• Title/Summary/Keyword: magnetic binder

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Effects of Coupling Agents on the Rheological and Magnetic Properties of Plastic Ferrite Magnets (커플링제가 플라스틱 페라이트 자석의 레올로지와 자기특성에 미치는 영향)

  • 이석희;최준환;문탁진;정원용
    • Journal of the Korean Magnetics Society
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    • v.8 no.5
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    • pp.275-281
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    • 1998
  • Effects of coupling agents on the rheological and magnetic properties of plastic ferrite magnets were investigated. Magnetic powder used was Sr-ferrite, and binder used was polypropylene (PP), and coupling agents used were ${\gamma}$-methacryloxypropyl trimethoxy silane (A174) and isopropyl triisostearoyl titanate (TTS). It was found that the addition of coupling agents to the PP/ferrite system reduced the melt viscosity and increased the magnetic properties considerably, and the treatment with TTS showed greater effect than A174 did. By comparison with that of the untreated one, the apparent viscosities of the mixtures treated with A174 and TTS decreased 23 % and 50%, respectively, at the shear rate of $1280\; sec^{-1}$ . Untreated plastic magnets showed remanent flux density $(B_r)$ of 1.89 kG and maximum energy energy product $(BH_{max})$ of 0.84 MGOe, and A174 treated magnets showed of Br 2.25 Kg and $BH_{max}$ of 1.23 MGOe. TTS treated magnets showed $B_r$ of 2.35 kG and $BH_{max}$ of 1.33 MGOe.

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Effect of Residual Impurity on Magnetic Properties of the Permalloy Soft Magnet by Powder Injection Molding (분말사출성형으로 제조된 퍼말로이 연자성체에서 잔류 불순물이 자기특성에 미치는 영향)

  • 정원용;최준환;정우상
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.291-296
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    • 2000
  • The manufacturing method of permalloy soft magnet with the Ni contents of 46.6 and 47.2 wt% was investigated by powder injection molding technology. The magnetic properties of permalloy were greatly affected on the residual carbon and oxygen content of the sintered magnet. Solvent extraction and thermal debinding process to minimize the residual carbon content in sintered magnet were developed by controlling the debinding atmosphere. The residual carbon content depends on the debinding condition of the binder system for powder injection molding and the residual oxygen content on the sintering atmosphere. The sintered magnet produced by powder injection molding process had a 50 ppm. residual carbon, 150 ppm. residual oxygen. The coercivity and maximum relative permeability of permalloy soft magnet were 0.46 Oe and 14,600 respectively.

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Characteristics of high-performance concrete with nano size cement (나노 시멘트를 이용한 고강도 콘크리트의 특성)

  • Jo, Byung-Wan;Park, Jong-Bin;Choi, Hae-Yun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.13-16
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    • 2005
  • Nanoscale materials are of great interest due to their unique optical, electrical and magnetic properties. Due to the recent amazing achievements in nano technology, new materials were developed. But these nano technology is not apply to the construction part in spite of exellent properties of nano size material. The purpose of this study is to apply to nano technology into building materials. To develop the high performance concrete, nano cement particles is prepared by mechanical method. In the results of this study, the nano silica powder increase effect according to increase of the mixing amount, appeared that compressive strength increased but is limit in increment. For the production of high-strength concrete, nano silica powder was suitable the binder ratio from 20$\%$. And, the compressive strength of concrete are especially dependent on the curing temperature.

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HVOF spray coating of WC-metal powder for the improvement of friction, wear and corrosion resistance of magnetic bearing shaft material of turbo blower (터보불로워 용 회전체 주축 소재의 마찰, 마모 및 부식 저항 향상을 위한 WC-metal 분말의 초고속화염용사코팅)

  • Joo, Y.K.;Yoon, J.H.;Cho, T.Y.;Chun, H.G.
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.7-11
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    • 2013
  • High velocity oxy-fuel (HVOF) spray coating of WC-metal powder (powder) was carried out to improve the resistances of friction, wear and corrosion of magnetic bearing shaft material Inconel718 (In718) of turbo blower. A micron sized WC-metal powder (86.5% WC, 9.5% Co 4% Cr) was coated onto In718 surface using HVOF thermal spraying. During the spraying, the binder metals and alloy such as Co, Cr and Co-Cr alloy were molten and a small portion of WC particles were partially decomposed to $W_2C$ and free carbon at above its decomposition temperature of $1250^{\circ}C$. The free carbon and excessively sprayed oxygen formed carbon oxide gases, resulting a porous coating of porosity of $2.2{\pm}0.3%$. The surface hardness of substrate increased approximately three times from 400 Hv of In718 to $1260{\pm}30Hv$ of the coating The friction coefficients of the coating were approximately $0.33{\pm}0.03$ at $25^{\circ}C$ and $0.26{\pm}0.03$ at $450^{\circ}C$. These values were smaller than those of In718 substrate at both temperatures due to the lubrication from the free carbon and the cobalt oxide debris. The corrosion resistance of the coating was higher than that of In718 both in salt water of 3.5% NaCl and acid of 1 M HCl solutions, on the contrary, it was lower in base solution of 1 M NaOH. According to this study, the HVOF WC-metal powder coating is recommended for the durability improvement of magnetic bearing shaft of turbo blower.

