the photoluminescence spectra. (1C) was found to be a possible candidate as red organic phosphor for hybrid LEDs.

• Toxicological Research
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• 제35권2호
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• pp.131-136
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• 2019

Ethylhexyl dimethyl para-aminobenzoic acid (PABA) is an oily yellow liquid derivative of water-soluble PABA commonly used in sunscreen. Ethylhexyl dimethyl PABA is widely used as an ingredient in many cosmetics at an average concentration of 1.25% (0.5-2.0%) in Korea. Previous studies, including those involving animals, have demonstrated that ethylhexyl dimethyl PABA is toxic to the following four organs: testis, epididymis, spleen, and liver. In addition, experiments using human keratinocytes found that ethylhexyl dimethyl PABA inhibits cell growth and DNA synthesis at low concentrations, and halted the cell cycle of MM96L cells (human melanoma cell line) at the G1 phase. Despite limited clinical data in humans, many studies have confirmed increased mutagenicity of ethylhexyl dimethyl PABA following exposure to sunlight, which suggests that this molecule is likely to contribute to onset of sun-induced cancer despite protecting the skin through absorption of UVB. For risk assessment, the no observed adverse effect level (NOAEL) chosen was 100 mg/kg bw/day in a 4 weeks oral toxicity study. Systemic exposure dosage (SED) was 0.588 mg/kg bw/day for maximum use of ethylhexyl dimethyl PABA in cosmetics. Based on the risk assessment and exposure scenarios conducted in this study, the margin of safety (MOS) was calculated to be 180.18 for a sunscreen containing 8% ethylhexyl dimethyl PABA, which is the maximum level allowed by the relevant domestic authorities.

• 대한금속재료학회지
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• 제49권12호
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• pp.924-929
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• 2011

It is well known that grain boundary cavitation is the main failure mechanism in austenitic stainless steel under tensile hold creep-fatigue interaction conditions. The cavities are nucleated at the grain boundary during cyclic loading and grow to become grain boundary cracks. The attenuation of ultrasound depends on scattering and absorption in polycrystalline materials. Scattering occurs when a propagation wave encounters microstructural discontinuities, such as internal voids or cavities. Since the density of the creep-fatigue cavities increases with the fatigue cycles, the attenuation of ultrasound will also be increased with the fatigue cycles and this attenuation can be detected nondestructively. In this study, it is found that individual grain boundary cavities are formed and grow up to about 100 cycles and then, these cavities coalesce to become cracks. The measured ultrasonic attenuation increased with the cycles up to cycle 100, where it reached a maximum value and then decreased with further cycles. These experimental measurements strongly indicate that the open pores of cavities contribute to the attenuation of ultrasonic waves. However, when the cavities develop, at the grain boundary cracks whose crack surfaces are in contact with each other, there is no longer any open space and the ultrasonic wave may propagate across the cracks. Therefore, the attenuation of ultrasonic waves will be decreased. This phenomenon of maximum attenuation is very important to judge the stage of grain boundary crack development, which is the indication of the dangerous stage of the structures.

• Earthquakes and Structures
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• 제24권5호
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• pp.317-331
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• 2023

The buckling-restrained braced frames with eccentric configurations (BRBFECs) are stable cyclic behavior and high energy absorption capacity. Furthermore, they have an architectural advantage for creating openings like eccentrically braced frames (EBFs). In the present study, it has been suggested to use the performance-based plastic design (PBPD) method to calculate the design base shear of the BRBFEC systems. Moreover, in this study, to reduce the required steel material, it has been suggested to use the performance-based practical design (PBPD) method instead of the force-based design (FBD) method for the design of this system. The 3-, 6-, and 9-story buildings with the BRBFEC system were designed, and the finite element models were modeled. The seismic performance of the models was investigated using two suits of ground motions representing the maximum considered earthquake (MCE) and design basis earthquake (DBE) seismic hazard levels. The results showed that the models designed with the suggested method, which had lower weights compared to those designed with the FBD method, had a desirable seismic performance in terms of maximum story drift and ductility demand under earthquakes at both MCE and DBE seismic hazard levels. This suggests that the steel weights of the structures designed with the PBPD method are about 13% to 18% lesser than the FBD method. However, the residual drifts in these models were higher than those in the models designed with the FBD method. Also, in earthquakes at the DBE hazard level, the residual drifts in all models except the PBPD-6s and PBPD-9s models were less than the allowable reparability limit.

• 한국음향학회지
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• 제37권4호
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• pp.223-231
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• 2018

최근 여러 환경적인 요인으로 인해 기존의 자갈 도상의 터널에서 콘크리트 도상의 터널로 교체가 되고 있지만 콘크리트 도상 터널의 경우 자갈 도상의 터널 보다 소음에 악영향을 미치고 있어 부수적으로 소음에 대한 대책이 필요한 실정이다. 이러한 대책 중 하나로 흡음블록은 설치의 제약이 적고 쉽고 빠르게 설치가 가능하기 때문에 많은 철도에서 시범적으로 적용되고 있다. 하지만 실제 환경과 운영조건에서 흡음블록의 성능에 대한 검증이 필요한 실정이다. 본 논문에서는 터널 내의 흡음블록의 성능을 확인하기 위해 흡음블록의 소음저감효과의 예측뿐만 아니라 호남선의 달성터널의 일부 구간에 흡음블록 설치 전 후의 KTX 실내 소음을 측정하고 그 결과를 비교, 분석하였다. ISO 3381를 준용한 측정장비, 측정방법을 사용하여 고속철도차량 실내소음을 측정하였으며, 터널 내부 운행시간동안에 등가소음도를 계산했다. 또한 흡음블록의 주파수별 흡음특성과 객실내부 장치소음이 영향을 주는 주파수 영역의 영향을 고려하기 위하여 가청주파수 영역 전체에 대한 등가소음도 뿐만 아니라 1/3-octave band를 기초로 주파수 영역대별 영향도도 함께 분석하였다. 또한, 열차의 운행속도와 측정시의 환경조건 등을 고려하여 흡음블록의 실내소음에 대한 영향을 평가하기 위하여 달성터널 전후에 위치한 터널내부 소음 측정값을 사용하여 보정하였다. 측정 결과의 분석을 통하여 흡음블록위에서 주행 할 때 최대 6.8 dB(A) 저감량을 나타내었다. 최종적으로 열차실내소음에 대한 1/3-octave band SPLs(Sound Pressure Levels) 예측값과 실측값을 비교하여 흡음블록에 의한 소음저감 메커니즘에 대한 이해를 증진시켰다.