• 한국세라믹학회지
• /
• 제48권6호
• /
• pp.577-583
• /
• 2011

Stabilized biocompatible superparamagnetic iron oxide nanoparticles (SPIONs) were prepared by controlled coprecipitation method for hyperthermia application. ESR measurements determined that all of the interactions in the individual SPIONs (1 nm and 11 nm) were antiferromagnetic in nature because the ions contributed to the magnetization with a range of magnetic moments. In-situ monitoring of the temperature increment was performed, showing that the microwave absorption rate of the SPIONs was dispersed in an appropriate host media (polar or non-polar solvents) during microwave irradiation. Microwave absorption energy rates and heat loss of SPIONs in solvent were calculated by non-linear data fitting with an energy balance equation. The microwave absorption rates of SPIONs dispersed in solvent linearly increases when the concentration of SPIONs increases, implying that the microwave absorption rate can be tunable by changing the concentration of SPIONs.

• 한국세라믹학회지
• /
• 제47권1호
• /
• pp.8-18
• /
• 2010

When metal oxides are exposed to chemical potential gradients, ions are driven to diffusive mass transport. During this transport process, the divergence of ionic fluxes offers the formation/annihilation of oxides. Therefore, the divergence of ionic flux may play an important role in the void formation in oxides. Kinetic equations were derived for describing chemical potential distribution, ionic fluxes and their divergence in oxides. The divergence was found to be the measure of void formation. Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior. The quantitative estimation on the void formation was successfully applied to a growing magnetite scale in high temperature oxidation of iron at 823 K.

• 통합자연과학논문집
• /
• 제1권3호
• /
• pp.247-249
• /
• 2008

자성 결정체인 $Fe_3O_4$ 나노 입자를 합성하기위하여 강한 극성 용매인 2-pyrrolidone을 연전도 반응매개체로 하여 용액 내에 $FeCl_3{\cdot}6H_2O$을 용해시켜 2-pyrrolidone의 비등점까지 나노 결정체 고온 열분해 방법을 이용하여 제조되었다. 고온 열분해 후, $Fe_3O_4$ 나노 입자는 methanol/diethyl ether (1:3)에 의해서 침전되어졌다. 합성된 $Fe_3O_4$ 나노 입자는 고결정도, 고자기성을 가지고 있으며, 수용성의 자성 나노 결정체이다. 합성된 $Fe_3O_4$ 나노 입자의 크기와 결정도는 transmission electron microscope (TEM, Tecnai F20)를 이용하여 특성 분석하였으며, area electron diffraction (SAED) pattern과 HRTEM을 이용하여 나노입자의 격자 패턴 (lattice fringes)을 확인하였다.

• Corrosion Science and Technology
• /
• 제11권3호
• /
• pp.82-88
• /
• 2012

The thickness and chemical composition of oxides on heat recovery steam generator tubes of combined cycle power plant were examined in order to evaluate the corrosion of the tubes. Tubes were removed from the plant after actual operations for 21,482, 42,552 and 56,123 hours respectively. Thickness and growth rate of the oxide scale on reheater inner tube (SA213-T22) were very high compared to those other tubes. The oxide scale was about $250{\mu}m$ thick and uniform. The components of the scale were iron oxides. The oxide scale was mixed oxides consisting of magnetite$(Fe_3O_4)$ and hematite$(Fe_2O_3)$. The oxide on inner tube was removed using many kinds of chemicals and it was found that chelating agents were dissolved faster than other chemicals.

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2015년도 추계학술논문요약집
• /
• pp.465-466
• /
• 2015

In this study, different amount of (fe(0)) were dissolve into different strength of phosphoric ($H_3PO_4$) acid and the optimum solubility was observed at 0.89M Fe(0) into 4M of $H_3PO_4$ acid. Different concentration of oxalic acid was added to determine the optimum precipitated condition. The dissolution kinetics of Fe(0) into $H_3PO_4$ acid was investigated at $40-50^{\circ}C$. The optimum Fe-oxalate precipitate was dried and thermal decomposition using DSC-TG was conducted. Approximately 52 wt(%) of oxalic acid was removed at $300^{\circ}C$. Iron oxides such as magnetite and hematite that may be formed on the surface of nuclear waste were also dissolved into the $H_3PO_4$ acid and the optimum solubility for magnetite is 0.005M while that for hematite is 0.02M in 8M $H_3PO_4$ acid, respectively.

• Advances in environmental research
• /
• 제1권1호
• /
• pp.1-14
• /
• 2012

We demonstrated that reductive degradation of 2,4,6-Trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (Royal Demolition Explosive, RDX) can be enhanced by bio-reduced iron-bearing soil minerals (IBSMs) using Shewanella putrefaciens CN32 (CN32). The degradation kinetic rate constant of TNT by bio-reduced magnetite was the highest (0.0039 $h^{-1}$), followed by green rust (0.0022 $h^{-1}$), goethite (0.0017 $h^{-1}$), lepidocrocite (0.0016 $h^{-1}$), and hematite (0.0006 $h^{-1}$). The highest rate constant was obtained by bio-reduced lepidocrocite (0.1811 $h^{-1}$) during RDX degradation, followed by magnetite (0.1700 $h^{-1}$), green rust (0.0757 $h^{-1}$), hematite (0.0495 $h^{-1}$), and goethite (0.0394 $h^{-1}$). Significant increase of Fe(II) was observed during the reductive degradation of TNT and RDX by bio-reduced IBSMs. X-ray diffraction and electron microscope analyses were conducted for identification of degradation mechanism of TNT and RDX in this study. 4-amino-dinitrotoluene were detected as products during TNT degradation, while Hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine, Hexahydro-1,3-dinitroso-5-nitro-1,3,5triazine, and Hexahydro-1,3,5-trinitroso-1,3,5-triazine were observed during RDX degradation.

