• KEPCO Journal on Electric Power and Energy
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• v.5 no.3
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• pp.181-188
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• 2019

In this study, the Heat & Mass balance design optimization tool has developed by linking the design input/output variables with the Heat & Mass balance calculation solver and optimization algorithm and also automating the iterative calculation process. As a result of testing this optimization tool for 10 kinds of power plant, it was expected to improve the NPV and IRR compared with general design methods.

• Korean Journal of Soil Science and Fertilizer
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• v.24 no.2
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• pp.124-129
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• 1991

A mass balance method which measures directly both the sorbed pesticide and equilibrium solution concentration was compared with the batch method in a hypothetical experiment to determine the precision of sorption measurement. The mass balance method was shown to improve precision of sorption measurement. The two methods were also tested experimentally on the Wahiawa soil, 0-20, 40-60 and 100-120 cm, and Salinas soil, 0-15 and 115-130 cm. The mass balance method greatly improved precision of sorption measurement on the deep Wahiawa subsoil having the lowest sorption. The coefficient of variation (CV) for $K_d$ measurement was 20.3% for the batch method and 8.4% for the mass balance method. For other soil samples tested, precision of the batch method was relatively high but was still improved by the mass balance method.

• Journal of Environmental Science International
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• v.17 no.4
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• pp.359-364
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• 2008

PM10 samples were collected from July 2007 to Oct. 2007 at Gwaebopdong(inland area) and Dongsamdong(coastal area), in Busan. This paper investigates the contribution of emission sources to PM10 mass in Busan. Source apportionment results derived from the chemical mass balance(CMB) method. A source profiles applied in this study is organized to minimize the collinearity among sources type via statistical method. Source profiles applied in this study utilized a measured value of fine particle directly sampled from metropolitan area such as Seoul and Incheon, After a CMB modeling, sulfate and nitrate related sources among those contributing to PM10 in Busan showed high contribution by 36.53% in Gwaebopdong and 42.02% in Dongsamdong.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2006.05a
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• pp.314-319
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• 2006

Main focus on balance shaft module is to reduce the vibration triggered from engine block and compensate it from unbalance mass in balance shaft. Since the performance of balance shaft module is controlled by rotor shape including unbalance mass, a design strategy on rotor is key issue on determine the quality of balance shaft system. Even the design result on balance shaft mostly affect the lay-out of housing and other related components, its issue on balance shaft should be considered in advance throughout the total design procedure. In this paper, optimal design strategy focused on balance shaft is presented to make a design process efficiently with ensuring its high performance. And its method is verified with field design process of balance shaft in commonly adapted vehicle with 3-cylinder and 4-cylinder engine.

• Journal of Korean Society of Water and Wastewater
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• v.37 no.6
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• pp.347-361
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• 2023

Water utilities are making various efforts to reduce water losses from water networks, and an essential part of them is to recognize the moment when a pipe burst occurs during operation quickly. Several physics-based methods and data-driven analysis are applied using real-time flow and pressure data measured through a SCADA system or smart meters, and methodologies based on machining learning are currently widely studied. Water utilities should apply various approaches together to increase pipe burst detection. The most intuitive and explainable water balance method and its procedure were presented in this study, and the applicability and detection performance were evaluated by applying this approach to water supply pipelines. Based on these results, water utilities can establish a mass balance-based pipe burst detection system, give a guideline for installing new flow meters, and set the detection parameters with expected performance. The performance of the water balance analysis method is affected by the water network operation conditions, the characteristics of the installed flow meter, and event data, so there is a limit to the general use of the results in all sites. Therefore, water utilities should accumulate experience by applying the water balance method in more fields.

• Analytical Science and Technology
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• v.30 no.5
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• pp.226-233
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• 2017

In general, quantitative chemical analysis in various areas including food, the environment, in vitro diagnostics, etc., requires traceability in order to increase the reliability of the measurements. Measurement traceability is a property of an unbroken chain of comparisons relating an instrument's measurements to SI units. Purity analysis is the first process for establishing traceability to SI units in chemical measurements. The purpose of this study is to develop and validate a method of purity assignment for establishing the traceability of $17{\beta}$-estradiol measurements in an in vitro diagnostics field. The establishment of this method is very important as it can be applied to the development of CRM and to the analysis of the purity of other hormones. The method of assignment of the purity of $17{\beta}$-estradiol was developed using the mass balance method and was validated through participation in an International comparison. In the mass balance method, impurities are categorized into four classes as follows: total related structure impurities, water, residual organic solvents, and nonvolatiles/inorganics. In this study, total related structure impurities were characterized by a gas chromatography-flame ionization detector (GC-FID) and a high-performance liquid chromatography-ultraviolet (HPLC-UV) detector, water content was determined by a Karl-Fisher coulometer, and total residual solvents and nonvolatiles/inorganics were checked simultaneously by thermogravimetric analysis (TGA). The purity of the $17{\beta}$-estradiol was 985.6 mg/g and the expanded uncertainty was 2.1 mg/g at 95% confidence. The developed method can be applied to the development of certified reference materials, which play a critical role in traceability.

