• Title/Summary/Keyword: material matrix

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Stress relaxation of ABS polymer melts. 1. Effect of weight fraction of rubber particle

  • Cho, Kwang-Soo;Park, Joong-Hwan;Kim, Sang-Yong;Youngdon Kwon
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.157-163
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    • 2000
  • We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

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A novel meso-mechanical model for concrete fracture

  • Ince, R.
    • Structural Engineering and Mechanics
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    • v.18 no.1
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    • pp.91-112
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    • 2004
  • Concrete is a composite material and at meso-level, may be assumed to be composed of three phases: aggregate, mortar-matrix and aggregate-matrix interface. It is postulated herein that although non-linear material parameters are generally used to model this composite structure by finite element method, linear elastic fracture mechanics principles can be used for modelling at the meso level, if the properties of all three phases are known. For this reason, a novel meso-mechanical approach for concrete fracture which uses the composite material model with distributed-phase for elastic properties of phases and considers the size effect according to linear elastic fracture mechanics for strength properties of phases is presented in this paper. Consequently, the developed model needs two parameters such as compressive strength and maximum grain size of concrete. The model is applied to three most popular fracture mechanics approaches for concrete namely the two-parameter model, the effective crack model and the size effect model. It is concluded that the developed model well agrees with considered approaches.

Preparation and Luminescence Properties of PDP Green Phosphors using Polymer Matrix Technique

  • Jun, Sang-Bae;Lee, Dong-Kyu;Kim, Soo-Jong;Masaki, Takaki;Han, Chung-Hwa
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.121-124
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    • 2007
  • The $Zn_2SiO_4:Mn$ phosphors were prepared using polymer matrix technique in order to improve the performance of green emitting phosphors for plasma display panel(PDP). $Zn_2SiO_4:Mn$ phosphor exhibits a strong green emission around 520-530 nm. The emission intensity and particle size of powders were controlled by sintering temperature and raw material composition. The zinc silicate $Zn_2SiO_4:Mn$ single phase were obtained at lower temperature than prepared by solid-state reaction method. PL luminance of $Zn_2SiO_4:Mn$ phosphor was similar to the commercial material.

Representative Volume Element Analysis of Fluid-Structure Interaction Effect on Graphite Powder Based Active Material for Lithium-Ion Batteries

  • Yun, Jin Chul;Park, Seong Jin
    • Journal of Powder Materials
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    • v.24 no.1
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    • pp.17-23
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    • 2017
  • In this study, a finite element analysis approach is proposed to predict the fluid-structure interaction behavior of active materials for lithium-ion batteries (LIBs), which are mainly composed of graphite powder. The porous matrix of graphite powder saturated with fluid electrolyte is considered a representative volume element (RVE) model. Three different RVE models are proposed to consider the uncertainty of the powder shape and the porosity. P-wave modulus from RVE solutions are analyzed based on the microstructure and the interaction between the fluid and the graphite powder matrix. From the results, it is found that the large surface area of the active material results in low mechanical properties of LIB, which leads to poor structural durability when subjected to dynamic loads. The results obtained in this study provide useful information for predicting the mechanical safety of a battery pack.

Fabrication of AC4A/SiCw composite by squeeze casting (III) - Mechanical characteristics - (용탕단조법에 의한 AC4A/SiCw 복합재료 제조에 관한 연구(III) - 기계적 특성 -)

  • Moon, Kyung-Cheol;Lee, Jun-Hee;Yoon, Eui-Pak
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.3
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    • pp.160-168
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    • 1994
  • This was studied about mechanical characteristic of AC4A/SiCw 10-30% reinforced composites. Tensile strength of pressed base metal(base metal) with SiCw preform was higher than without pressed base metal(AC4A). If SiCw whisker volume fraction was increased, tensile strength at room temperature was increased. And tensile strength of SiCw 30% was about $35kg/mm^2$. Tensile strength of SiCw 30 % $400^{\circ}C$ at same time aging was the most excellence, about $40kg/mm^2$. The fracture energy value of composite material at three point bending test was higher than AC4A. Dislocation at matrix of composite material was evenly distributed. But dislocation around whisker of composite material was more existed than matrix. The reasom was thought of pile-up around whisker.

