• 제목/요약/키워드: magnetic minerals

검색결과 91건 처리시간 0.025초

전해생성(電解生成)된 염소(鹽素)에 의한 폐인쇄회로기판(廢印刷會路基板)으로부터 동(銅)의 침출(浸出) (Leaching of Copper from Waste Printed Circuit Boards Using Electro-generated Chlorine in Hydrochloric Acid)

  • 김민석;이재천;정진기;김병수;김은영
    • 자원리싸이클링
    • /
    • 제14권5호
    • /
    • pp.45-53
    • /
    • 2005
  • 염산용액에서 전해생성 된 염소를 이용하여 폐프린터의 인쇄회로기판으로부터 동을 침출하는 연구를 수행하였다. 폐인쇄회로기판을 분쇄한 다음 입자크기가 $0.6{\sim}1.2mm$인 비자성 성분을 선별하여 침출실험을 행하였다. 비자성 분쇄물 중 금속성분의 평균함량은 45wt%이었으며, 동이 금속성분의 83.6wt% 이었다. 1 M 염산용액에서 전해생성된 염소에 의한 동의 침출반응은 전류밀도와 교반속도에 크게 영향을 받았다. 염산농도: 1 M, 전류밀도: $20mA/cm^2$, 침출온도: $50^{\circ}C$, 침출시간: 180분, 교반속도: 600rpm의 침출조건에서 동의 침출율은 98%로서 침출액에서 농도는 3.69g/l 해당하였다. 동의 침출반응에 대한 전해생성 된 염소의 이용율은 교반속도가 높고 인가전류밀도가 낮을 수록 높았다. 또한 침출반응 초기에는 알루미늄, 납, 주석 등의 기타금속 성분의 침출이 활발하고 동의 침출반응은 억제되었다.

Superconducting magnetic separation of ground steel slag powder for recovery of resources

  • Kwon, H.W.;Kim, J.J.;Ha, D.W.;Choi, J.H.;Kim, Young-Hun
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제19권1호
    • /
    • pp.22-25
    • /
    • 2017
  • Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.

포항이남 제3기분지암석의 자기 비등방성과 지구조적 응력장 (Magnetic Anisotropy and Tectonic Stress Field of Tertiary Rocks in Pohang-Ulsan area, Korea)

  • 김인수
    • 자원환경지질
    • /
    • 제23권1호
    • /
    • pp.59-71
    • /
    • 1990
  • Magnetic anisotropy of a total of 213 independently oriented Tertiary rock samples from Pohang-Ulsan area has been studied. The sampled strata comprise basalts, tuffs and black shale, and range in age from Eocene to Miocene. The previous palaeomagnetic studies indicate that their magnetic carrier minerals are titanomagnetites. Among 23 sampled sites, 11 sites were found to preserve magnetic load foliation parallel to the bedding plane caused by the Iithostatic load of the overlying strata. Other 4 sites showed magnetic lineation indicating the flow direction of lava and tuffs. The remaining 8 sites revealed the magnetic tectonic foliation nearly vertical to the bedding plane. This magnetic foliation is interpreted to be generated by tectonic compression which acted nearly horizontally during the solidification stage of the strata. The compression directions deduced from the tectonic foliation of the 8 sites can be grouped into internally very consistent two group: a N-S trending one and the other WNW-ESE trending one. It is interpreted that the former N-S compression was associated with the N-S spreading of the East Sea(Sea of Japan) and the dextral strike-slip movement of the Yangsan-Ulsan fault system. The latter WNW-ESE compression is interpreted to represent the folding and reverse faulting activity in the Korean and Tsushima straits during middle/late Miocene times.

  • PDF

전남(全南) 보성강(寶城江) 유역(流域)에 분포(分布)하는 중사광상(重砂鑛床)의 지질(地質) 및 선광(選鑛)에 관(關)한 연구(硏究) (A Study on the Geology and Ore Dressing of Heavy Mineral Placer Deposits along the Boseong River, Jeonranamdo)

