• 제목/요약/키워드: material consequence

검색결과 177건 처리시간 0.027초

리튬이온전지용 스피넬계 LiMn2O4 양극에서 상이한 입자크기를 가진 전도성물질이 전기화학적 성능에 미치는 영향 (Effects on Electrochemical Performances of Conductive Agents with Different Particle Size in Spinel LiMn2O4 Cathode for Li-ion Batteries)

  • 이창우;이미숙;김현수;문성인
    • 한국전기전자재료학회논문지
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    • 제18권8호
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    • pp.702-707
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    • 2005
  • Spinel $LiMn_2O_4$ has become appealing because manganese is inexpensive and environmentally benign. In general, cathodes for lithium ion batteries include carbon as a conductive agent that provides electron transfer between the active material and the current collector. In this work, we selected Acetylene Black and Super P Black as conductive agents, and then carried out their comparative investigation for the performances of the $Li/LiMn_2O_4$ cells using different conductive agents with different particle size. In addition, their electrochemical impedance characteristic of $Li/Mn_2O_4$ cells using different conductive agents is effectively identified through a.c. impedance technique. As a consequence, $Li/LiMn_2O_4$ cells with Super P Black show better electrochemical performances ascribed to the significant contribution of feasible ionic conduction due to larger particle size than those with Acetylene Black.

On-Film Formation of Nanowires for High-efficiency Thermoelectric Devices

  • Ham, Jin-Hee;Shim, Woo-Young;Lee, Seung-Hyun;Voorhees, Peter W.;Lee, Woo-Young
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.17-17
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    • 2009
  • We report the invention of a direct growth method termed On-Film Formation of Nanowire (OFF-ON) for making high-quality single-crystal nanowires, i.e. Bi and $Bi_2Te_3$, without the use of conventional templates, catalysts, or starting materials. We have used the OFF-ON technique to grow single crystal semi-metallic Bi and compound semiconductor $Bi_2Te_3$ nanowires from sputtered Bi and BiTe films after thermal annealing, respectively. The mechanism for nanowire growth is stress-induced mass flow along grain boundaries in the polycrystalline films. OFF-ON is a simple but powerful method for growing perfect single-crystal semi-metallic and compound semiconductor nanowires of high aspect ratio with high crystallinity that distinguishes it from other competitive growth approaches that have been developed to date. Our results suggest that Bi and $Bi_2Te_3$ nanowires grown by OFF-ON can be an ideal material system for exploring their unique thermoelectric properties due to their high-quality single crystalline and high conductivity, which have consequence and relevance for high-efficiency thermoelectric devices.

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자기유변유체를 이용한 하드디스크 슬라이더의 표면연마를 위한 기초연구 (A preliminary study on the surface finishing of a hard disk slider using magnetorheological (MR) fluid)

  • 정봉수;장경인;민병권;이상조;석종원
    • 정보저장시스템학회논문집
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    • 제3권2호
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    • pp.66-72
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    • 2007
  • Surface finishing using magnetorheological (MR) fluid is useful to finish small but not too small workpieces such as those in a few millimeter scale. However, due to the high surface hardness, this finishing process does not seem to be suit for applying to a hard disk slider. In this work, a preliminary study is performed on the finishing of the hard disk slider surface with a mixture of an MR fluid and diamond powder. During a wheel type MR finishing process, centrifugal force is found to be a major factor to cause a reduction in material remove rate (MRR), which is supported by a theoretical model. To facilitate this founding, the rotational speed of tool is confined to 500rpm while a rectilinear alternating motion with the mean speed, which is equivalent to the rotational speed, is additionally applied to the workpieces. As a consequence, MRR of about 2 times of the sole rotational case is obtained. This paper shows that MR finishing process can be used to polish a hard material in millimeter scale efficiently by controlling the speeds of the tool and the workpiece.

