• 제목/요약/키워드: maximum absorption

검색결과 1,132건 처리시간 0.028초

Eye safety 라이다 센서용 황화납 양자점 기반 SWIR photodetector 개발 (Shortwave Infrared Photodetector based on PbS Quantum Dots for Eye-Safety Lidar Sensors)

  • 최수지;권진범;하윤태;정대웅
    • 센서학회지
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    • 제32권5호
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    • pp.285-289
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    • 2023
  • Recently, the demand for lidar systems for autonomous driving is increasing, and research on Shortwave Infrared(SWIR) photodetectors for this purpose is being actively conducted. Most SWIR photodetectors currently being developed are based on InGaAs, and have the disadvantages of complex processes, high prices, and limitations in research due to monopoly. In addition, current SWIR photodetectors use lasers in the 905 nm wavelength band, which can pass through the pupil and cause damage to the retina. Therefore, it is required to develop a SWIR photodetector using a wavelength band of 1400 nm or more to be safe for human eyes, and to develop a material that can replace the proprietary InGaAs. PbS QDs are group 4-6 compound semiconductors whose absorption wavelength band can be adjusted from 1000 to 2700 nm, and have the advantage of being simple to process. Therefore, in this study, PbS QDs having an absorption wavelength peak of 1415 nm were synthesized, and a SWIR photodetector was fabricated using this. In addition, the photodetector's responsivity was improved by applying P3HT and ZnO NPs to improve electron hole mobility. As a result of the experiment, it was confirmed that the synthesized PbS QDs had excellent FWHM characteristics compared to commercial PbS QDs, and it was confirmed that the photodetector had a maximum current change of about 1.6 times.

착지 높이와 무릎관절 근육 피로가 착지 후 방향 전환 동작 시 하지관절의 움직임에 미치는 영향 (Effects of Landing Height and Knee Joint Muscle Fatigue on Movement of the Lower Extremity during Cutting After Landing)

  • 김유경;염창홍
    • 한국운동역학회지
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    • 제25권3호
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    • pp.311-322
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    • 2015
  • Objective : The purpose of this study was to investigate the effects of landing height and knee joint muscle fatigue on the movement of the lower extremity during cutting after landing. Method : Subjects included 29 adults (age: $20.83{\pm}1.56years$, height: $172.42{\pm}9.51cm$, weight: $65.07{\pm}10.18kg$). The subjects were asked to stand on their dominant lower limb on jump stands that were 30 and 40 cm in height and jump from each stand to land with the dominant lower limb on a force plate making a side step cutting move at a $45^{\circ}$ angle with the non-dominant lower limb. The fatigue level at 30% of the knee extension peak torque using an isokinetic dynamometer. Results : The results showed that the difference of landing height increased maximum range of motion and angular velocity of hip, knee, and ankle joints in the sagittal plane, and in the angular velocity of motion of the hip joint in the sagittal plane. The maximum range of motion of the knee joint in the sagittal plane and the frontal plane decreased on landing from both heights after the fatigue exercise. The angular velocity of the hip joint in the sagittal plane, and the maximum range of motion of the hip joint in the transverse plane decreased for both landing heights after the fatigue exercise. The angular velocity of the hip joint in the frontal plane decreased for the 30 cm landing height after the fatigue exercise. On the other hand, the angular velocity and maximum range of motion of the ankle joint in the sagittal plane for both landing heights, and the angular velocity and maximum range of motion of the ankle joint in the frontal plane increased on landing from the 40 cm height after the fatigue exercise. Conclusion : Different landing heights of 30 and 40 cm and 30% fatigue of peak torque of knee extensor found a forefoot and stiff landing strategy, when cutting after landing. These results might be due to decline in the shock absorption capability of the knee joint and the movement capability related to cutting while increasing the contribution of the ankle joint, which may cause increased ankle joint injuries.

