• Title/Summary/Keyword: material balance

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A Review on Electrochemical Model for Predicting the Performance of Lithium Secondary Battery (리튬이차전지 성능 모사를 위한 전기화학적 모델링)

  • Yang, Seungwon;Kim, Nayeon;Kim, Eunsae;Lim, Minhong;Park, Joonam;Song, Jihun;Park, Sunho;Appiah, Williams Agyei;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.22 no.1
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    • pp.43-52
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    • 2019
  • As the application area of lithium secondary batteries becomes wider, performance characterization becomes difficult as well as diverse. To address this issue, battery manufacturers have to evaluate many batteries for a longer period, recruit many researchers and continuously introduce expensive equipment. Simulation techniques based on battery modeling are being introduced to solve such difficulties. Various lithium secondary battery modeling techniques have been reported so far and optimal techniques have been selected and utilized according to their purpose. In this review, the electrochemical modeling based on the Newman model is described in detail. Particularly, we will explain the physical meaning of each equation included in the model; the Butler-Volmer equation, which represents the rate of electrode reaction, the material and charge balance equations for each phase (solid and liquid), and the energy balance. Moreover, simple modeling processes and results based on COMSOL Multiphysics 5.3a will be provided and discussed.

Analysis of the Esterification Process for Poly(ethylene terephthalate)

  • Ahn, Young-Cheol;Park, Soo-Myung
    • Macromolecular Research
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    • v.11 no.6
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    • pp.399-409
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    • 2003
  • The first esterification reactor in the continuous polymerization of poly(ethylene terephthalate) has been analyzed by solving the material balances for the two-phase system with respect to the solubility of terephthalic acid. The Newton-Raphson method was used to solve the material balance equations instead of the Simplex method that is frequently used for finding a minimum point of a residual rather than a solution of an equation. A solution for the material balance equations, with the constraint of non-zero liquid phase fraction, could not be obtained with the solubility data of Yamada et al., but could be obtained with solubilities over a minimum value that is larger than their data. Thus, the solubility data of Yamada et al. are considered to be too small. On the other hand, the solubility data of Baranova and Kremer are so large that they gave a solution with the liquid phase only. Based on our results, several typical solubility curves satisfying the constraint of a non-zero liquid phase fraction are suggested in this study; we studied the reaction characteristics of the system using these curves. A higher temperature and a lower pressure are preferred for reducing the content of diethylene glycol.

A CONCEPTUAL STUDY OF PYROPROCESSING FOR RECOVERING ACTINIDES FROM SPENT OXIDE FUELS

  • Yoo, Jae-Hyung;Seo, Chung-Seok;Kim, Eung-Ho;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.40 no.7
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    • pp.581-592
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    • 2008
  • In this study, a conceptual pyroprocess flowsheet has been devised by combining several dry-type unit processes; its applicability as an alternative fuel cycle technology was analyzed. A key point in the evaluation of its applicability to the fuel cycle was the recovery yield of fissile materials from spent fuels as well as the proliferation resistance of the process. The recovery yields of uranium and transuranic elements (TRU) were obtained from a material balance for every unit process composing the whole pyroprocess. The material balances for several elemental groups of interest such as uranium, TRU, rare earth, gaseous fission products, and heat generating elements were calculated on the basis of the knowledge base that is available from domestic and foreign experimental results or technical information presented in open literature. The calculated result of the material balance revealed that uranium and TRU could be recovered at 98.0% and 97.0%, respectively, from a typical PWR spent fuel. Furthermore, the anticipated TRU product was found to emit a non-negligible level of $\gamma$-ray and a significantly higher level of neutrons compared to that of a typical plutonium product obtained from the PUREX process. The results indicate that the product from this conceptual pyroprocessing should be handled in a shielded cell and that this will contribute favorably to retaining proliferation resistance.

A Study on the Change of Furturism Style in the Costume -Giacomo Balla and Fortunato Depero- (복식에 표현된 미래주의 양식과 그 변화에 관한 연구 -Giacomo Balla와 Fortunato Depero 중심으로-)

  • 박윤정;양숙희
    • The Research Journal of the Costume Culture
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    • v.6 no.4
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    • pp.84-103
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    • 1998
  • The purpose of this study si focused on Futurism style and contemporary fashion in the 20th century, by researching the Giacomo Balla, Fortunato Depero, Tullio Crali, Erenesto Thayate characteristics fashion design. The results of this study are following as : The general traits of Futurism style are classified with aesthetics, formative characteristics. First, aesthetic characteristics are based on H. Bergson's life-phylosophy and F. Nietzche's art theory. Second, formative characteristics is Dynamism. Futurism Dynamism are classified with psychological Dynamism and physical Dynamism. Futurism trends in the costume : first, dynamism in fashion design, second, asymmetrical balance, third, formativeness, forth, technology, fifth, anti-traditionalism. Dynamism are expressed textile, pattern and costuem shape in contemporary dress. Asymmetrical balance are expressed costume silhouette shape and framework through the geometrical asymmetrical balance. Formativeness are agree with Paco Rabanne's fashion design expressed body and movement and phychological world of human through the secondly fabric. Technology are expressed new mechanical dynamism in used technology art and new fashion material by metal. The last, anti-traditionalism is recognized new value and idea in fashion.

