• Journal of the Korean Magnetics Society
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• v.16 no.5
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• pp.261-263
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• 2006

In order to investigate the magnetic properties of Eu ions in the single crystal $MnF_2$, the temperature dependent magnetic susceptibilities of the antiferromagnetic $MnF_2$ and the single crystal $MnF_2$(1.5% $EuF_3$) with the rutile structures were measured in the temperature range from 4K to 300K. The detailed analysis of the measured susceptibilities showed that the magnetic susceptibility by the doping of the small amount $EuF_3$ in the antiferromagnetic single crystal $MnF_2$ follows the antiferromagnetic Curie-Weiss law with the negative paramagnetic Curie temperature similarly as in $MnF_2$. It was also found that Eu ion has +3 valence. This solves the long standing discrepancy on this problem.

• Proceedings of the Korean Magnestics Society Conference
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• 2008.12a
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• pp.38.2-38.2
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• 2008

• Journal of the Korean Geographical Society
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• v.44 no.4
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• pp.463-480
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• 2009

The weathering properties and provenance of loess-paleosol sequence deposited on gravel layer of river terrace in Bongdong-eup, Wangju-gun, Jeonbuk Province are examined using soil analysis, magnetic susceptibility measurement, grain size and element analysis. The Bongdong section consists of, from top to bottom, Layer 1(paleosol), Layer 2(loess), Layer 3(paleosol) and the gravel layer of river terrace. The magnetic susceptibility values show the systematic variations in the sequence and the results of grain size analysis reveal that the sequence was deposited by not fluvial or slope process, but eolian process, and that contains finer materials than the Daecheon loess and Chinese Loess Plateau. Among the results of soil analysis, organic contents indicate systematic variations similar to the magnetic susceptibility. The wet soil colors further reflect the characteristics of the sequence rather than the dry soil colors. Based on the analytical results of major and rare earth elements, the eolian materials contained in the sequence were deposited by the materials originated from the areas where the Chinese Loess Plateau has been originated or the reworked materials from the Chinese Loess Plateau, and after the depositions, the materials experienced the intensive chemical weathering under the humid-warm climatic conditions in the Korean Peninsula.

• Journal of the Korean earth science society
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• v.23 no.1
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• pp.87-96
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• 2002

Aeromagnetic and gravity data were analyzed to delineate the subsurface structure of the Yeongdong basin and its related fault movement in the Okcheon fold belt. The aeromagnetic data of the total intensity (KIGAM, 1983) were reduced to the pole and three dimensional inverse modeling, which considers topography of the survey area in the modeling process, were carried out. The apparent susceptibility map obtained by three dimensional magnetic inversion, as well as the observed aeromagnetic anomaly itself, show clearly the gross structural trend of the Yeongdong basin in the direction on between $N30^{\circ}E$ and $N45^{\circ}E$. Gravity survey was carried out along the profile, of which the length is about 18.2 km across the basin. Maximum relative Bouguer anomaly is about 7 mgals. Both forward and inverse modeling were also carried out for gravity analysis. The magnetic and gravity results show that the Yeongdong basin is developed by the force which had created the NE-SW trending the magnetic anomalies. The susceptibility contrast around Yeongdong fault is apparent, and the southeastern boundary of the basin is clearly defined. The basement depth of the basin appears to be about 1.1 km beneath the sea level, and the width of the basin is estimated to be 7 km based on the simultaneous analysis of gravity and magnetic profiles. There exists an unconformity between the sedimentary rocks and the gneiss at the southeastern boundary, which is the Yeongdong fault, and granodiorite is intruded at the northwestern boundary of the basin. Our results of gravity and magnetic data analysis support that the Yeongdong basin is a pull-apart basin formed by the left-stepping sinistral strike-slip fault, which formed the Okcheon fold belt.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3615-3620
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• 2013

Two novel copper(II) bromide complexes with pyridine containing Schiff base ligands, $Cu(pmed)Br_2$ and $Cu(pmed)Br_2$ where pmed = N'-((pyridin-2-yl)methylene)ethane-1,2-diamine (pmed) and dpmed = N,N-diethyl-N'-((pyridin-2-yl)methylene)ethane-1,2-diamine (dpmed) were synthesized and characterized using X-ray single crystal structure analysis, optical and magnetic susceptibility measurements. Crystal structural analysis of $Cu(pmed)Br_2$ showed that the copper(II) ion has a distorted square-pyramidal geometry with the trigonality index of ${\tau}=0.35$ and two intermolecular hydrogen bonds, which result in the formation of two dimensional networks in the ab plane. On the other hand, $Cu(pmed)Br_2$ displayed a near square-pyramidal geometry with the value of ${\tau}=0.06$. In both compounds, the NNN Schiff base and one Br atom occupy the basal plane, whereas the fifth apical position is occupied by the other Br atom at a greater Cu-Br apical distance. The reported complexes show $g_{\mid}$ > $g_{\perp}$ > 2.0023 with a $d_{x2-y2}$ ground state and a penta-coordinated square pyramidal geometry. Variable temperature magnetic susceptibility measurements showed that the developed copper(II) complexes follow the Curie-Weiss law, that is there are no magnetic interactions between the copper(II) ions since the Cu--Cu distance is too far for magnetic contact.

