• Title/Summary/Keyword: maximum absorption

Search Result 1,131, Processing Time 0.031 seconds

Distributions of Formaldehyde in Seoul in June, 2005 (2005년 6월의 서울시 대기의 포름알데히드 농도분포 특징)

  • Hwang Jung hoon;Lee Mee hye;Lee Gang woong;Han Jin seock
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.22 no.1
    • /
    • pp.63-71
    • /
    • 2006
  • An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

Synthesis and Characterization of Organic Light-Emitting Copolymers Containing Naphthalene

  • Kim, Jung-Sik;Heo, Jun;Kang, Peng-Tao;Kim, Jin-Hak;Jung, Sung-Ouk;Kwon, Soon-Ki;Kim, Un-Kyung;Kim, Yun-Hi
    • Macromolecular Research
    • /
    • v.17 no.2
    • /
    • pp.91-98
    • /
    • 2009
  • Conjugated PPV-derived block copolymers containing 2-ethylhexyloxynaphthalene unit were synthesized and characterized in this study. The resulting polymers were soluble in common organic solvents and showed good thermal stabilities, The weight-average molecular weights ($M_w$) of the copolymers ranged from 246,000 to 475,000 with PDIs of $1.3{\sim}2.1$. The optical properties of these polymers, measured both in a chloroform solution and on a film, showed a maximum absorption at $405{\sim}476\;nm$ for Copolymers $I{\sim}VIII$. In the PL spectra, Copolymers $I{\sim}VIII$ showed maximum peaks at $510{\sim}566\;nm$. The HOMOs, LUMOs and band gaps of the PPV derivatives of Copolymers $I{\sim}VIII$ were $5.30{\sim}5.77$, $3.04{\sim}3.24$, and $2.5{\sim}2.2\;eV$, respectively, The multi-layered, light-emitting diodes of ITO/PEDOT/copolymers/LiF/Al exhibited turn-on voltages of $6{\sim}2.5\;V$ Copolymer VIII exhibited the maximum brightness of $3.657\;cd/m^2$. Particularly, Copolymer VII, with an identical composition of MEH-PPV and naphthalene-PPV, showed a maximum luminance efficiency and power efficiency of 2,63 cd/A and 1.06 lm/W, respectively.

Langmuir phosphorus adsorption maximum as a criterion for determination of rate of phosphorus application (인산시용량(燐酸施用量) 결정기준(決定基準)으로서의 최대인산흡착량(最大燐酸吸着量))

  • Ryu, In-Soo;Jo, In-Sang
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.10 no.2
    • /
    • pp.93-97
    • /
    • 1977
  • A pot experiment was conducted to find out suitable method in determining the rate of phosphorus application. Soybean was planted under optimum moisture condition. The soils used in this experiment were cultivated and non-cultivated mineral soils, and volcanic ash soils. The results were summarized as follows: 1. Phosphorus adsorption maximum(PAM) was the good parameters to determine phosphorus adsorption capacity of all tested soils. 2. Phosporus adsorption maximum was increased with the content of ammonium acetate extractable aluminum, and the organic matter effects on PAM was considerably high in volcanic ash soils. 3. Requirement of phosphorus for maximum yields were in the range of 30~35% of PAM for tested soils. 4. PAM was considered as a suitable criteria to determine the rate of the phosphorus application and it was also considered to be more attractive than phosphorus absorption coefficient.

  • PDF

Output power characteristics of a CW Nd:YVO4/KTP laser pumped by a tunable Ti:Sapphire laser (파장가변 티타늄 사파이어 레이저로 펌핑하는 연속발진 Nd:YVO4/KTP 레이저의 출력 특성)

  • 추한태;안범수;김규욱;이치원
    • Korean Journal of Optics and Photonics
    • /
    • v.13 no.2
    • /
    • pp.140-145
    • /
    • 2002
  • We measured the absorption rate of a Nd:YVO$_4$crystal with a thickness of 1 mm and the output power characteristics of a cw Nd:YVO$_4$/KTP laser with respect to the change of wavelength and the polarizations of a tunable Ti:sapphire pump laser with a linewidth of 0.2 nm. In the case of S-polarization (E┴$\pi$) and P-polarization (E∥$\pi$) of a pump laser, the maximum absorption rate of the crystal was 82% at 809.4 nm and 98% at 808.8 nm, and slope efficiencies for the output power of the Nd:YVO$_4$laser (1064 nm) were 43% and 52%, respectively. The maximum Nd:YYO$_4$laser output power of 516 mW was obtained from the P-polarization pump laser of 1000 mW. As a result of an intracavity frequency-doubling, slope efficiency for the output power of the Nd:YVO$_4$/KTP green laker (532nm) was 23% and the maximum output power of 205 mW with the beam quality (M$^2$) of 1.42 was obtained from the P-polarization pump laser of 1000 mW.