원자로에 있어서 Xenon 독소의 최적제어 (Optimal Control of Xenon Poison In Nuclear Reactor)

  • 곽은호;고병준
    • 대한전자공학회논문지
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    • 제13권5호
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    • pp.17-23
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    • 1976
  • 고속열중성자로에서 정상 운전중인 원자로를 운전정지하였다가 재가동할 때 가장 문제가 되는 것은 핵분열 생성물인 Xe135의 독소작용이다. 이것은 Xe135가 원자로 출력에 영향을 주는 열중성자에 대한 흡수단면적이 크고 그의 반감기가 길기 때문이다. 그러므로 원자로의 일시적 운전정지가 요구될 때 이의 재가시에는 반듯이 이 독소를 능과할 수 있는 충분한 초과반응도를 가해 주던지, Xe135가 붕괴되어 그의 농도가 줄어든 이후에야 원자로의 재가동이 가능하게 된다. 위와 같은 문제는 사실상 원자로 운전시 안전성 뿐만 아니라 경제성에도 큰 영향을 주고 있다. 본 논문에서는 이 점을 고려하여 Pontoyagin의 최대원리를 이용하여 운전정지를 최적화시키므로서 언제든지 원자로를 전출력으로 재가동할 수 있도록 운전정지 방법을 개선하였다. 그러나 제어과정에서나 그 이후에도 X, 농도는 제어된 허용치를 넘지 않고 최소시간 이내에 모든 제어를 끝내도록 하였다. The buildup of fission product, i.e. Xe-135 poisoning, is a prime factor in restarting a nuclear reactor from the shutdown, which was under normal operation in the high flux thermal reactor, It is caused by the high absorption crosssection of Xe-135 to thermal neutrons and its long half life, from which the thermal power is affected. It is then possible to restart a nuclear reactor after the sufficient excess reactivity to override this poisoning must be inserted, or its concentration is decreased sufficiently when its temporary shutdown is required. As ratter of fact, these have an important influence not only on reactor safety but also on economic aspect in operation. Considering these points in this study, the shutdown process was cptimized using the Pontryagin's maximum principle so that the shutdown mirth[d was improved as to restart the reactor to its fulpower at any time, but the xenon concentration did not excess the constrained allowable value during and after shutdown, at the same time all the control actions were completed within minimum time from beginning of the shutdown.

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천연염료자원 탐색 및 염색특성(II) - 염색조건에 따른 거북꼬리(Boehmeria tricuspis Makino)추출물의 염색특성 - (The Search and Dyeing Properties of Natural Dyes Resources(II) - The Dyeing Properties of Boehmeria tricuspis Makino Extracts by Dyeing Condition -)

  • 조현진;이상극;강하영;최돈하;최인규
    • 임산에너지
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    • 제25권2호
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    • pp.22-27
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    • 2006
  • 거북꼬리의 적정염색 조건을 구명하기 위하여 열수 및 알칼리추출물을 사용하여 염색조건에 따른 염착량(K/S) 및 Munsell의 색상(Hue), 명도(Value), 채도(Chroma)의 변화에 대하여 조사하였다. 면, 한지, 실크에 대한 열수 및 알칼리추출물 처리 염색물의 최대흡수파장(${\lambda}max$)은 400 mm였다. 염색조건에 따른 염착량은 온도와 시간 조건에서 실크 염색물이 높은 수치를 나타내었고, $80\;^{\circ}C$와 40분을 전후로 큰 변화를 보이지 않았다. 농도조건에서는 농도가 높을수록 급격히 증가하는 경향을 나타내었다. Munsell의 색상은 온도와 시간조건에서 알칼리추출물 처리 염색물은 YR (Yellow Red) 계열의 색상을, 열수추출물 처리 염색물은 R (Red) 계열의 색상을 나타내었으며 온도는 $80\;^{\circ}C$, 시간은 40분을 전후로 큰 변화가 없었다. 명도 및 채도는 뚜렷한 변화를 보이지 않았고 염색조건에는 큰 영향을 미치지 않는 것으로 사료된다. 따라서 거북꼬리추출물로 염색할 경우 최적 염색조건은 온도 $80\;^{\circ}C$, 시간 40분, 농도 100% (추출원액)로 조절하는 것이 바람직할 것으로 생각된다.