• 보존과학회지
• /
• 제25권4호
• /
• pp.399-409
• /
• 2009

외부 환경에 노출된 철제문화재는 환경오염요인에 직접적으로 영향을 받아 부식에 취약하다. 특히 철제유물에 있어서 활성부식을 일으키는 염화이온($Cl^-$)은 반드시 제거되어야 하지만 옥외 철제문화재는 유물의 특성상 탈염의 대상에서 제외되고 있다. 그러므로 본 연구에서는 조선시대 철비를 대상으로 보존처리 및 탈염실험을 실시하였으며, 탈염은 흡습지를 이용한 탈염방법과 기존의 침적탈염방법을 함께 실시하여 그 효율성을 비교하였다. 탈염의 평가는 실체 금속 현미경, SEM-EDS, pH측정과 이온크로마토그래피(IC), XRD분석을 통하여 알아보았다. 실체 금속현미경으로 조사된 결과 부식은 층을 이루고 있으며 금속조직은 백주철로 확인된다. 또한 탈염 전 부식물에 대한 SEM-EDS분석결과 Fe와 O가 주로 검출되었으며 특히 Cl이 2.48wt%까지 측정되었다. 탈염용액에 대한 pH와 음이온을 분석한 결과에서는 흡습지를 이용한 탈염방법도 침적탈염방법과 유사한 탈염효과를 볼 수 있었다. 마지막으로 탈염 전 후 부식물에 대한 XRD분석 결과 탈염전에는 goethite, magnetite, lepidocrocite와 akaganeite가 검출되었으나 탈염 후에는 akaganeite가 검출되지 않아 흡습지를 이용한 탈염의 효과를 확인할 수 있었다. 그러므로 본 연구를 통하여 흡습지를 이용한 탈염방법에서도 기존의 침적탈염방법과 유사한 탈염효과를 확인할 수 있었다.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.398-403
• /
• 2001

There is a potential usability of electric arc furnace(EAF) dust produced during the iron manufacturing process as a recycled resource, because valuable materials such as Zn, Pb and Fe are contained in it. In this study, metallic Zn was recycled from the fine electric arc furnace dust by a solid state reduction method using carbon at relatively low temperature. It was possible to recover metallic zinc by using of high vapour pressure of zinc with this reduction method. The feasibility of recycled zinc for cold bonded pellet(CBP) was investigated. The main composition of EAF dust were franklinite(ZnFe$_2$O$_4$), magnetite(Fe$_3$O$_4$) and zincite(ZnO), and Pb and Cl were completely removed by a heat treatment in oxidation environment. The reduction ratio increased as the solid carbon content increased, and it increased with decreasing of dust particle size and increasing of compaction pressure due to a increase of contact area.

• 한국재료학회지
• /
• 제16권11호
• /
• pp.687-691
• /
• 2006

Synthesis of Iron oxides by air oxidation of $FeSO_4$ solutions in the presence of NaOH, Diethylenetriamine (DETA), Butylamine (BA) and influence of ultrasonic wave were investigated by XRD, SEM and particle size analyzer. As the DETA addition increased to 0.05 mol, $Fe_3O_4$ was formed with goethite($\alpha$- FeOOH) and $Fe_3O_4$ single phase was formed above 0.18mol of DETA. As the BA addition increased, the XRD peak intensity of (020) face of lepidocrocite($\gamma$-FeOOH) was developed until the formation of $Fe_3O_4$ and reduced the size of the iron oxide particles formed. Ultrasonic wave reduced the size of the iron oxide particles but gave little effects on the iron oxide particles synthesized by amine.

• 한국초전도ㆍ저온공학회논문지
• /
• 제21권2호
• /
• pp.22-25
• /
• 2019

The superconducting magnetic separation system has been developing to separate the iron oxide scale from the feed water of the thermal power plant. The accumulation in the boiler lowers the heat exchange rate or in the worst case damages it. For this reason, in order to prevent scale generation, controlling pH and redox potential is employed. However, these methods are not sufficient and then the chemical cleaning is performed regularly. A superconducting magnetic separation system is investigated for removing iron oxide scale in a feed water system. Water supply conditions of the thermal power plant are as follows, flow rate 400 t / h, flow speed 0.2 m / s, pressure 2 MPa, temperature $160-200^{\circ}C$, amount of scale generation 50 - 120 t / 2 years. The main iron oxide scale is magnetite (ferromagnetic substance) and its particle size is several tens ${\mu}m$. As the first step we are considering to introduce the system to the chemical cleaning process of the thermal power plant instead of the thermal power plant itself. The current status of development will be reported.