• Title/Summary/Keyword: magnesium oxide

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The effect of sodium aluminate concentration of oxide layer coated at AZ31 magnesium alloy by plasma electrolytic oxidation (AZ31 마그네슘 합금의 PEO 처리시 Sodium Aluminate 전해질이 산화막 특성에 미치는 영향)

  • Lee, Jong-Seok;Baek, Hong-Gu;Kim, Seong-Wan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.311-312
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    • 2012
  • PEO(Plasma Electrolytic Oxidation) 방법으로 인한 마그네슘 합금의 산화막 코팅시 Sodium Aluminate의 역할을 알아보았다. 전해액 내에 Sodium Aluminate 의 농도가 증가할수록 Plasma arc 발생에 필요한 전압의 상승이 빨라졌으며 그 산화막이 치밀해짐을 알 수 있었다. 또한 치밀한 산화막의 기공률은 분석하여 이를 내식성 결과와 비교함으로써 산화막의 기공률이 내식성에 미치는 영향을 고찰해보았다.

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Effect of Various Supports on the Physico-chemical Properties of V-Sb Oxides in the Oxidative Dehydrogenation of Isobutane

  • Shamilov, N.T.;Vislovskiy, V.P.
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.812-818
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    • 2011
  • [ $V_{0.9}Sb_{0.1}O_x$ ]systems, bulk and deposited on different supports (five types of ${\gamma}$-aluminas, ${\alpha}$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

The Effect of Small Additions of Zr, Cr, Mg, Al, and Si on the Oxidation of 6:4 Brass

  • 이동복;문재진
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.327-327
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    • 1999
  • The oxidation behavior of 60%Cu-40%Zn brass haying small amounts of Zr, Cr, Mg, Al, and Si was studied between 873 and 1043 K in air. The alloying element of Mg was harmful, while other alloying elements were beneficial to oxidation resistance. Particularly, the simultaneous addition of Al and Si decreased the oxidation rate drastically. During oxidation, Zr formed ZrO₂, Cr formed CuCr₂O₄, Mg formed MgO, Al formed A1₂CuO₄, and Si formed amorphous SiO₂. These oxides were incorporated in the oxide scale composed predominantly of ZnO. The oxide scales formed on all the tested alloyswere prone to cracking, wrinkling, and spallation.

Electrical Properties of Mg Doped ZnSnO TFTs Fabricated by Solution-process (용액공정을 이용한 ZnSnO 산화물 반도체 박막 트랜지스터에서 Mg 첨가에 따른 영향)

  • Choi, Jun-Young;Park, Ki-Ho;Kim, Sang-Sig;Lee, Sang-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.9
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    • pp.697-700
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    • 2011
  • Thin-film transistors(TFTs) with magnesium zinc tin oxide(MZTO) channel layer are fabricated by solution-process. The threshold voltage (Vth) shifted toward positive directly with increasing Mg contents in MZTO system. Because the Mg has a lower standard electrode potential (SEP) than Sn, Zn, thus degenerate the oxygen vacancy ($V_O$). As a result, the Mg act as carrier suppressor and oxygen binder in the MZTO as well as a Vth controller.

A Study on the Fundamental Mechanical Properties of Hydrophobic Cementeous Mortar using Silane Admixtures (실란계 혼화제를 활용한 소수성 시멘트 모르타르의 기초물성 연구)

  • Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.79-86
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    • 2018
  • In this study, emulsion type hydrophobic admixture was prepared by mixing polyvinyl alcohol surfactant, polymethyl hydro-siloxane and meta kaolin, and the compressive strength and mechanical properties such as permeability and contact angle test of the mortar were evaluated. The developed hydrophobic admixture showed no decrease in strength and the mortar specimen with magnesium oxide developed the early strength. In the case of permeability, total seepage was significantly decreased when the hydrophobic admixture was directly mixed with the mortar, but the effect of meta kaolin contained in hydrophobic admixture was not significant. The surface of specimens coated with hydrophobic admixture shows that the contact angle on the surface was highly increased compared with reference mortar specimen. Further researches to obtain the optimum mix proportion of the PVA fiber, nano-silica and meta kaolin for producing the super-hydrophobic surface are required.