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${\beta}$-Glucan 첨가가 식빵의 물리적 및 품질 특성에 미치는 영향 (Effect of ${\beta}$-Glucan on Rheological Properties and Quality Characteristics of White Pan Bread)

  • 이정훈
    • 한국조리학회지
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    • 제18권3호
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    • pp.227-238
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    • 2012
  • 미생물 발효로 제조한 ${\beta}$-glucan을 밀가루의 3, 6, 9%를 대체 첨가하여 반죽의 물리적 특성으로 farinograph, amylograph를 분석하였고, 제빵에 미치는 영향으로 식빵의 부피 및 비용적, 수분함량, 조직감, 관능검사 등을 분석하였다. Farinograph에서 ${\beta}$-glucan 첨가량이 많을수록 흡수율이 높았고 특히 9% 첨가구는 대조구에 비하여 13% 정도 높았다. 첨가량이 많아짐에 따라 반죽형성시간도 증가하였으나 안정도는 감소하였다. Amylograph 분석에서 첨가량에 관계없이 호화온도와 최고점도온도에는 영향이 없었으나 최고점도는 첨가량이 증가할수록 감소하였다. 식빵의 부피와 비용적은 첨가량이 증가함에 따라 다소 감소하는 경향을 보였다. 수분함량은 시험구들이 대조구보다 높았고 6% 첨가구에서 가장 높았다. 식빵의 조직감도 6% 첨가구가 가장 부드러운 것으로 나타났고, 관능검사의 전체적 품질에서 3%와 6% 첨가구는 대조구와 유의적 차이가 없었으나 9% 첨가구는 대조구보다 낮은 점수를 얻었다. 따라서 건강 기능성 식빵을 제조하는데 미생물 발효로 얻은 ${\beta}$-glucan을 6%까지는 첨가가 가능한 것으로 나타났고 향 후 케이크나 쿠키 등에도 응용이 가능하리라 생각된다.

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Benzo[1,2,5]thiadiazole을 기본 골격으로 한 공액고분자의 합성 및 광전변환특성 연구 (Synthesis and Photovoltaic Properties of New π-conjugated Polymers Based on Benzo[1,2,5]thiadiazole)

  • 배준휘;임경은;김주현
    • 공업화학
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    • 제24권4호
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    • pp.396-401
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    • 2013
  • Benzo[1,2,5]thiadiazole, carbazole 및 phenanthrene을 기본 골격으로 한 교대공중합체인 poly[9-(2-octyl-dodecyl)-9H-carbazole-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PCD20TBT)와 poly[9,10-bis-(2-octyl-dodecyloxy)-phenanthrene-alt-4,7-di-thiophen-2-yl-benzo[1,2,5]thiadiazole] (PN40TBT)을 Suzuki coupling reaction을 이용하여 중합하였다. 합성한 고분자들은 chloroform, chlorobenzene, 1,2-dichlorobenzene, tetrahydrofuran, toluene과 같은 유기용매에 대한 용해도가 우수하였다. PCD20TBT의 최대흡수 파장과 밴드갭은 각각 535 nm와 1.75 eV이고, PN40TBT의 최대흡수 파장과 밴드갭은 각각 560 nm과 1.97 eV이었다. PCD20TBT의 HOMO 및 LUMO 에너지준위는 각각 - 5.11 eV와 - 3.36 eV이고, PN40TBT의 HOMO 및 LUMO 에너지준위는 각각 -5.31 eV와 -3.34 eV이었다. 합성한 고분자와 (6)-1-(3-(methoxycarbonyl)-{5}-1-phenyl[5,6]-fullerene(PCBM)을 1:2의 중량비로 블랜딩하여 제작한 이종접합형태(bulk heterojunction) 태양전지를 제작하였다. PCD20TBT의 광전변환효율은 0.52%, PN40TBT의 광전변환효율은 0.60%이었다. 그리고 소자의 단락 전류밀도, 충진 인자와 개방전압은 PCD20TBT가 각각 $-1.97mA/cm^2$, 38.2%, 0.69 V이며, PN40TBT의 경우 각각 $-1.77mA/cm^2$, 42.9%, 0.79 V이었다.