A Study on the Resource Development by Heat Dissolution in Electric Arc Furnace of Clinker generated in the Recycling Process of Electric Arc Furnace Dust (전기로 제강분진의 재활용과정에서 발생된 Clinker의 전기로에서의 가열용해에 의한 자원화에 관한 연구)

  • Jae-hong Yoon;Chi-hyun Yoon;Akio Honjo
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.1
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    • pp.22-32
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    • 2023
  • In general, when scrap is dissolved in an electric arc furnace, the amount of electric furnace steel dust (EAFD) generated is about 1.5% of the scrap charge amount, and the electric furnace steel dust collected by the bag filter is charged into the Rotary Kiln or Rotary Hearth Furnace (RHF), and the zinc component is recovered as crude zinc oxide, at which time a clinker of Fe-Base is generated. In this research, first, for the efficient resource conversion of electric furnace steel dust, a reduction and roasting experiment was conducted and the reaction kinetics was examined. As a result of the experiment, it was observed that the reduction and roasting reaction was actively conducted in the range of 1100~1150℃, and melting occurred in the range of 1250℃. In the past, this clinker was widely used as a roadbed material for road construction and an Fe-Source for cement production, but in recent years, it has been mainly reclaimed due to strengthening environmental standards. However, landfill treatment is by no means a desirable treatment method due to environmental pollution caused by leachate, expensive landfill costs, and waste of Fe resources. Therefore, in order to more actively recycle the Fe component in the clinker, first of all the clinker was pulverized into an optimal particle size, and anthracite and binder (starch) were added to the magnetic material obtained by specific gravity and magnetic separation for briquet. As a experimental results, it was possible to efficiently separate clinker as Fe component and other slag component by specific gravity and magnetic force. As a results of loading and dissolving the manufactured briquet clinker in an electric arc furnace, it was observed that the unit of power and production yield were clearly improved and the carbon addition effect in molten metal was also somewhat.

Synthesis of DyF3 paste and Magnetic Properties of GBDPed Nd-Fe-B Magnets (DyF3 paste 제조 및 이를 이용한 Nd-Fe-B 입계확산 자석의 특성 연구)

  • Jeon, Kwang-Won;Cha, Hee-Ryoung;Lee, Jung-Goo
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.437-441
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    • 2016
  • Recently, the grain boundary diffusion process (GBDP), involving heavy rare-earth elements such as Dy and Tb, has been widely used to enhance the coercivity of Nd-Fe-B permanent magnets. For example, a Dy compound is coated onto the surface of Nd-Fe-B sintered magnets, and then the magnets are heat treated. Subsequently, Dy diffuses into the grain boundaries of Nd-Fe-B magnets, forming Dy-Fe-B or Nd-Dy-Fe-B. The dip-coating process is also used widely instead of the GBDP. However, it is quite hard to control the thickness uniformity using dip coating. In this study, first, a $DyF_3$ paste is fabricated using $DyF_3$ powder. Subsequently, the fabricated $DyF_3$ paste is homogeneously coated onto the surface of a Nd-Fe-B sintered magnet. The magnet is then subjected to GBDP to enhance its coercivity. The weight ratio of binder and $DyF_3$ powder is controlled, and we find that the coercivity enhances with decreasing binder content. In addition, the maximum coercivity is obtained with the paste containing 70 wt% of $DyF_3$ powder.

Electromagnetic Wave Absorption Properties of Fe73Si16B7Nb3Cu1-Based Nanocrystalline Soft Magnetic Powder Composite Mixed with Charcoal Powder (나노결정 Fe73Si16B7Nb3Cu1 연자성분말과 숯분말 혼합 복합성형체의 전자파흡수 특성)

  • Kim, Sun-I;Kim, Mi-Rae;Sohn, Keun-Yong;Park, Won-Wook
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.291-295
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    • 2009
  • The electromagnetic wave absorption sheets were fabricated by mixing of $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline soft magnetic powder, charcoal powder and polymer based binder. The complex permittivity, complex permeability, and scattering parameter have been measured using a network analyzer in the frequency range of 10 MHz$\sim$10 GHz. The results showed that complex permittivity of sheets was largely dependent on the frequency and the amount of charcoal powder : The permittivity was improved up to 100 MHz, however the value was decreased above 1 GHz. The power loss of electromagnetic wave absorption data showed almost the same tendency as the results of complex permittivity. However, the complex permeability was not largely affected by the frequency, and the values were decreased with the addition of charcoal powder. Based on the results, it can be summarized that the addition of charcoal powder was very effective to improve the EM wave absorption in the frequency range of 10 MHz$\sim$1 GHz.

