• Title/Summary/Keyword: mass fraction

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A Study on the Chemical Warfare Agents Dispersion Modelling in a Naturally Ventilated Indoor System (자연환기상태 실내공간에서의 화학작용제 확산 모델링 연구)

  • Kye, Young-Sik;Chung, Woo-Young;Kim, Yong-Joon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.4
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    • pp.133-140
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    • 2008
  • The purpose of this study is to provide response methods to minimize the damage from chemical terrorism in a naturally ventilated indoor system using several types of dispersion simulations. Three chemical warfare agents such as sarin(GB), phosgene and chlorine gas which have high potential to be used in terror or to be involved with accidents were selected in this simulation. Fire dynamic simulation based on Large Eddy Simulation which is effective because of less computational effort and detailed expression of the dispersion flow was adopted to describe the dispersion behavior of these agents. When the vent speed is 0.005m/s, the heights of 0.1 agent mass fraction are 0.9m for sarin, 1.0m for phosgene and 1.1m for chlorine gas, and the maximum mass fraction are 0.27 for all three agents. However, when the vent speed is increased to 0.05m/s, the heights of 0.1 agent mass fraction become 1.6m for all three agents and maximum mass fraction inside the room increase to 0.70 for sarin, 0.58 for phosgene and 0.53 for chlorine gas. It is shown that molecular weight of the agents has an important role for dispersion, and it is important to install ventilation system with height less than 1.6m to minimize the damage from chemical toxicity.

Characterization of ABS/PC/POE Thermoplastic Composites and Prediction of Mechanical Properties by Geometry Simulation (ABS/PC/POE 열가소성 복합재료의 특성평가 및 시뮬레이션을 통한 물리적 성능 예측 연구)

  • Yu, Seong-Hun;Lee, Jong-Hyuk;Yeo, Dong-Hyun;Shin, Yong-Ho;Park, Jong-Su;Sim, Jee-Hyun
    • Textile Coloration and Finishing
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    • v.34 no.2
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    • pp.117-126
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    • 2022
  • In this study, thermoplastic composites were manufactured using ABS(acrylonitrile butadiene styrene), PC(polycarbonate), and POE(polyolefin elastomer), which are thermoplastic plastics. Twin screw extruder and injection molding were used to manufacture thermoplastic composites. When the ABS/PC/POE thermoplastic composite material was manufactured, the POE mass fraction was set to 1 to 5 wt.%, and the thermal and mechanical properties according to the POE mass fraction were analyzed. Based on the physical properties of ABS/PC/POE, a 3D model in the form of an e-bike frame was created. After setting the boundary conditions, when an external load is applied, geometry simulation was performed to predict product performance. The ABS/PC/POE thermoplastic composite material exhibited the best physical properties when the mass fraction of POE was 3 wt.%. In the simulation results for the physical properties of the 3D model in the form of an e-bike frame, the best physical properties were shown when the mass fraction of POE was 2 ~ 3 wt.%. As a result, the manufacturing conditions for ABS/PC/POE thermoplastic composite materials were set, and research was conducted to reduce product development costs and development time.

Comparative GC-MS Based In vitro Assays of 5α-Reductase Activity Using Rat Liver S9 Fraction

  • Lee, Su-Hyeon;Lee, Dong-Hyoung;Lee, Jeong-Ae;Lee, Won-Yong;Chung, Bong-Chul;Choi, Man-Ho
    • Mass Spectrometry Letters
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    • v.3 no.1
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    • pp.21-24
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    • 2012
  • $5{\alpha}$-Dihydrotestosterone (DHT) is the primary active metabolite of testosterone, catalyzed by $5{\alpha}$-reductase ($5{\alpha}R$) in the skin, prostate, and liver. In this study, the $5{\alpha}R$ activity in rat liver S9 fraction in the presence of a NADPH-generating system was evaluated and compared by gas chromatography-mass spectrometry (GC-MS)-based in vitro assays. Testosterone and a $5{\alpha}R$ inhibitor, finasteride, were added to the S9 fractions and incubated at $37^{\circ}C$ for 1 h. Both testosterone and DHT were quantitatively measured and compared with two different GC-MS-based steroid profiling techniques. DHT was not detected by conventional GC-MS analysis in the absence of finasteride when the concentration of testosterone in the S9 fraction was less than $0.2{\mu}M$, whereas the isotope-dilution GC-MS (GC-IDMS) system was able to evaluate the $5{\alpha}R$ activity. Because the S9 fraction contains more reactive enzymes and is easier to collect from tissues compared with a microsomal solution, the combination of the S9 fraction and GC-IDMS technique may be a promising assay for evaluating the $5{\alpha}R$ activity in large-scale clinical studies.