기계적 합금화법으로 제조한 Mg2NiHx-Graphene 복합재료의 수소화 특성 평가 (Evaluation of Hydrogen Properties on Mg2NiHx-Graphene Composites by Mechanical Alloying)

  • 이영상;이수선;이병하;정석;홍태환
    • 한국수소및신에너지학회논문집
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    • 제25권1호
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    • pp.19-27
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    • 2014
  • Mg hydride has a high hydrogen capacity (7.6%), at high temperature, and is a lightweight and low cost material, thus it a promising hydrogen storage material. However, its high operation temperature and very slow reaction kinetics are obstacles to practical application. In order to overcome these disadvantages of Mg hydride, graphene powder was added to it. The addition of graphene has been shown to reduce the operating temperature of dehydrogenation. Moreover, in this report the environmental aspects of $MgH_x$-Graphene composites are investigated by means of the environmental life cycle assessment (LCA) method. $MgH_x$-Graphene mixture was prepared by hydrogen induced mechanical alloy (HIMA). The synthesized powder was characterized by XRD(X-ray Diffraction). The hydrogenation behaviors were evaluated by using a Sievert's type automatic PCT apparatus. Such evaluation of Materials also conducted in the LCA. From the result of P-C-T(Pressure-Composition-Temperature) curves, the $MgH_x$-3wt.% graphene composite was evaluated as having a 5.86wt.% maximum hydrogen storage capacity, at 523K. From absorption kinetic testing, the $MgH_x$-7wt.% graphene composite was evaluated as having a maximum 6.94wt.%/ms hydrogen absorption rate, at 573K. Environment evaluation results for the $MgH_x$-graphene composites and other materials indicated environmental impact from the electric power used and from the materials themselves.

오메프라졸 장용성제제에 대한 생물학적 동등성 평가 (Bioequivalence of Enteric-coated Omeprazole Products)

  • 김종국;정은주;이은진;신희종;이원근
    • Journal of Pharmaceutical Investigation
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    • 제23권1호
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    • pp.41-49
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    • 1993
  • The bioequivalence of two omeprazole enteric-coated products was evaluated in 16 normal male volunteers (age 26-32 yr, body weight 57-75 kg) following single oral administration. Test product was enteric-coated KD-182 tablet (Chong Kun Dang Corp., Korea) and reference product was $Rosec^{\circledR}$ capsule containing enteric-coated pellets of omeprazole (Yuhan Corp., Korea). Both products contain 20 mg of omeprazole. One tablet or capsule of the test or the reference product was administered to the volunteers, respectively, by randomized two period cross-over study ($2\;{\times}\;2$ Latin square method). Average drug concetrations at each sampling time and pharmacokinetic parameters calculated were not significantly different between two products(p>0.05); the area under the concentrationtime curve to last sampling time (8 hr) $(AUC_{0-8hr})$ $(1946.5{\pm}675.3\;vs\;2018.3{\pm}761.6\;ng{\cdot}hr/ml)$, AUC from time zero to infinite $(AUC_{o-\infty})$ $(2288.6{\pm}1212.8\;vs\;2264.9{\pm}1001.3\;ng{\cdot}hr/ml)$, maximum plasma concentration $(C_{max})$ $(772.5{\pm}283.3\;vs\;925.8{\pm}187.7\;ng/ml)$, time to maximum plasma concentration $(T_{max})$ $(2.38{\pm}1.06\;vs\;2.34{\pm}1.09\;hr)$, apparent elimination rate constant $(k_{\ell})$ $(0.5339{\pm}0.2687\;vs\;0.5769 {\pm}0.2184\;hr^{-I})$, apparent absorption rate constant $(k_a)$ $(1.1536{\pm}0.5278\;vs\;0.9739{\pm}0.9507 hr^{-1})$ and mean residence time (MRT) $(3.13{\pm}0.73\;vs \;3.41{\pm}1.04\;hr)$. The differences of mean $(AUC_{0-8hr})$, $C_{max}$, $T_{max}$ and MRT between the two products (3.69, 19.83, 1.32 and 8.99%, respectively) were less than 20%. The power $(1-{\beta})$ and treatment difference $(\triangle)$ for $AUC_{o-8hr}$ $C_{max}$ and MRT were more than 0.8 and less than 0.2, respectively. Although the power for $T_{max}$ was under 0.8, $T_{max}$ of the two products was not significantly different each other(p>0.05). These results suggest that the bioavailability of KD-182 tablet is not significantly different from that of $Rosec^{\circledR}$ capsule. Therefore, two products are bioequivalent based on the current results.

