• Title/Summary/Keyword: material substitution

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Effect of n-type Dopants on CoSb3 Skutterudite Thermoelectrics Sintered by Spark Plasma Sintering (Spark Plasma Sintering 법으로 제조한 CoSb3 Skutterudite계 열전소재의 n형 첨가제 효과)

  • Lee, Jae-Ki;Choi, Soon-Mok;Lee, Hong-Lim;Seo, Won-Seon
    • Korean Journal of Materials Research
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    • v.20 no.6
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    • pp.326-330
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    • 2010
  • $CoSb_3$ Skutterudites materials have high potential for thermoelectric application at mid-temperature range because of their superior thermoelectric properties via control of charge carrier density and substitution of foreign atoms. Improvement of thermoelectric properties is expected for the ternary solid solution developed by substitution of foreign atoms having different valances into the $CoSb_3$ matrix. In this study, ternary solid solutions with a stoichiometry of $Co_{1-x}Ni_xSb_3$ x = 0.01, 0.05, 0.1, 0.2, $CoSb_{3-y}Te_y$, y = 0.1, 0.2, 0.3 were prepared by the Spark Plasma Sintering (SPS) system. Before the SPS synthesis, the ingots were synthesized by vacuum induction melting and followed by annealing. For phase analysis X-ray powder diffraction patterns were checked. All the samples were confirmed as single phase; however, with samples that were more doped than the solubility limit some secondary phases were detected. All the samples doped with Ni and Te atoms showed a negative Seebeck coefficient and their electrical conductivities increased with the doping amount up to the solubility limit. For the samples prepared by SPS the maximum value for dimensionless figure of merit reached 0.26, 0.42 for $Co_{0.9}Ni_{0.1}Sb_3$, $CoSb_{2.8}Te_{0.2}$ at 690 K, respectively. These results show that the SPS method is effective in this system and Ni/Te dopants are also effective for increasing thermoelectric properties of this system.

The relation of the crystal phase and the charge/discharge capacity of $Li[Li_yMn_{2-y}]O_4$ cathode materials substituted Li (Li 치환된 $Li[Li_yMn_{2-y}]O_4$ 정극 활물질의 결정 구조와 충방전 용량과의 관계)

  • Jeong, In-Seong;Gu, Hal-Bon;Park, Bok-Gi;Son, Myeng-Mo;Lee, Heon-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.117-120
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    • 2000
  • The relation of crystal phase and charge/discharge capacity of $Li[Li_yMn_{2-y}]O_4$ were studied for different degrees of Li substitution (y). All cathode material showed spinel phase based on cubic phase in X-ray diffraction. Other peaks didn't show in spite of the increase of y value in $Li[Li_yMn_{2-y}]O_4$. Ununiform of $Li[Li_yMn_{2-y}]O_4$ which calcinated by (111) face and (222) face was more stable than that of pure $LiMn_2O_4$. In addition, At TG analysis, calcined $Li[Li_{0.1}Mn_{1.9}]O_4$ exhibited much mass loss at $800{\mu}m$. The cycle performance of the $Li(Li_yMn_{2-y}]O_4$ was improved by the substitution of $Li^{1+}$ for $Mn^{3+}$ in the octahedral sites. Specially, $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It is excellent than that of pure $LiMn_2O_4$, which 125mAh/g at first cycle, 65mAh/g at 70th.

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Nutrient Utilisation and Growth Performance of Broiler Rabbits Fed Oat Plant Meal and Tall Fescue Hay