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Manufacturing of Composite Solders by an In-situ Process (In-situ 공정에 의한 복합솔더 제조)

  • Hwang, Seong-Yong;Lee, Joo-Won;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.22 no.1
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    • pp.35-41
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    • 2002
  • To improve the reliability of solder joints, a composite solder which consists of solder matrix and intermetallic reinforcements was manufactured by a new method. The cast ingot of Sn-6.9Cu-2.9Ag alloy had primary Cu6Sn5 intermetallics in the form of dendrites. After rolling the ingot, the intermetallic dendrites were crushed into fine particles and distributed uniformly throughout the solder matrix. As the rolled strips became thinner, the average size of the crushed particles reached a critical size which did not decrease any more by further rolling. The critical size was nearly the same as the average width of intermetallic dendrite trunk. The crushed intermetallic particles did not melt and remained in solid state during reflow soldering due to their high meltingterm-perature. The coarsening and gravitational segregation of the particles were observed during reflow soldering.

Simulation of Material Properties of Amorphous Carbon Nitride with Non-uniform Nitrogen Distribution

  • Lu, Y.F.;He, Z.F.
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.3
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    • pp.1-6
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    • 2001
  • A simulation method is proposed to study the amorphous structure of carbon nitride. The material properties of a non-uniform nitrogen distribution in an amorphous CN matrix can be studied. The cohesive energy of a group of randomly generated atoms can be minimized to find the relative positions of atoms. From the calculated configuration of atoms, many properties of amorphous carbon nitride can be calculated such as bulk modulus, P-V curve, sp$^3$/sp$^2$ ratio of carbon, and vibrational spectra. The calculation shows that the cohesive energy of non-uniform nitrogen distribution is lower than that of a uniform distribution. This may suggest that the regular structure of carbon nitride can at most be metastable. It is not easy to incorporate nitrogen atoms into a carbon matrix.

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Numerical study on the influence of mesomechanical properties on macroscopic fracture of concrete

  • Zhu, W.C.;Tang, C.A.;Wang, S.Y.
    • Structural Engineering and Mechanics
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    • v.19 no.5
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    • pp.519-533
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    • 2005
  • The numerical simulations on the influence of mesoscopic structures on the macroscopic strength and fracture characteristics are carried out based on that the concrete is assumed to be a three-phase composite composed of matrix (mortar), aggregate and bond between them by using a numerical code named MFPA. The finite element program is employed as the basic stress analysis tool when the elastic damage mechanics is used to describe the constitutive law of meso-level element and the maximum tensile strain criterion and Mohr-Coulomb criterion are utilized as damage threshold. It can be found from the numerical results that the bond between matrix and aggregate has a significant effect on the macroscopic mechanical performance of concrete.

Effects of Alloying Elements and Heat-Treatment on the Tendency of Chill Formation of Ductile Cast Iron Produced by Metal Mold Cast (금형주조 구상흑연주철의 칠 형성 경향에 미치는 화학조성 및 열처리의 영향)

  • Kim, Sug-Won;Park, Jin-Sung;Kim, Ki-Kon
    • Journal of Korea Foundry Society
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    • v.27 no.1
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    • pp.24-30
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    • 2007
  • The effects of C, Si and RE additions on the tendency of chill formation of ductile cast iron obtained from metal mold casting were investigated. In case of metal mold cast, the ductile cast iron with 2.5%Si had pearlitic matrix, and specimens with 2.9%Si had bull's eye type regardless of C contents. As-cast specimen with a large amount of fine graphites could be obtained by adding 0.2% RE. Normalizing process was necessary to remove carbide and form a large amount of spheroidal graphites for the as-cast specimens. Good mechanical properties could be obtained by heat-treatment of as-cast specimens with pearlitic matrix. Normalizing the specimens with RE caused the reduction in mechanical properties.

Fine Dust Adsorption Properties of Cement Matrix Mixed with Expanded Graphite (팽창흑연을 혼입한 시멘트 경화체의 흡착 특성)

  • Lee, Jin-Won;Lee, Chang-Woo;Hwang, Woo-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.105-106
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    • 2022
  • Now, the world is increasingly anxious about fine dust due to abnormal temperatures caused by global warming and increased yellow dust caused by desertification, and the World Health Organization (WHO) pointed out that more than 99% of the world's population is exposed to fine dust. In this situation, the reduction rate of fine dust and carbon dioxide of the matrix was tested by using expanded graphite, an eco-friendly and porous material, to improve air quality. As a result of the test, since expanded graphite is a material that expands between layers compared to conventional graphite, the reduction rate of fine dust and carbon dioxide decreases as the replacement rate of expanded graphite increases.

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