• Title/Summary/Keyword: magnetic separation

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Application of Solvent Extraction to the Treatment of Industrial Wastes

  • Shibata, Junji;Yamamoto, Hideki
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.259-263
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    • 2001
  • There are several steps such as slicing, lapping, chemical etching and mechanical polishing in the silicon wafer production process. The chemical etching step is necessary to remove damaged layer caused In the slicing and lapping steps. The typical etching liquor is the acid mixture comprising nitric acid, acetic acid and hydrofluoric acid. At present, the waste acid is treated by a neutralization method with a high alkali cost and balky solid residue. A solvent extraction method is applicable to separate and recover each acid. Acetic acid is first separated from the waste liquor using 2-ethlyhexyl alcohols as an extractant. Then, nitric acid is recovered using TBP(Tri-butyl phosphate) as an extractant. Finally hydrofluoric acid is separated with the TBP solvent extraction. The expected recovered acids in this process are 2㏖/l acetic acid, 6㏖/1 nitric acid and 6㏖/l hydrofluoric acid. The yields of this process are almost 100% for acetic acid and nitric acid. On the other hand, it is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. Some examples of the application of solvent extraction to the treatment of wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse solution, etching solution and pickling solution are introduced.

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A study on the contactless generator and recharge system for a bicyle (비접촉식 자전거 발전기 및 충전 시스템 개발에 관한 연구)

  • Park, Wang-Geun;Won, Si-Tae
    • Design & Manufacturing
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    • v.11 no.2
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    • pp.29-36
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    • 2017
  • In this study, the non-contact type bicycle generator system considering the recharge is developed to use the eco-friendly energy source when the bicycle is operating. The following three main factors are considered in this study. One of factors is that the intensity of the rotating magnet is in the range of 2,700~4,300 [Gause]. The next factor is that the separation distance of rotating magnet and bicycle rim is in the range of 1.5-3.0 mm. The last factor is that the pedaling speed is in the range of 55 RPM [Wheel speed 5.6Km]~150 RPM [Wheel speed 15.25Km] consirering with the 5 staged gear transmission. The obtained results are as followed. (1) The generator output voltage gradually increases from 3V to 10V with the pedaling speed increases, at the separation distance is less than 2.5 mm and the operating voltage of the LED lamp is generated at a pedaling speed of 60 RPM or more. (2) The output current of the generator increases from 20mA to 40mA with the pedaling speed increases, at a separation distance is less than 2.0 mm and the operating current of the LED lamp is generated at a pedaling speed of 60 RPM or more. (3) When the separation distance was 3.0 mm, the output voltage and current are significantly lower than those of the bicycle LED lamp is generated. (4) The charging time is expected to be 12.24 ~ 17.65 hours when the magnitude of the magnet is 3,400[Gauss] at a pedaling speed of 55 RPM or more. (5) As a result of this study, it is thought that the non-contact type bicycle generator system considering the recharge can replace the conventional friction power generation system.

Synthesis of SiC from the Wire Cutting Slurry of Silicon Wafer and Graphite Rod of Spent Zinc-Carbon Battery (폐 반도체 슬러리 및 폐 망간전지 흑연봉으로부터 탄화규소 합성)

  • Sohn Yong-Un;Chung In-Wha;Sohn Jeong-Soo;Kim Byoung-Gyu
    • Resources Recycling
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    • v.12 no.3
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    • pp.25-30
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    • 2003
  • The synthesis of SiC used for the parts of the gas turbine and the heat exchanger, was carried out. In this study, wire cutting slurry of silicon wafer and the graphite rod of spent zinc-carbon battery were applied to the starting materials for the synthesis. The powders of Si or Si+SiC were obtained from the waste material by filtration, gravity separation and magnetic separation. Graphite powder was produced by dismantling, grinding and gravity separation from spent zinc-carbon battery. The synthesis of SiC could be completed from the mixture powders of Si and C or Si+SiC and C at the condition of equivalent ratio of Si and C, atmosphere of Ar or vacuum, temperature of above 1$600^{\circ}C$ and 2 hours reactions. The purity of synthesized Si-C was above 99%.