  • Bhatt, R.S.;Sharma, S.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.9
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    • pp.1228-1232
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    • 2001
  • Forty five Soviet Chinchilla rabbits weaned at 35 d of age were fed 5 experimental diets prepared by using oat plant meal ($T_2,\;T_4$) and tall fescue hay ($T_3,\;T_5$) at 25% and 50% level along with control ($T_1$). The gain in body weight at 84 d of age decreased with test material substitution, however, the differences were non significant when compared with oat plant meal and were significant (p<0.05) with tall fescue hay at both the levels. Feed conversion ratio also deteriorated with test material and its increasing proportion and the differences were significant (p<0.05). The performance-index calculated were 42.1, 36.7, 29.4, 33.3 and 18.8 in $T_1,\;T_2,\;T_3,\;T_4$ and $T_5$, respectively. Digestibility of all the organic nutrients decreased significantly (p<0.05) with test material incorporation, as a result nutritive value of the test diets decreased linearly. Nitrogen balance as per cent of intake was higher in oat plant meal substituted diet compared to tall fescue substituted diet. Cost per kg live weight gain was lowest with 50% oat plant meal followed by 25% oat plant meal incorporation. It was highest with tall fescue hay substitution. Nutritive value of oat plant meal as calculated was DCP 5.1%, TDN 35.8% and that of tall fescue hay was DCP 6.5%, TDN 30.8%. Thus, oat plant meal can be substituted safely up to 25% in the feeding regime of weaner rabbits whereas, for tall fescue hay the safe limit is below 25% level and needs to be ascertained.

Effect of ICT Capital on the Demands for Labor and Energy in Major Industries of Korea, US, and UK (ICT 자본 투입이 노동 및 에너지 수요에 미치는 영향: 한국, 미국, 영국의 제조업 및 전기·가스·수도사업의 생산구조 비교)

  • Kim, Jihyo;Heo, Eunnyeong
    • Environmental and Resource Economics Review
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    • v.23 no.1
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    • pp.91-132
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    • 2014
  • We investigate the effect of ICT capital on the demands for labor and energy in manufacturing and electricity gas water industries of Korea, US, and UK. Assuming ICT capital, non-ICT capital, labor, electricity, fuel, and material as input factors for manufacturing and ICT capital, non-ICT capital, labor and energy material as input factors for electricity gas water industry, we estimate the Morishima elasticities of substitution. Considering the relative price changes of input factors, ICT capital has substituted labor in manufacturing and electricity water gas industries of the three countries. ICT capital has substituted both electricity and fuel in US and UK manufacturing. Although ICT capital has substituted electricity and fuel each other in Korean manufacturing, ICT capital is unlikely to decrease the demands for electricity and fuel when considering their relative price changes. ICT capital has substituted energy material in electricity gas water industries of the three countries.

Evaluation of Tribological Properties on Piston Ring/Liner Using Accelerative Wear Test (가속마모시험에 의한 피스톤 링/라이너의 마찰마모특성 평가)

  • Song Keunchul;Kim Kyungwoon;Shim Dongseob
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.75-78
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    • 2004
  • Engine power cylinder parts are faced with more severe wear and friction environment. For instance, emission gas recirculation (EGR), one of the most valid technologies related to emission legislation, is known to accelerate wear of piston ring and cylinder liner. Therefore, advanced materials and surface treatments have been developed and adopted successively so that a need exists for an accurate and repeatable friction and wear bench test for various combination of piston ring and cylinder liner that more closely relates to engine test result. This paper introduces accelerative bench wear test method for piston ring and cylinder liner, presents the experimental result of friction and wear properties of piston ring surface treatments that noticed in substitution for hard chrome plating.

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Adsorption Characteristics of Al (III), Ni (II), Sm (III) Ions on Resin with Styrene Hazardous Material in Reinforcement Water Fire Extinguishing Agent

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.6 no.3
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    • pp.151-157
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    • 2013
  • The ion exchange resins were synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous material) divinylbenzene (DVB) copolymer with crosslinks of 1%, 6%, and 15% by substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, surface area, and IR-spectrum. The object of this study was to seperate the metal ion absorbed in reinforcement water fire extinguishing agent. As the results of the effects of pH, equilibrium arrival time, and crosslink of synthetic resin on metal ion adsorption for resin adsorbent, the metal ions were showed high adsorption at pH 3 or over and adsorption equilibrium of metal ions was about 2 hours. In addition, adsorption selectivity for the resin in water was the order of Al (III) > Ni (II) > Sm (III) ions, adsorbability of the metal ions was in the crosslinks order of 1%, 6%, and 15%.