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Energy-balance assessment of shape memory alloy-based seismic isolation devices

  • Ozbulut, O.E.;Hurlebaus, S.
    • Smart Structures and Systems
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    • v.8 no.4
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    • pp.399-412
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    • 2011
  • This study compares the performance of two smart isolation systems that utilize superelastic shape memory alloys (SMAs) for seismic protection of bridges using energy balance concepts. The first isolation system is a SMA/rubber-based isolation system (SRB-IS) and consists of a laminated rubber bearing that decouples the superstructure from the bridge piers and a SMA device that provides additional energy dissipation and re-centering capacity. The second isolation system, named as superelastic-friction base isolator (S-FBI), combines the superelastic SMAs with a flat steel-Teflon bearing rather than a laminated rubber bearing. Seismic energy equations of a bridge structure with SMA-based isolation systems are established by absolute and relative energy balance formulations. Nonlinear time history analyses are performed in order to assess the effectiveness of the isolation systems and to compare their performance. The program RSPMatch 2005 is employed to generate spectrum compatible ground motions that are used in time history analyses of the isolated bridge. Results indicate that SRB-IS produces higher seismic input energy, recoverable energy and base shears as compared to the S-FBI system. Also, it is shown that combining superelastic SMAs with a sliding bearing rather than rubber bearing significantly reduce the amount of the required SMA material.

Ethyl Silicate Bonded Alumina as a Ceramic Binder

  • N, Korobova;Dea-Wha, Soh
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.103-107
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    • 2002
  • Ethyl silicate was used as organic binder for alumina refractories. In the present work only 15% of the water required for complete hydrolysis of ethyl silicate was initially added. The balance was provided from the atmosphere under controlled conditions of temperature and rh. The purpose of detailing the possible binder problem areas is more to indicate that the binder can have an effect on ceramic operations.

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Evaluation of Nitrogen and Phosphorus Balance in Green Manure-Rice Cropping Systems without Incorporation of Green Manure Crops (녹비작물 무 환원-벼 작부체계에서 질소와 인산수지 평가)

  • Kim, TaeYoung;Daquiado, Aileen Rose;Alam, Faridul;Lee, YongBok
    • Korean Journal of Environmental Agriculture
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    • v.31 no.4
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    • pp.308-312
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    • 2012
  • BACKGROUND: The nutrient balance in Korea during 1985-2006 had continually increased and maintained the highest levels among OECD countries. The use of green manure crops such as barley and hairy vetch is common practice for reducing chemical fertilizer application and maintaining soil fertility. However, green manure crops can also be used as a livestock feeding material which may reduce nutrient balance in the national scale. We calculated nitrogen and phosphate balance under green manure-rice cultivating system where all green manure was removed and used for feeding livestock. METHODS AND RESULTS: The barley and hairy vetch grown in pure stands or in mixtures with different sowing rates were tested for rice cultivation without chemical fertilization. The conventional fertilization (NPK) for rice cultivation was selected to compare nutrient balance with green manure-rice cultivation. Nitrogen and phosphate balance were calculated according to the surface balance method of the PARCOM guidelines. Total aboveground biomass of mixture (barley and hairy vetch) was higher compared to that of pure barley or hairy vetch. Among the mixture with barley and hairy vetch, the highest aboveground biomass was observed in B75H25 (barley 75%+hairy vetch 25%). The nitrogen and phosphate balance in the B75H25 mixture was-104 kg N/ha and-50.3 kg P/ha, respectively. CONCLUSION(S): The barley and hairy vetch mixture proved to be a very effective strategy for biomass production of green manure. The amount of nitrogen and phosphate fertilizer to be applied is estimated to be 104 kg N/ha and 50.3 kg P/ha in order to maintain soil fertility if all green manure and rice straw were removed from rice field for livestock feeding.

A Numerical Study of Heat and Mass Transfer Phenomena for Thermal Protection Material (열보호재료의 열 및 물질전달 현상에 관한 수치해석적 연구)

  • Kim, Jung-Hoon;Kwon, Chang-Oh;Seo, Jeong-Il;Bai, Cheol-Ho;Song, Dong-Joo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1201-1212
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    • 1999
  • A numerical analysis is performed to predict the thermal response and ablation rate for charring or non-charring material which is designed to be used as thermal protection system (TPS). The numerical program composed of in-depth energy balance equation and the aerotherm chemical equilibrium (ACE) program. The ACE program calculates various thermochemical state from ablation products. The developed numerical program is verified by comparing the reported results from literature. The sensitivity tests for input parameters are performed. The thermal behavior of ablating material is mainly affected by density of ablating material, convective heat transfer coefficient and recovery enthalpy of flow field.

On the analysis of delamination in multilayered inhomogeneous rods under torsion

  • Rizov, Victor I.
    • Coupled systems mechanics
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    • v.8 no.5
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    • pp.377-391
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    • 2019
  • The present paper is focused on analyzing the delamination of inhomogeneous multilayered rods of circular cross-section loaded in torsion. The rods are made of concentric longitudinal layers of individual thickness and material properties. A delamination crack is located arbitrary between layers. Thus, the internal and external crack arms have circular and ring-shaped cross-sections, respectively. The layers exhibit continuous material inhomogeneity in radial direction. Besides, the material has non-linear elastic behavior. The delamination is analyzed in terms of the strain energy release rate. General solution to the strain energy release rate is derived by considering the energy balance. The solution is applied to analyze the delamination of cantilever rod. For verification, the strain energy release rate is derived also by considering the complementary strain energy.