  • 최영천
    • 자원환경지질
    • /
    • 제15권3호
    • /
    • pp.113-122
    • /
    • 1982
  • The surveyed Boseong river, flows from south to north crossing Boseong gun Mirukg myon, Nodong myon, Yuleo myon, Bocgnae myon, Mundeog myon, and Seungju gun Nam myon, Jeonranam do. The geology of the surveyed area consists of age-unknown composite gneiss and schist, crystaline chlorite gneiss, porphyroblastic gneiss and granite gneiss, and metasediments of Myon Bong formation and Seologri formation. These metamorphic rocks are intruded by cretaceous biotite granite, granodiorite, and quartz diorite. The heavy sands occur in Quarternary alluvium and colluvium. The composition of the river bed is sand 60%, gravel 30%, and clay 10%. The gravel content of the river bed decreases as the increases. The average depth of auger boring is 0.87 m. The average heavy mineral composition of the heavy sand is monazite 6.83%, zircon 4.88%, ilmenite 11.36%, magnetite 8.36% and garnet 4.84%. The best heavy minerals separation procedure would be primary treatment of the sand by humphrey spiral and table, and retreatment of the table concentrate by magnetic separator. The minimum economically feasible capacity of gravity and magnetic separation plant would be 500 ton/hr when only the heavy minerals are recovered but it may be reduced to 100 ton/hr. capacity, if gravels and sands are added to the valuable products.

  • PDF

기계적합금법으로 제조한 NdFeB계 분말의 자기적 성질 (Magnetic Properties of NdFeB Powders Prepared by Mechanical Alloying)

  • 김택수;황연;이효숙
    • 한국자기학회지
    • /
    • 제8권4호
    • /
    • pp.210-215
    • /
    • 1998
  • Ball Mill을 이요하여 Ar 분위기에서 기계적합금법으로 Nd15Fe77B8과 Nd16Fe76B8 분말을 제조하고, 제조된 분말을 연속 진공열처리 시킨 후 열처리온도에 따른 상변화 및 자기적 성질을 조사하엿다. 450시간 볼밀도처리한 Nd15Fe77B8과 Nd16Fe76B8 합금 분말에서 Nd와 B의 피크는 보이지 않고 전체적으로 $\alpha$-Fe 결정상만 존재하고 있었으며, 이를 $700^{\circ}C$에서 30분간 열처리를 시키면 고상반응에 의하여 Nd2Fe14B와 소량의 NdB6이 흔재된 상을 얻을 수 있었다. $700^{\circ}C$로 열처리 한 Nd16Fe76B8 합금 분말은 iHc9.9kOe, Bs, 12.9 KG, (BH)max 10.1 MGOe의 자기적 성질을 나타내었다.

  • PDF

Ilmenite의 炭素還元에 의한 $TiO_2$ 品位 向上 硏究 (Upgrade of $TiO_2$ by Carbon Reduction of Ilmenite)

  • 김준수;김성돈;박형규
    • 자원리싸이클링
    • /
    • 제13권5호
    • /
    • pp.17-22
    • /
    • 2004
  • 본 연구는 탄소 환원반응을 이용하여 ilmenite 중 $TiO_2$의 품위 향상을 목적으로 ilmenite 중에 존재하는 철산화물의 탄소환원에 가장 효과적인 첨가물과 최적조건을 검토하였다. Ilmenite 중 철산화물의 환원에 가장 적절한 환원제의 종류 및 첨가량은 $FeCl_3$로서 ilmenite 시료무게의 2 wt.%이었고, 또한 최적의 탄소환원제 양은 당량비로 2배였다. 그리고 적절한 환원온도 및 시간은 $1100^{\circ}C$ 부근으로서 대부분 철산화물의 환원반응이 종료되는 30분 정도로 조사되었다. 이와 같은 조건하에서 얻어진 환원반응 생성물은 자력선별 공정을 거치면 rutile의 대체 자원으로 사용이 가능함을 확인하였다.

광물성 한약으로 이용되는 양기석, 연옥,음기석의 분광학적 및 자기적 특성 (Spectmscopic and Magnetic Properties of Yanggiseok, Yeonok and Eumgiseok used as Mineral Medicine)