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리튬이온전지용 Conducting Agents의 전기화학적 성능에 미치는 영향 (Effects on Electrochemical Performances of Conducting Agents for Lithium-ion Batteries)

  • 이창우;이미숙;문성인;김영규;김병화;김동훈
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.593-594
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    • 2005
  • Lithium-ion batteries have used the layered $LiCoO_2$ materials as cathodes, but Co is relatively toxic and expensive. In this regard, the spinel $LiMn_2O_4$ has become appealing because manganese is inexpensive and environmentally benign. In general, cathodes for lithium ion batteries include carbon as a conductive agent that provides electron transfer between the active material and the current collector. In this work, we selected Acetylene Black and Super P Black as conducting agents, and then carried out comparative investigation for the performances of the cells using different conducting agents with different particle size. As a consequence, Li/$LiMn_2O_4$ cells with Super P Black show better electrochemical performances than those with Acetylene Black.

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Improvement Plan for Prevention Regulations to Improve Hazardous Material Safety Management

  • Seongju Oh;Jaewook Lee;Hasung Kong
    • International Journal of Advanced Culture Technology
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    • 제11권3호
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    • pp.346-357
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    • 2023
  • The purpose of this study is to suggest improvement plans for prevention regulations by reflecting the toxicity, fire and explosion effects of hazardous materials factories and surrounding areas using an off-site consequence assessment program. Regarding the effects of the hydrogen cyanide leak accident, which is the 1st petroleum of the 4th class flammable liquid, Areal Locations of Hazardous Atmospheres (ALOHA) program was used to compare and analyze the extent of damage effects for toxicity, overpressure, and radiation. As a result, the toxicity was analyzed to exceed 5km in the area with Acute exposure guideline level (AEGL)-2 concentration or higher, the overpressure was 103m in the range of 1 psi or more, and the radiant heat was analyzed to be 724m in the range of 2kw/m2 or more. Toxicity and radiation affected the area outside the hazardous material storage area, but the overpressure was limited to the inside of the hazardous material storage area. Therefore, we propose to improve the safety management of hazardous materials by conducting a risk assessment for hazardous materials and reflecting the results in internal and external emergency response plans to prepare prevention regulations.

몬테카를로 해석 기반 확률적 위상최적화 (Topology Optimization based on Monte Carlo Analysis)

  • 김대영;노혁천
    • 한국전산구조공학회논문집
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    • 제30권2호
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    • pp.153-158
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    • 2017
  • 본 논문에서는 재료 탄성계수의 공간적 불확실성을 고려한 위상최적화 문제를 다루었다. 88줄로 작성된 MATLAB Code를 사용하여 MBB(messerschmidt-$b{\ddot{o}}lkow$-blohm) model에 대해 5,000개의 추계장 표본을 작성하여 해석에 사용하였다. 재료탄성계수의 추계장 표본은 스펙트럼 모사법을 적용하여 작성하였고, 구조계영역 내에서 정규분포하는 것으로 가정하였다. 해석결과에 대한 통계처리를 통하여 형상최적화의 결과를 나타내는 체적률의 변화도를 추계장의 상관거리에 대하여 나타내었다. 최적형상의 변화도는 상관거리가 작을 경우 크게 산정되었고, 상관거리가 큰 경우에는 적은 값을 나타내었다. 큰 상관거리에서 변화도가 적은 것은 위상최적화가 선형해석에 따르기 때문이다. 따라서 위상최적화 시 구조재료 불확실성의 특성에 따른 고려가 필요한 것으로 사료된다.

Torsional effects due to concrete strength variability in existing buildings

  • De Stefano, M.;Tanganelli, M.;Viti, S.
    • Earthquakes and Structures
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    • 제8권2호
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    • pp.379-399
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    • 2015
  • Existing building structures can easily present material mechanical properties which can largely vary even within a single structure. The current European Technical Code, Eurocode 8, does not provide specific instructions to account for high variability in mechanical properties. As a consequence of the high strength variability, at the occurrence of seismic events, the structure may evidence unexpected phenomena, like torsional effects, with larger experienced deformations and, in turn, with reduced seismic performance. This work is focused on the torsional effects related to the irregular stiffness and strength distribution due to the concrete strength variability. The analysis has been performed on a case-study, i.e., a 3D RC framed 4 storey building. A Normal distribution, compatible to a large available database, has been taken to represent the concrete strength domain. Different plan layouts, representative of realistic stiffness distributions, have been considered, and a statistical analysis has been performed on the induced torsional effects. The obtained results have been compared to the standard analysis as provided by Eurocode 8 for existing buildings, showing that the Eurocode 8 provisions, despite not allowing explicitly for material strength variability, are conservative as regards the estimation of structural demand.