Study on Oil Production from Pyrolysis of Mixed Plastic Waste Using Multidimensional Chromatography (Multidimensional Chromatography/Mass Spectrometry를 이용한 혼합 폐플라스틱의 열분해 오일 특성 평가에 관한 연구)

  • 김석완
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.375-382
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    • 2002
  • The total hydrocarbon distribution of oil products obtained from the pyrolysis of four kinds of mixtures of polyethylene-polystyrene waste has been studied by multidimensional chromatography(high performance liquid chromatography followed by capillary gas chromatography)/mass spectrometry. Saturated, unsaturated and aromatic hydrocarbons in oil products were selectively pre-separated according to structural groups by HPLC and the weight fraction of each group was estimated by analysis of each component using GC-FID response factors. The hydrocarbon distribution of aliphatic fraction consists of $C_{5}$ to $C_{25}$ saturated and unsaturated hydrocarbons. And that of aromatics fraction consists of benzene, toluene, xylene, styrene, propenyl benzene, naphthalene, and some of derivatives. Pyrolysis temperature did not affect the ratio of total weight fraction of aliphatic over aromatic hydrocarbon distribution in case of PS only and PE-PS mixtures (1:1 and 1:4 wt. ratio) as a feed while affected the ratio of total wt. fraction in case of PE only. The optimal temperature for the maximum oil production was $600^{\circ}C$ for pyrolysis of PS and 1:1 and 1:4 mixtures of PE and PS. The optimal condition for aromatic recovery was $600^{\circ}C$ with 1:1 mixture of PE and PS. In this condition, aromatic was produced up to 90% of total oil product. The maximum yield of toluene, xylene, styrene, and propenyl benzene were 8.6, 8.9, 51.0 and 7.4% of feed for pyrolysis PS at $700^{\circ}C$, respectively. However, only 1.3% naphthalene was recovered at $700^{\circ}C$ with 1:1 PE:PS(by wt.).

Properties of Galaxies in Cosmic Filaments around the Virgo Cluster

  • Lee, Youngdae;Kim, Suk;Rey, Soo-Chang;Chung, Jiwon
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.64.2-64.2
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    • 2020
  • We present the properties of galaxies in filaments around the Virgo cluster with respect to their vertical distance from the filament spine. Using the NASA-Sloan Atlas and group catalogs, we select galaxies that do not belong to groups in filaments. The filament member galaxies are then defined as those located within 3.5 scale length from the filament spine. The filaments are mainly (~86%) composed of low-mass dwarf galaxies of logh2M∗/M⊙ < 9 dominantly located on the blue cloud in color-magnitude diagrams. We observe that the g - r color and stellar mass of galaxies correlate with their vertical distance from the filament spine in which the color becomes red and stellar mass decreases with increasing vertical filament distance. The galaxies were divided into two subsamples in different stellar mass ranges, with lower-mass (logh2M∗/M⊙ ≤ 8) galaxies showing a clear negative g-r color gradient, whereas higher-mass (logh2M∗/M⊙ > 8) galaxies have a flat distribution against the vertical filament distance. We observe a negative EW(Hα) gradient for higher-mass galaxies, whereas lower-mass galaxies show no distinct variation in EW(Hα) against the vertical filament distance. In contrast, the NUV - r color distribution of higher-mass galaxies shows no strong dependence on the vertical filament distance, whereas the lower-mass galaxies show a distinct negative NUV - r color gradient. We do not witness clear gradients of HI fraction in either the higher- or lower-mass subsamples. We propose that the negative color and stellar mass gradients of galaxies can be explained by mass assembly from past galaxy mergers at different vertical filament distances. In addition, galaxy interactions might be responsible for the contrasting features of EW(Hα) and NUV - r color distributions between the higher- and lower-mass subsamples. The HI fraction distributions of the two subsamples suggest that ram-pressure stripping and gas accretion could be ignorable processes in the Virgo filaments.

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Development and mechanical properties of bagasse fiber reinforced composites

  • Cao, Yong;Goda, Koichi;Shibata, Shinichi
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.283-298
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    • 2007
  • Environment-friendly composites reinforced with bagasse fiber (BF), a kind of natural fiber as the remains from squeezed sugarcane, were fabricated by injection molding and press molding. As appropriate matrices for injection molding and press molding, polypropylene (PP) and polycaprolactone-cornstarch (PCL-C) were selected, as a typical recyclable resin and biodegradable resin, respectively. The mechanical properties of BF/PP composites were investigated in view of fiber mass fraction and injection molding conditions. And the mechanical properties and the biodegradation of BF/PCL composites were also evaluated. In the case of injection molding, the flexural modulus increased with an increase in fiber mass fraction, and the mechanical properties decreased with an increase in cylinder temperature due to the thermal degradation of BF. The optimum conditions increasing the flexural properties and the impact strength were $90^{\circ}C$ mold temperature, 30 s injection interval, and in the range of 165 to $185^{\circ}C$ cylinder temperature. On the other hand, as to BF/PCL-C fully-green composites, both the flexural properties and the impact strength increased with an increase in fiber mass fraction. It is considered that the BF compressed during preparation could result in the enhancement in mechanical properties. The results of the biodegradability test showed the addition of BF caused the acceleration of weight loss, which increased further with increasing fiber content. This reveals that the addition and the quantities of BF could promote the biodegradation of fully-green composites.