The Variation of Packing Density According to Powder Size Distribution and Epoxy Resin in Soft Magnetic Composite (연자성 복합체에서 파우더 크기 분포와 Epoxy Resin에 따른 Packing Density 변화)

  • Lee, Chang Hyun;Oh, Sea Moon;Shin, Hyo Soon;Yeo, Dong Hun;Kim, Jin Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.12
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    • pp.782-787
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    • 2017
  • There is growing interest in power inductors in which metal soft magnetic powder and epoxy resin are combined. In this field, the process technology for increasing the packing density of magnetic particles in an injection molding process is very important. However, little research has been reported in this regard. In order to improve the packing density, we investigated and compared the sedimentation heights of pastes for three types of soft magnetic alloy powders as a function of the mixing ratios and the type of resin used. Experimental results showed that the packing density was the highest (71.74%) when the mixing ratio was 80 : 16 : 4 (Sendust : Fe-S : CIP) according to the particle size using an SE-4125 resin. In addition, the packing density was found to be inversely related to the layer separation distance. As a result, it was confirmed that the dispersion of solid particles in the paste was important for curing; however, the duration of the curing process can greatly affect the packing density of the final composite.

Research Status and Prospectives of Magnetic Nanoparticles in Bio-medical Applications (바이오-메디컬 자성나노입자 연구의 현황과 전망)

  • Min, J.H.;Song, A.Y.;Kim, Y.K.;Wu, J.H.
    • Journal of the Korean Magnetics Society
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    • v.19 no.1
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    • pp.28-34
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    • 2009
  • Magnetic nanoparticles are widely used for bio-medical applications such as MRI contrast agents, drug-delivery systems, cell separation and hyperthermia, thanks to their unique magnetic properties and physico-chemical characteristics. In the early stage, efforts were focused on synthesis of uniform nanoparticles of desired dimension to achieve targeted, stable functionalities. Recently, it has been of great interest in dispersion of such nanoparitcles in aqueous solution and to render the nanoparticles bio-compatible with biofunctionality on request for utilization in bio-medical fields. In this paper, we survey the research status and give prospective on future work of magnetic nanoparticles for biomedical applications.

Trajectory Simulation of ASR Particles in Induction Electrostatic Separation (유도형 정전선별에서 ASR 입자의 궤적모사)

  • Kim, Beom-uk;Park, Chul-hyun
    • Resources Recycling
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    • v.28 no.6
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    • pp.96-105
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    • 2019
  • Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.

Evaluation of Extremely Low Frequency Magnetic Fields emission Level from High Voltage Transmission Lines (고압 송전선로에서 극저주파 자기장 영향평가 적용에 관한 연구)

  • Jung, Joon Sig;Choi, Sung Ho;Jeon, Hyung Jin;Kim, Yoon Shin;Hong, Seung Cheol
    • Journal of Environmental Impact Assessment
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    • v.23 no.5
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    • pp.353-363
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    • 2014
  • The purpose of this study was to investigated the ELF-MF emission level of various environments such as 258 facilities near located to high voltage transmission lines and 120 high voltage transmission lines, 17 underground cable lines. In addition, ELF-MF reduction rate according to separation distance was calculated by using simulations. An appropriate separation distance showing below 4mG was at least 70m. In the case of the appropriate separation distance for 120 high voltage transmission lines, 154kV required 20m of separation distance and 345kV required 60m of separation distance. The simulation results showed that the appropriate separation distance showing below 4mG was 40m and 60m for overhead 154kV and 345kV respectively. To adjust the worst conditions considering the aspects of environmental impact assessment study and the electric power currents that will increase in the future, the appropriate minimum separation distance for HVTL is judged to be above 70m in this study. Thus, there is a need to establish the greenbelt or buffer zone within 70m so as to create an environment in which the receptors are not exposed and thereby eliminate the risk factors of ELF-MF against humans.