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PM10 연속자동측정기(β-ray) 등가성평가 및 비교관측 연구 (PM10 β-ray attenuation samplers (β-ray absorption method) equivalence evaluation and comparatively observed study)

  • 정원석;고희정;서원익;정지영;오상민;부경온
    • 한국입자에어로졸학회지
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    • 제19권1호
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    • pp.13-20
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    • 2023
  • The Asian dust observation network operates β-ray attenuation samplers to measure PM10 concentrations. In addition, equivalence evaluation and accuracy inspection(Precision Tests) are conducted every year for the reliability of data. β-ray attenuation samplers(16 units) were comparatively observed from May to June 2020 and from July to December 2021. During the observation period, the average daily temperature was the lowest at 6.4℃ in December and the highest at 27.3℃ in August. The average daily humidity ranged from 60% to 100%, but the average daily humidity was over 75% from July to September. The minimum value of the PM10 Gravimetric method was 5.0 ㎍/m3, the maximum value was 53.4 ㎍/m3, and the average value was 17.8 ㎍/m3. The equivalence evaluation results of the PM10 Gravimetric method and β-ray attenuation samplers satisfied the criteria (slope: 1±0.1, intercept: 0±0.5). A relative error analysis between the PM10 Gravimetric method and β-ray attenuation samplers equipment showed that the relative error increased when the concentration was low and the temperature and humidity were high. In addition, in the β-ray attenuation samplers 5-minute interval observation data in May 2020, a relatively large Standard devication was shown as an average maximum ±23.4 ㎍/m3 and a minimum ±15.2 ㎍/m3. At standard deviations of 10% and 90%, equipment with high variability (deviation) was measured at 6 ㎍/m3and 61 ㎍/m3, and equipment with low variability was measured at 12 ㎍/m3 and 47 ㎍/m3. It was confirmed that concentration differences occurred due to differences in variability for each equipment.

GaAs(100)기판 위에 성장된 $Zn_{0.86}Mn_{0.14}Te$에피막의 띠 간격 에너지 (Energy band gap of $Zn_{0.86}Mn_{0.14}Te$ epilayer grown on GaAs(100) substrates)

  • 최용대;안갑수;이광재;김성구;심석주;윤희중;유영문;김대중;정양준
    • 한국결정성장학회지
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    • 제13권3호
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    • pp.122-126
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    • 2003
  • 본 연구에서는 두께가 0.7 $\mu \textrm{m}$$Zn_{0.86}Mn_{0.14}$Te 에피막을 GaAs(100) 기판 위에 열벽 적층 성장하였다. 선택에칭용액에 의하여 GaAs 기판이 제거된 X-선 회절 패턴으로부터 $Zn_{0.86}Mn_{0.14}$Te에피막의 결정구조는 zincblende 이었으며 격자상수는 6.140 $\AA$으로 계산되었다. 이러한 격자상수 값과 Vegard 법칙으로부터 Mn의 조성비 x=0.14임을 알았다. 성장된 에피막의 결정성은 이중결정요동 곡선의 반폭치 값이 256 arcsec인 것으로부터 양호하다는 것이 확인되었다 상온에서 10K 까지 $Zn_{0.86}Mn_{0.14}$Te에피막의 온도에 따른 띠 간격 에너지를 측정하기 위하여 투과 스펙트럼으로부터 흡수 스펙트럼이 얻어졌다 온도가 감소할수록 흡수 스펙트럼에서 강하게 흡수가 일어나는 영역은 에너지가 큰 쪽을 향하여 이동하였고 흡쑤단 근처에서 자유 엑시톤 형성을 의미하는 흡수 피크가 생겨났다. $Zn_{0.86}Mn_{0.14}$Te에피막의 온도에 따른 자유 엑시톤 피크 에너지로부터 OK와 300 K일 때 띠 간격 에너지는 각각 2.4947 eV와 2.330 eV로 구하여졌다. 10 K에서 기판이 제거된 $Zn_{0.86}Mn_{0.14}$Te 에피막의 흡수 스펙트럼의 자유 엑시톤 피크 에너지는 광발광 피크 에너지보다 15.4 meV 정도 크다. 이 에너지 차이는 흡수 스펙트럼과 발광 피크 사이의 에너지 차이를 의미하는 Stokes shift를 나타낸다.