• Environmental Engineering Research
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• v.20 no.2
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• pp.191-197
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• 2015

The first objective of this study was to discuss the applicability of the $CO_2/CH_4$ ratio method in order to assess $CH_4$ oxidation efficiency. To achieve this objective, a comparison between $CO_2/CH_4$ ratios and the mass balance method was conducted. The second objective of this study was to estimate the $CH_4$ oxidation efficiency in an interim landfill soil cover and assess how a $CH_4$ influx influences the $CH_4$ oxidation efficiency. The results showed that despite the $CO_2$ problems brought by respiration, the $CH_4$ oxidation efficiencies obtained by the $CO_2/CH_4$ ratio method led to similar results compared to the mass balance method. In this respect, the $CO_2/CH_4$ ratio method can be an indicator of the $CH_4$ oxidation efficiencies for landfill cover soils. The $CH_4$ oxidation efficiencies derived in this study through the $CO_2/CH_4$ ratio method ranged between 46% and 64%, and between 41% and 62% through the mass balance method. The results imply that the Intergovernmental Panel on Climate Change's (IPCC) default value of 10% for the $CH_4$ oxidation efficiency is an underestimation for landfill cover soils. $CH_4$ oxidation efficiency tends to be negatively correlated with $CH_4$ influx. Therefore, $CH_4$ influx reaching a landfill cover should be limited in order to increase the $CH_4$ oxidation efficiency.

• Natural Product Sciences
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• v.25 no.3
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• pp.222-227
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• 2019

Quantitative nuclear magnetic resonance (qNMR) is a well-established method adopted by international pharmacopoeia for quantitative and purity analyses. Emodin is a type of anthraquinone, well known as the main active component of Fabaceae, Polygonaceae and Rhamnaceae. Purity analysis of emodin is usually performed by using the high-performance liquid chromatography (HPLC)-UV method. However, it cannot detect impurities such as salts, volatile matter, and trace elements. Using the qNMR method, it is possible to determine the compound content as well as the nature of the impurities. Several experimental parameters were optimized for the quantification, such as relaxation delay, spectral width, number of scans, temperature, pulse width, and acquisition time. The method was validated, and the results of the qNMR method were compared with those obtained by the HPLC and mass balance analysis methods. The qNMR method is specific, rapid, simple, and therefore, a valuable and reliable method for the purity analysis of emodin.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.5B
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• pp.475-483
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• 2008

2D finite element model for analysis of transport of accidentally released pollutants in the flow was developed by SUPG method, and the mass balance of this model was checked though two example problems: line source and point source problem in the straight channel and unidirectional 2D flow field, respectively. All the test cases were simulated with both SUPG and conventional Galerkin method to compare the accuraccy of the numerical mass balance. Test results show that the model with SUPG can adequately conserve the released mass though simulation than the model using Galerkin method, so the developed model verified to be appropriate to solve this accidental mass release problem.

• Analytical Science and Technology
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• v.32 no.6
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• pp.225-232
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• 2019

Traceability establishment in chemical measurements is a like a linkage established through an unbroken chain from the measured results to the international system (SI) of units. The primary process for traceability establishment is the purity assignment of a target material to be measured. In this study, we studied the purity assignment of 17α-hydroxyprogesterone (17-OHP). The presence of 17-OHP is indicative of congenital adrenal hyperplasia (CAH) and it builds up due to the deficiency of 21-hydroxylase and 11β-hydroxylase enzyme in the human blood. The purity assignment of 17-OHP was performed by the mass balance method, in which the impurities are categorized into four classes: total related structural impurities, water, residual organic solvents, and nonvolatiles/inorganics. The total related structural impurities were characterized by HPLC-UV; water content was determined by Karl-Fisher coulometer; and the total residual solvents and nonvolatiles/inorganics were determined by TGA. The purity of 17-OHP from a commercial manufacturer was calculated as 993.30 mg/g, and the expanded uncertainty was 0.58 mg/g. The proposed method was validated by uncertainty evaluation and comparing with the actual value of purity.