SOLUBILIZATION OF 4-HYDROXY-$4^1$-NITROSTILBENE IN MICELLAR SOLUTIONS

  • Shin, Dong-Myung;Kim, Yong-In;Kwon, Ohoak;Oh, Yung-Hee
    • Journal of Photoscience
    • /
    • v.2 no.2
    • /
    • pp.89-93
    • /
    • 1995
  • Solvatochromic effects and hydrogen bonding interactions of 4-hydroxy-4'-nitrostilbene(NSOH) were investigated. Electronic transition energies of NSOH have good correlation with Taft's $\pi$$^*$. The hydrogen bonding interactions can be accounted by analysis with equation of $\Delta$E= $\Delta$E$_0$ + s($\pi$$^*$ + d$\delta$) + a$\alpha$ + b$\beta$. From UV-visible absorption maximum energies, $\Delta$E = 81.2 kcal/mole - 6.66($\pi$$^*$ - 0.20$\delta$) - 0.66$\alpha$ - 1.93$\beta$ (corr.=0.970) was obtained, and from fluorescence intensity maximum energies, $\Delta$E= 70.07 kcal/mole - 21.6($\pi$$^*$ - 0.11d) - 1.74$\alpha$ - 2.73$\beta$ (corr.=0.947) was obtained. The micropolarity estimated at the solubilization sites is close to the polarity of water. The apparent Taft's $\pi$$^*$ values of solubilization sites are close to 1. Howcver, the solubilization sites for the fluorescent NSOH is rather nonpolar. Both NSOH and NSO$^-$ can be solubilized in CTAB and CTAC micelles and NSOH is the only species that can be solubilized in SDS and Brij-35 micelles.

  • PDF

Studies on Antibacterial Activity of Lactics (유산균(乳酸菌)의 항생작용(抗生作用)에 관(關)한 연구(硏究))

  • Kim, Dong Shin
    • Current Research on Agriculture and Life Sciences
    • /
    • v.1
    • /
    • pp.169-177
    • /
    • 1983
  • 1. At selected time intervals, viable cell plate counts were run. After the 12 hours incubution the number of viable cells was maximum. 2. The morphology of L. acidophilus in tomato juice was thicker rods than those of in milk media. 3. In the assay of antimicrobial activity; (1) The antimicrobial activity of acidophilus tomato juice showed bigger inhibitory zone than acidophilus milk in the well-cup assay technique. (2) The inhibitory zone against Shigella dysenteriae was the biggest among the other pathogenic organisms in the disc assay. 4. The antimicrobial activity of sephadex G-50 gel filtration chomatography showed in the 5th fraction. 5. The spectra of ultraviolet absorption exhibited around maximum peak at 270nm.

  • PDF

Design and analysis of low velocity impact on thermoplastic hat section with curvilinear profile

  • Gaur, Kumresh K;Dwivedi, Mayank;Bhatnagar, Naresh
    • Advances in materials Research
    • /
    • v.6 no.1
    • /
    • pp.65-78
    • /
    • 2017
  • A hat section was designed and developed for maximum impact energy absorption and/or transmission under low velocity impact. Towards this, different hat sections, having material properties of thermoplastic, were modeled and investigated numerically using finite element analysis (FEA) in the range of 20-50 J impact energy. In the study it was experienced that the design configuration of hat section with curvilinear profile (HSCP) was excellent in energy attenuation capacity and for even distribution of maximum impact force around and along the hat section under low velocity impact loading. To validate the numerical findings, polypropylene copolymer (Co-PP) HSCP and low density polyethylene (LDPE) HSCP were developed and evaluated experimentally in the said impact energy range. A correlation was established between FEA and experimental test results, thereby, validating a numerical model to predict results for other thermoplastic materials under given range of impact energy. The LDPE HSCP exhibited better performance as compared to Co-PP HSCP in the said range of impact energy. The findings of this study will enable the engineers and technologists to design and develop low velocity impact resistance devices for various applications including devices to protect bone joints.