A Study on the Structural Design of a Seat frame in Automotive Vehicles (승용차 시트프레임의 구조설계에 관한 연구)

  • 김홍건;조영태;최금호;이병휘
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.05a
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    • pp.159-163
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    • 1999
  • A seat frame structure in automotive vehicles made of polymer matrix composite to achieve weight reduction at low cost was developed. In order to design and manufacture the actual product, studies on material selection, and structural analyses were performed. Structural analyses were performed with a finite element analysis. Analyses were done for several cases suggested in various safety regulations of FMVSS(Federal Motor Vehicle Safety Standards). Each result was utilized to modify the actual shape to obtain a lighter, safer and more stable design. The final design was used to produce a sample bottom plate of the seat structure. Substitution of the material resulted in a weight reduction effect with equivalent strength, fatigue and impact characteristics. Furthermore, several effects from the replacement of the material besides weight reduction were also examined.

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The Characteristics of P.H.C Pile using Admixture by Waste TFT-LCD Glass Powder (폐 TFT-LCD 유리분말을 혼입한 고강도 콘크리트 파일의 특성)

  • Jeon, Seong-Hwan;Min, Kyung-San;Soh, Yang-Seob
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.419-425
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    • 2010
  • In order to examine the P.H.C pile raw material using glass forming ceramic. The used materials is ordinary portland cement, waste TFT-LCD glass powder and reactive agent(Ca$(OH)_2$). The first experiment is characteristics analysis of the waste TFT-LCD glass powder, For the second experiment is mortar and concrete compressive strength for using of the concrete file raw material for waste TFT-LCD glass powder. The results of experiment showed that the substitution ratio of 10% waste TFT-LCD glass powder and 1% reactive agent(Ca$(OH)_2$) was excellent at a point of view for the physical characteristic. The study's most important finding is that the recycling of waste TFT-LCD glass powder.

Comprehensive piezo-thermo-elastic analysis of a thick hollow spherical shell

  • Arefi, M.;Khoshgoftar, M.J.
    • Smart Structures and Systems
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    • v.14 no.2
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    • pp.225-246
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    • 2014
  • The present paper develops piezo-thermo-elastic analysis of a thick spherical shell for generalized functionally graded piezoelectric material. The assumed structure is loaded under thermal, electrical and mechanical loads. The mechanical, thermal and electrical properties are graded along the radial direction based on a power function with three different non homogenous indexes. Primarily, the non homogenous heat transfer equation is solved by applying the general boundary conditions, individually. Substitution of stress, strain, electrical displacement and material properties in equilibrium and Maxwell equations present two non homogenous differential equation of order two. The main objective of the present study is to improve the relations between mechanical and electrical loads in hollow spherical shells especially for functionally graded piezoelectric materials. The obtained results can evaluate the effect of every non homogenous parameter on the mechanical and electrical components.

A study on the Electrical Characteristics of piezoelectric Ceramics Used In Ultrasonic Trasmitting Sensor by Ba Substitution (Ba 치환에 의한 초음파 송신기용 압전 소자의 전기적 특성에 관한 연구)

  • 조봉희;최창규;박창규;박상만
    • Electrical & Electronic Materials
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    • v.3 no.1
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    • pp.20-28
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    • 1990
  • Pb(Zr, Ti)O$_{3}$-Pb(Ni, Nb)O$_{3}$계 세라믹스에 Ba를 치완시켜 Ba치환량의 증가에 따른 유전율, 전기기계결합계수 및 압전 d정수의 변화를 고찰하였다. 또한 Ba치환에 따른 세라믹스 소자의 송신감도 특성을 조사하고 큐리온도 이동에 따른 온도안정성을 고려하여 초음파 송신기용 압전소자에 응용가능함을 보였다.

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