  • 김선옥;박맹언;정율필
    • 자원환경지질
    • /
    • 제35권4호
    • /
    • pp.317-323
    • /
    • 2002
  • 양기와 음기를 보하는 약재로 알려진 양기석과 음기석 및 연옥에 대한 의료적 활용을 파악하고, 광물학적 특성, 분광학적 및 자기적 특성을 규명하기 위하여 X선 형광분석, X-선 회절분석, 주사전자현미경, 적외선 분광분석, 핵자기 공명분석 및 감응자기력을 실시하였다. 광물성 한약으로 사용되는 양기석은 양기석으로 확인되었으뗘, 연옥은 투각섬석으로 구성되었다. 또한, 음기석은 주로 질석으로 구성되며, 소량의 카올리나이트와 할로이사이트를 함유하였다. 사슬형 규산염 중 각섬석군에 속하는 이들 연옥과 양기석은 유사한 범위의 분광학적 특성을 가지며, 연옥은 4$0^{\circ}C$에서 방사에너지가 큰 반면, 양기석은 15$0^{\circ}C$에서 방사에너지가 크다 음기석은 각섬석군의 광물보다 4$0^{\circ}C$와 15$0^{\circ}C$에서 모두 낮은 방사에너지를 나타내었다. 광물성 한약을 증류수에 20일간 침적한 후에 측정한 NMR분석에서의 선폭은 음기석, 양기석, 연옥의 순으로 감소되나, 80일이 경과한 후의 결과는 음기석, 연옥, 양기석 순으로 감소하였다. 양기석과 음기석은 가열 온도가 높아짐에 따라 감응 자기력 값이 대체적으로 증가하고, 연옥은 감소하는 경향을 나타내었다. 광물별로는 상온과 가열시 모두 음기석, 양기석, 연옥의 순으로 감소하였다.

페그마타이트에서 산출하는 전기석의 운모화작용: 고분해능 투과전자현미경(HRTEM) 연구 (Sericitization of Tourmaline in a Pegmatite: a HRTEM Study)

  • 안중호;이정후
    • 한국광물학회지
    • /
    • 제9권1호
    • /
    • pp.7-16
    • /
    • 1996
  • Partially sericitized tourmaline from a pegmatite, Black Hills, South Dakota, U.S.A., was investigated using high-resolution transmission electron microscopy (HRTEM). Muscovite occurs as the only alteration product of tourmaline, and it is developed extensively as narrow veinlets along the {110} and {100} cleavage directions of tourmaline, indicating that a cleavage-controlled alteration mechanism was dominant. Muscovite was characterized mainly as two-layer polytypes with minor stacking disorder, but tourmaline is almost free of structural defects. HRTEM images of tourmaline-muscovite interfaces revealed that the interfaces between two minerals are composed of well-defined {110} and {100} boundaries of tourmaline. The (001) of muscovite is in general parallel to the c-axis of tourmaline, but tourmaline and replacing muscovite do not show specific crystallographic orientation relationship; muscovite consists of numerous 100-1000$\AA$ thick subparallel packets, and the angles between the (001) of muscovite and (110) of tourmaline is highly variable. Al/Si ratios of both minerals suggest that tourmaline to muscovite alteration by late magnetic fluids has been facilitated by their similar Al/Si ratio in the incipient alteration stage, in that the hydration reaction with preservation of Al and Si would require only addition of K+ and H2O. Aluminous minerals other than muscovite were not characterized as the alteration products of tourmaline, indicating that tourmaline reacted directly to muscovite; the tourmaline alteration apparently occurred by the presence of residual fluids in which K+ is available and silica was not undersaturated.

  • PDF

옥천대 북동부에 분포하는 하부 고생대층에 대한 고지자기 연구 (Paleomagnetic Study of the Lower Ordovician Formations in the North Eastern Okcheon Zone)

  • 민경덕;이윤수;황석연
    • 자원환경지질
    • /
    • 제26권3호
    • /
    • pp.395-401
    • /
    • 1993
  • Lower Ordovician rock samples were collected from 23 sites located at the Okcheon non-metamorphic zone, near Taeback and Yeongweol areas, southern part of the Korean Peninsula. A characteristic magnetic component was obtained from four sites. This stable direction ($Dm=-19.4^{\circ}$, $Im=24.1^{\circ}$) which is carried by hematite of very high temperature $679^{\circ}C$), successfully pass both of reversal test and paleopole reliability test, and is regarded as a primary direction. The remagnetized components can be divided into three on the basis of their characteristic directions and magnetic minerals. The first which is carried by hematite, magnetite and pyrrhotite, is widely found at the whole sites. It shows syn- or post-tectonic remagnetization according to strongly negative fold test and distribution between Mesozoic and present field directions. The second, in situ, is distinguishable from the present field direction. After bedding correction, it is identical to Late Triassic to Early Jurassic direction. Its magnetic carrier is considered to be a single component hematite, which may be acquired by pre-tectonic CRM in the Okcheon orogenic zone. The third, which is carried by magnetite and hematite, is characterized by stable reversed direction. These minerals may be acquired by the thermal or chemical process in unknown period. Paleopole position is $169.2^{\circ}E$ in longitude and $59.9^{\circ}S$ in latitude, which indicates that the study area was located at $12.6^{\circ}S$ in paleo-latitude and belonged to northern end of the Gondwana in Early Ordovician.

  • PDF