Natural Indigo Dyeing of Wool by the One Step Reduction/Dyeing Method (일단계 환원/염색에 의한 모직물의 천연인디고 염색)

  • Son, Kyung-Hee;Shin, Youn-Sook;Yoo, Dong-Il
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.34 no.3
    • /
    • pp.508-517
    • /
    • 2010
  • One-step reduction/dyeing method was optimized for wool dyeing with natural indigo dye in this study. The effects of reduction/dyeing conditions including dye temperature and time, the pH of bath, concentration of dye, and reducing agent on dye uptake and color were investigated. The dye uptake was higher with no addition of alkali. Dyeing was carried out through the use of only sodium hydrosulfite in the bath. The maximum dye uptake was obtained at $60^{\circ}C$ for 30min and the dyed fabrics appeared in the PB Munsell color range. Dye uptake improved with the increase of a natural indigo dye concentration with the same sodium hydrosulfite concentration. At a higher dye uptake, the fabric color became more purplish and the maximum absorption shifted from 660nm to 620nm. Color reproducibility was reliable with a color difference in the range of 0.41~1.43. Regardless of color strength, washing and dry cleaning fastnesses were good with a 4/5 rating, and fastnesses to rubbing and light were acceptable with a 3/4~4 rating.

A Study on the Characteristics of Mandu-pi Differing in Roasted Soy Flour Content (볶은 콩가루 첨가를 달리한 만두피의 특성 연구)

  • 변진원;남혜원;우인애
    • The Korean Journal of Food And Nutrition
    • /
    • v.14 no.4
    • /
    • pp.287-292
    • /
    • 2001
  • The purpose of this study was to investigate the effect of roasted soy f1our on the characteristics of Mandu-pi. Various Mandu-pi samples were prepared with wheat flour along with the addition of different amount of roasted soy flour. and then instrumental characteristics and sensory evacuation were investigated. As a result of amylography study, there were no difference In the initial pasting and maximum viscosity temperatures between samples. And maximum viscosity decreased with the increase of flour addition. In farinography study, the addition of roasted sop f1our did not affect the gelatinization temperature, while stability and developing time of dough increased by addition of soy flour level. Besides cooked weight, cooked volume and water absorption of Mandu-pi were also higher significantly than control. The more soy flour was added, the less lightness and more redness and yellowness were obtained. The result of sensory evaluation revealer that there were no differences between samples in beano aroma, smoothness, and chewness. However Mandu-pi added roasted soy flour showed higher scores in surface appreance, nutty aroma, nutty taste. sweet taste, and overall preferance than control.

  • PDF

Effects of high temperatures and hygrothermals on the collapse characteristics of CFRP thin-walled laminates (고온 .senter dot. 고습환경이 CFRP 적층 원통부재의 압궤특성에 미치는 영향)

  • 곽훈이;김정호;양인영
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 1995.10a
    • /
    • pp.650-654
    • /
    • 1995
  • In this study, in order to measure energy-absorbing charactistics in collapse test of CFRP thin-walled laminates and interpretate the cause of decreasing age when collapse test is carried out under the environments of high temperatures and hygrothermals, the moisture absorbing behavior according to the variety of orientation angel is observed and collapse characteristics is compared with the influence of high temperatures and hygrothermals. Especially, we supposed to clearly understand reationship between collapse characteristics in proportion to the variety of orientation angel and moisture absorbing. The value of the maximum loading, mean loading,rate of energy absorption energy per unit volume and mass in CFRP thin-walled laminates on the high temperatures and hygrothermals is measured lower than under no moisture absorbing. The maximum collapse loading in dynamic impact test is taken measurement lower than in static collapse test regarding compared with collapse characteristics conformity with the variety of the CFRP circular laminates in high temperatures and hygrothermals. But the absorbed energy per unit mass and volume is almost same and the biggest amount of energy is shown in the CFRP circular laminates with orientation angel of 15 .deg.. Therefore, in the case of use to CFRP circular laminates with axisymmetric mode, CFRP thin-walled structal members with orientation angel of 10 .deg. , 15 . deg. are generally useful.

  • PDF