• Journal of The Geomorphological Association of Korea
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• v.19 no.4
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• pp.157-168
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• 2012

The Eonyang section is located at the confluent area of Samdong River to Taehwa River in Sinhwa-ri, Samnam-myeon, Ulju-gun, Ulsan-si, Korea. Physical analyses such as the OSL age dating, magnetic susceptibility and grain size analysis were performed. Coarse grains in the upper section were deposited by the aeolian processes from the local sources and the grains in the lower section by the fluvial processes. The Eonyang section shows the large differences such as the irregularity in the variations of magnetic susceptibility, large deviations in the Y values and very poor sorting values from the loess sediments in Bongdong, Geochang and Daecheon in Korea. These characteristics in the Eonyang section suggest the multi-source areas such as the Chinese Loess Plateau and nearby floodplain or the influences by the other processes. The loess sediments of Eonyang section were formed during the period from the late MIS 3 to MIS 2.

• Journal of The Geomorphological Association of Korea
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• v.17 no.3
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• pp.31-47
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• 2010

The history of mass movement has been reconstructed from the Angol basin in Guryongcheon drainage basin. Sedimentary facies study, radiocarbon dating, particle size analysis, magnetic susceptibility and geomorphological analysis have been performed to reconstruct the paleo-environmental history of Angol basin. From 40,480 to 9,850yrBP there were five periods of slope instability and from 9,850yrBP to present there were at least four periods of slope instability. Magnetic susceptibility curves match well with the sedimentary facies data. This study may help reconstruct the denudational history of the small basins in Cheonan area and could be the cornerstone of the paleo-climatological study of the Korean Peninsula.

• Bulletin of the Korean Chemical Society
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• v.14 no.4
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• pp.465-468
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• 1993

Four compounds containing two 2,2,6,6-tetramethylpiperidin-1-yloxyl radicals were synthesized. They are all chemically bonded with squaric moieties. The diradical compounds show fundamentally the paramagnetic behaviors satisfying the theoretical magnetic susceptibility according to Curie's law. A diradical compound of salf-form 4 however shows a relatively strong antiferromagnetic interaction in comparison with other reported organic radicals. The antiferromagnetic interaction of diradical 4 approximates a value of J/k= -50 K by the theoretical analysis of its temperature dependence.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1603-1606
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• 2009

A new 1D oxalato bridged compound Ni(en)(ox)-2$H_2$O, (ox = oxalate; en = ethylenediamine) has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR spectrum, TG analysis, and magnetic measurements. In the structure the Ni atoms are coordinated with four oxygen atoms in two oxalate ions and two nitrogen atoms in one ethylenediamine molecule. The oxalate anion acts as a bis-bidentate ligand bridging Ni atoms in cis-configuration. This completes the infinite zigzag neutral chain, [Ni(en)(ox)]. The interchain space is filled by water molecules that link the chains through a network of hydrogen bonds. Thermal variance of the magnetic susceptibility shows a broad maximum around 50 K characteristic of one-dimensional antiferromagnetic coupling. The theoretical fit of the data for T > 20 K led to the nearest neighbor spin interaction J = -43 K and g = 2.25. The rapid decrease in susceptibility below 20 K indicate this compound to be a likely Haldane gap candidate material with S = 1.

• Bulletin of the Korean Chemical Society
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• v.11 no.6
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• pp.564-567
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• 1990

A lithiated compound $Li_{0.1}Pr^{3+}Ba_2Cu_3O_y$ has been successfully prepared by electrochemical method, which is achieved with a two electrode cell of the type: Metal(Li)/($Li^+\;,\;ClO_4^-$) + propylene carbonate/$PrBa_2Cu_3O_y$. All Pr ions in the lithiated compound are stabilized with a trivalent state as the other rare earths (Ⅲ) substituted in the 90K superconductor lattice ($Y_{1-x}Ln_x^-Ba_2Cu_3O_{7-{\delta}}$). Powder X-ray diffraction analysis shows that both compounds, $PrBa_2Cu_3O_y$ and $Li_{0.1}PrBa_2Cu_3O_y$ are isostructural with the 90 K superconductor, ($YBa_2Cu_3O_{7-{\delta}}$), nevertheless both of them are non-metallic and also non-superconducting down to 10 K. Magnetic susceptibility ${\chi}$ vs. temperature data indicate that Curie contribution from the magnetic ions (Pr and Cu) is weakened on the one hand, but on the other hand temperature-independent part of susceptibility ${\chi}_o$ increases depending upon the rate of lithium intercalation in $PrBa_2Cu_3O_y$ lattice.