Experimental Study of Molten Wood's Metal Jet Breakup in Subcooled Water (과냉각수조 내의 제트에 의한 용융우드메탈 미립화에 관한 실험적 연구)

  • Heo, Hyo;Jerng, Dong Wook;Bang, In Cheol
    • Journal of ILASS-Korea
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    • v.19 no.4
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    • pp.197-203
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    • 2014
  • The liquid jet breakup has been studied in the areas such as aerosols, spray and combustion. The breakup depends on several physical parameters such as the jet velocity, the nozzle inner diameter, and the density ratio of the water to the jet. This paper deals with characteristics of the jet breakup according to the jet velocity and the nozzle diameter. In order to consider only hydrodynamic factors, all the experiments were conducted in non-boiling conditions. The jet behavior in the water pool was observed by high-speed camera and PIV technique. For the condition of the inner diameter of 6.95 mm and the jet velocity of 2.8 m/s, the debris size of 22 mm gave the largest mass fraction, 39%. For higher jet velocity of 3.1 m/s, the debris size of 14 mm gave the largest mass fraction, 36%. For the nozzle with inner diameter of 9.30 mm, the debris size distribution was different. For jet velocity of 2.8 m/s and 3.1 m/s, the debris size with the largest mass fraction was found to be 14 mm. It was identified that the debris size decreased as the diameter or the jet velocity increased.

A Study on Combustion Characteristic Methane Fuel according to Torch Volume Variation in a Constant Volume Combustion Chamber (정적연소기에서 토치의 체적 변화에 따른 메탄의 연소특성 파악)

  • Kwon, Soon-Tae;Park, Chan-Jun;Ohm, In-Young
    • Journal of the Korean Society of Visualization
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    • v.9 no.1
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    • pp.42-48
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    • 2011
  • Six different size of torch-ignition device were applied in a constant volume combustion chamber for evaluating the effects of torch-ignition on combustion. The torch-ignition device was designed for six different volumes and same orifice size. The combustion pressures were measured to calculate the mass burn fraction and combustion enhancement rate. In addition, the flame propagations were visualized by shadowgraph method for the qualitative comparison. The result showed that the combustion pressure and mass burn fraction were increased when using the torch ignition device. And the combustion duration were decreased. The combustion enhancement rates of torch-ignition cases were improved in comparison with conventional spark ignition. Finally, the visualization results showed that the torch-ignition induced faster burn than conventional spark ignition due to the earlier transition to turbulent flame and larger flame surface, during the initial stage. Finally, the initial flame propagation was affected by torch-ignition volume.

Study on the cooling performance of discrete heat sources using coolants (냉각제들에 따른 불연속 발열체의 냉각성능 연구)

  • 최민구;조금남
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.2
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    • pp.224-235
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    • 1999
  • The present study investigated the effects of the experimental parameters on the cooling characteristics of the multichip module cooled by the indirect liquid cooling method using water, PF-5060, and paraffin slurry. The experimental parameters were coolants including Paraffin slurry with mass fraction of 2.5~7.5%, heat flux of 10~40W/$\textrm{cm}^2$ for the simulated VLSI chips and Reynolds numbers of 3,000~20,000. The size of paraffin slurry was constant as 10~40${\mu}{\textrm}{m}$ before and after the experiment. The chip surface temperatures for paraffin slurry were lower than those for water and PF-5060. The local heat transfer coefficients for the paraffin slurry were larger than those for water and the local heat transfer coefficients reached a row-number-independent and thermally-fully-developed value approximately after the third row. The local Nusselt numbers for paraffin slurry with a mass fraction of 7.5% were larger by 20~38% than those for water. The paraffin slurry with a mass fraction of 5% shelved the best thermal and hydrodynamic characteristics when local heat transfer and pressure drop were considered simultaneously.

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Laser Diagnostics of Spray and Combustion Characteristics Using Multi-Component Mixed Fuels in a D.I. Diesel Engine (다성분 혼합연료를 이용한 디젤 분무 및 연소특성의 광계측 진단)

  • Yoon, Jun-Kyu;Myong, Kwang-Jae;Senda, Jiro;Fujimoto, Hajime;Cha, Kyung-Ok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.172-180
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    • 2006
  • This study was to analyze the effect of mixed fuel composition and mass fraction on the characteristics of evaporating diesel spray and combustion under the various ambient conditions. The characteristics of vaporization distribution and combustion were visualized by laser induced fluorescent method and direct photography. The experiments were conducted in the constant volume vessel and rapid compression expansion machine with optical access. Multi-component fuels mixed i-octane, n-dodecane and n-hexadecane were injected the vessel and rapid compression expansion machine with electronically controlled common rail injector. Experimental results show that fuel vapor formed stratified distribution. And vaporization and diffusion are become actively increasing in mass fraction of low boiling point component. Consequently multi-component fuels were expected to control the evaporating behavior according to their suitable mass fraction.