파괴 시 발생하는 측면함몰과 소성영역크기와의 관계 (Relationship between Side-Necking and Plastic Zone Size at Fracture)

  • 김도형;김동학;강기주
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.365-371
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    • 2004
  • Generally, fracture of a material is influenced by plastic zone size developed near the crack tip. Hence, according to the relative size of plastic zone in the material, the mechanics as a tool for analyzing the fracture process are classified into three kinds, that is, Linear Elastic Fracture Mechanics, Elastic Plastic Fracture Mechanics, Large Deformation Fracture Mechanics. Even though the plastic zone size is such an important parameter, the practical measurement techniques are very limited and the one for in-situ measurement is not virtually available. Therefore, elastic-plastic FEA has been performed to estimate the plastic zone size. In this study, it is noticed that side necking at the surface is a consequence of plastic deformation and lateral contraction and the relation between the plastic zone and side necking is investigated. FEA for modified boundary layer models with finite thickness, various mode mixities $0^{\circ}$, $30^{\circ}$, $60^{\circ}$, $90^{\circ}$ and strain hardening exponent n=3, 10 are performed. The results are presented and the implication regarding to application to experiment is discussed.

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PVK/P3DoDT 블랜드를 발광층으로 사용한 EL 소자의 발광효율 향상에 관한 연구 (Improvement of external quantum efficiency of EL devices with PVK/P3DoDT blends using as a emitting layer)

  • 김주승;서부완;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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    • pp.96-99
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    • 2000
  • We fabricated electroluminescent(EL) devices which have a blended single emitting layer containing poly(N-vinylcarbazole)[PVK] and poly(3-dodecylthiophene)[P3DoDT]. The molar ratio between P3DoDT and PVK changed with 1:0, 2:1 and 1:1. To improve the external quantum efficiency of EL devices, we applied insulating layer, LiF layer, between polymer emitting layer and Al electrode. All of the devices emit orange-red light and its can be explained that the energy transfer occurs from PVK to P3DoDT. In the voltage-current and voltage-light power characteristics of devices applied LiF layer, current and light power drastically increased with increasing applied voltage. In the consequence of the result, the external quantum efficiency of the devices that have a molar ratio 1:1 with LiF layer was 35 times larger than that of the device without LiF layer at 6V.

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Scaled SONOSFET를 이용한 NAND형 Flash EEPROM (The NAND Type Flash EEPROM Using the Scaled SONOSFET)

  • 김주연;권준오;김병철;서광열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.145-150
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    • 1998
  • 8$\times$8 bit scaled SONOSFET NAND type flash EEPROM that shows better characteristics on cell density and endurance than NOR type have been designed and its electrical characteristics are verified with computer aided simulation. For the simulation, the spice model parameter was extracted from the sealed down SONOSFET that was fabricated by $1.5mutextrm{m}$ topological design rule. To improve the endurance of the device, the EEPROM design to have modified Fowler-Nordheim tunneling through the whole channel area in Write/Erase operation. As a result, it operates Write/Erase operation at low current, and has been proven Its good endurance. The NAND type flash EEPROM, which has upper limit of V$_{th}$, has the upper limit of V$_{th}$ as 4.5V. It is better than that of floating gate as 4V. And a EEPROM using the SONOSFET without scaling (65$\AA$-l65$\AA$-35$\AA$), was also designed and its characteristics have been compared. It has more possibliity of error from the V$_{th}$ upper limit as 4V, and takes more time for Read operation due to low current. As a consequence, it is proven that scaled down SONOSFET is more pertinent than existing floating gate or SONOSFET without scaling for the NAND type flash EEPROM.EPROM.

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