Immobilization of oxidative enzymes onto Cu-activated zeolite to catalyze 4-chlorophenol decomposition

  • Zol, Muhamad Najmi Bin;Shuhaimi, Muhammad Firdaus Bin;Yu, Jimin;Lim, Yejee;Choe, Jae Wan;Bae, Sungjun;Kim, Han S.
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.195-200
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    • 2020
  • In this study, a biocatalyst composite was prepared by immobilizing oxidoreductases onto Cu-activated zeolite to facilitate biochemical decomposition of 4-chlorophenol (4-CP). 4-CP monooxygenase (CphC-I) was cloned from a 4-CP degrading bacterium, Pseudarthrobacter chlorophenolicus A6, and then overexpressed and purified. Type X zeolite was synthesized from non-magnetic coal fly ash using acetic acid treatment, and its surfaces were coated with copper ions via impregnation (Cu-zeolite). Then, the recombinant oxidative and reductive enzymes were immobilized onto Cu-zeolite. The enzymes were effectively immobilized onto the Cu-zeolite (79% of immobilization yield). The retained catalytic activity of CphC-I after immobilization was 0.3423 U/g-Cu-zeolite, which was 63.3% of the value of free enzymes. The results of this study suggest that copper can be used as an effective enzyme immobilization binder because it provides favorable metalhistidine binding between the enzyme and Cu-zeolite.

The Characterizations of Tape Casting for Low Temperature Sintered Microwave Ceramics Composite (저온소성 마이크로파 유전체 세라믹스 복합체의 Tape Casting특성)

  • Lee, Woo-Suk;Kim, Chang-Hwan;Ha, Mun-Su;Jeong, Soon-Jong;Song, Jae-Sung;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.42 no.2 s.273
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    • pp.132-139
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    • 2005
  • Sintering behavior of $BaO-Nd_{2}O_3-TiO_2$ with a Pb-based glassceramics frit were investigated in order to understand an effect of glassceramics as a low temperature sintering agent on dielectric ceramics. A green sheet form was fabricated through tape casting method with the glassceramic fut added $BaO-Nd_{2}O_3-TiO_2$. The dispersion properties, rheological properties and final density of dielectric composit slurry as a function of amount and composition of organic additives was examined. The dispersants' addition was effective in controlling dispersion of the ceramics in solution. The addition of excessive dispersant showed adverse effect on dispersion. The prepared slurries, containing ceramic : powders, glass-ceramics and various kinds of organic viechles, exhibited typical shear thinning behavior. The best properties of tape casting appeared powder to solvent ratio 65 : 35 and amount of the binder 6 wt$\%$ and plasticizer 3 wt$\%$. The viscosity of the slurry was 677 cps and green/sintered density in the tape was $3.3 g/cm^3,\;5.56 g/cm^3$ respectively.

Control of Automatic Pipe Cutting Robot with Magnet Binder Using Learning Controller (반복학습제어기를 이용한 자석식 자동 파이프 절단 로봇의 제어)

  • Lee Sung-Whan;Kim Gook-Hwan;Rhim Sung-Soo;Lee Soon-Geul
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.541-546
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    • 2005
  • Tracking control of an automatic pipe cutting robot (APCROMB) is studied. Using magnetic force APCROMB, which is designed and developed in Kyung Hee University, binds itself to the pipe and executes unmanned cutting process. The gravity effect on the movement of APCROMB varies as it rotates around the cylindrical pipe laid in the gravitational field. To maintain a constant velocity and consistent cutting performance against the varying gravitational effect, the authors adopt a multi-rate repetitive learning controller (MRLC), which learns the required effort to cancel the repetitive tracking errors caused by nonlinear effect. In addition to the varying gravity effect other types of nonlinear disturbances including backlash in the driving system and the slip between the wheels of APCROMB and the pipe also cause degradation in the cutting process. In order to identify those nonlinear disturbances the position estimation based on the encoder attached at the motor is not good enough. To identify the absolute angular position of APCROMB the authors propose the angular position estimation based on the signals from a MEMS-type two-axis accelerometer mounted on APCROMB. The tracking performances of APCROMB with a MRLC using the encoder-based position estimation is experimentally measured and results are shown. Also the difference between the encoder-based angular displacement measurement and the accelerometerbased angular displacement measurement is included.

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