Removal of PVC from Mixed Plastic Waste by Combination of Air Classification and Centrifugal Process (풍력(風力) 및 습식비중(濕式比重) 선별(選別)에 의한 혼합(混合)폐플라스틱 종말품(終末品)으로부터 PVC 제거(除去)에 관한 연구(硏究))

  • Choi, Woo-Zin;Yoo, Jae-Myung
    • Resources Recycling
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    • v.16 no.5
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    • pp.71-76
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    • 2007
  • The mixed plastic waste generated from households after hand-picking and/or mechanical sorting processes amounts to 1,750,000 ton in 2006, and most of these waste are finally end up with landfill and/or incineration due to the lacks of separation technologies and economical reasons. The mixed plastic wastes can not be used as raw materials for chemical and/or thermal recycling processes because of their high content of PVC(upto 4.0 wt.%). In the present research, gravity separation system has been developed to remove PVC from the mixed plastic waste and to recover the PO-type plastics. This system mainly consists of air classification, magnetic separation, one-step crushing, feeding system at fixed rate and wet-type gravity separation system. The gravity system based on centrifugal separation has been developed at capacity of 0.5 ton/h and it consists of mixing, precleaning, separation, dewatering, recovery system and wastewater treatment system, etc. The main objective of this process is to achieve high separation efficiency of polyolefins with less than 0.3 wt.% PVC content and less than 10% moisture content in the final products. In addition, a crushing unit of with 8 rotor system is also developed to improve the crushing efficiency of soft-type plastics. The system with a capacity of 1.0 ton/h is developed and operational results are presented.

A Study on the Recovery of a Metalic Fe-particle from the Steelmaking E.A.F. Slag by the Magnetic Separation (전기로 제강 슬래그에서 자력선별에 의한 지금의 회수)

  • 현종영;김형석;신강호;조동성
    • Resources Recycling
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    • v.6 no.3
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    • pp.3-8
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    • 1997
  • The EA.F. sleelmaking slag (slag that follow) of a cnmvany 1 Co.. containzd a simple substance of a metal, wustlte (FeO), magnetite (Fe,O,), gehlenite (CaAl,SiO,), monlicellite (CaMgSiO,), dc. To recovere a metal (Fe grade . t95%) in the slag, it is desirable that the particles of a metal are isolated from thc slag and madc for a liberated subslance. Then, the liberaled melal is easlly recoveled by a magnetic separation. If thc rcclarnalcd slag, the sizc of which ranges under 40 nun, have a mulli-stage crushing, the most of a metal in thc slag is simply isolaled as a liberated subslance. If the mad, lhat is a liberated subslance and a sphere, is recovered by a magnetic field intensity. the minimum intensity, at which a metal is attracted, is approximately IOOG and did no1 dcpcnd on the particle size of a metad in the same particles. TIe recovered material. that contdined a iron (Fe) over 95% is a metal which is crushed slag by l00G in the multi-stage. If the magnetic field intcns~ty increase, the recovery mcrcasc, but the concentration grade decrease Bewusc thc concentration eams more and more impurities, iron oxide and the coml~ound of alkali earth element. 'll~ercforc If the rccla~nated slag have the multi-stage crushing, the metal is almostly recovered in the crushed slag by lO0G on each particles. If the slag, used as a rcclamatian lhat is a amount of 350,000 tan from I Co., was undcr the multistage crushing and then separaled by 100gauss, it is possible to recova a metal approximately 2.500 Ion, lhat is 0.73% of n ~eclamated slag. in 304.7 mm particles and to recover 4.200 tan in 0.3-1.7 mm particles , that is 1.2% nf a rcclamated slag, in a year. Therefore, ihe told recoverable meld is 6,700 ton, that is 19% of a reclmated slag, in a year, too.

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Upgrade of $TiO_2$ by Carbon Reduction of Ilmenite (Ilmenite의 炭素還元에 의한 $TiO_2$ 品位 向上 硏究)

  • Kim, Joon-Soo;Kim, Sung-Don;Park, Hyung-Kyu;Sohn, Hong-Yong
    • Resources Recycling
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    • v.13 no.5
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    • pp.17-22
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    • 2004
  • It has been carried our for establishing the methodology to upgrade $TiO_2$ by carbothermal reduction of iron oxide in ilmenite. Based on present experimental results, the possibility for substitution with rutile has been investigated. It could by proposed that the 2 wt.% $FeCl_3$ of sample and carbon of 2 equivalents are optimum conditions as a feeding materials. And also appropriate reducing temperature and reduction time were about $1100^{\circ}C$ and 30 minutes. The product obtained by the processes of carbon reduction and magnetic separation may be used the substitute mineral of rutile.