A Study on the MgO Protective Layer Deposited by Oxygen-Neutral-Beam-Assisted Deposition in AC PDP (산소 중성빔으로 보조증착된 MgO 보호막을 갖는 AC PDP의 특성에 관한 연구)

  • Li, Zhao-Hui;Kwon, Sang-Jik
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.96-101
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    • 2008
  • The magnesium oxide (MgO) protective layer plays an important role in plasma display panels (PDPs). Our previous work demonstrated that the properties of MgO thin film could be improved, which were deposited by Ion-Beam-Assisted Deposition (IBAD). However arc discharge always occurs during the IBAD process. To avoid this problem, Oxygen-Neutral-Beam-Assisted Deposition (NBAD) is used to deposit MgO thin films in this paper. The energy of the oxygen neutral beam was used as the parameter to control the deposition. The experimental results showed that the oxygen neutral beam energy was effective in determining in structural and discharge characteristics. The lowest firing inception voltage, the highest brightness and the highest luminous efficiency were obtained when the MgO thin film was deposited with an oxygen neutral beam energy of 300eV. The surface morphology of MgO thin film was also analyzed using AFM (Atomic Force Microscopy) and SEM (Scanning Electron Microscopy).

The Strength and Drying Shrinkage Properties of Alkali-activated Slag using Hard-burned MgO (MgO를 혼합한 알칼리 활성화 슬래그의 강도와 건조수축 특성)

  • Kim, Tae-Wan;Jun, Yubin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.3
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    • pp.39-47
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    • 2015
  • In this study, the properties of strength and drying shrinkage of alkali-activated slag cement (AASC) with magnesium oxide (MgO) contents between 0 and 16 wt% were investigated. The ground granulated furnace blast slag (GGBFS) was activated by potassium hydroxide (KOH) and dosage of activator was 2M and 4M. The MgO was replaced with 2% to 16% of GGBFS by weight. The water-binder ratio (w/b) was 0.5. In the result, the higher MgO content leads to a slightly higher degree of reaction and thus to a higher compressive strength at all ages. The compressive strength and ultra sonic velocity (UPV) increased with increases MgO contents. The drying shrinkage of AASC was decreased as the contents of MgO increases. The results from SEM confirmed that there were densified reaction product of higher MgO content specimens.

X-Ray Photoelectron Spectroscopy Studies of Pd Supported MgO/Mg (X-선 광전자분광법을 이용한 MgO/Mg 표면에 증착된 Pd의 분석)

  • Tai, Wei-Sheng;Seo, Hyun-Ook;Kim, Kwang-Dae;Kim, Young-Dok
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.281-287
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    • 2009
  • Pd was deposited on magnesium-oxide-covered magnesium ribon substrate by metal thermal evaporation method in high vacuum. The electronic and chemical properties of Pd samples with different coverages were studied using in-situ X-ray Photoelctron Spectroscopy (XPS) and Field Emission Scanning Electron Microscopy (SEM). For relatively lower amounts of Pd deposited(< 1nm), separate Pd particles could be observed, whereas at higher Pd coverages, Pd thin films caused by agglomeration of Pd nanoparticles was found. The metal support interaction with Pd-support was observed. The Pd atoms on the metal oxide/metal interface were partially negative charged by charge transfer.

A study on corrosion resistance and surface properties of AZ31 alloy according to Ca-GP addition during PEO treatment (PEO 처리시 Ca-GP첨가에 따른 AZ31합금의 내식성 및 표면특성에 관한 연구)

  • Lee, Jun-Su;Park, Je-Shin;Park, Il-Song
    • Journal of the Korean institute of surface engineering
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    • v.54 no.5
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    • pp.238-247
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    • 2021
  • PEO (plasma electrolytic oxidation) was applied to modify the surface of AZ31 magnesium alloy in this study. The mixed solution of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) was used as the electrolyte, and 0 - 0.05 g/L of Ca-GP (Glycerol Phosphate Calcium salt) was added in the electrolyte as an additive. PEO treatment was conducted at a current density of 30mA/cm2 for 5 minutes using a DC power supply. The surface properties were identified by SEM, XRD and surface roughness analyses, and the corrosion resistance was evaluated by potentiodynamic polarization and immersion tests. In addition, the biocompatibility was evaluated by immersion test in SBF solution. As the concentration of Ca-GP was increased, the surface morphology was denser and more uniform, and the amount of Ca and the thickness of oxide layer increased. Only Mg peak was observed in XRD analysis due to very thin oxide layer. The corrosion resistance of PEO-treated samples increased with the concentration of Ca-GP in comparision with the untreated sample. In particular, the highest corrosion resistance was identified at the group of 0.04g Ca-GP through potentiodynamic polarization and immersion tests in saline solution (0.9 wt.%NaCl). During the immersion in saline solution, pH rapidly increased at the beginning of immersion period due to rapid corrosion, and then increase rate of pH decreased. However, the pH value in the SBF temporarily increased from 7.4 to 8.5 during the day, then decreased due to the inhibition of corrosion with HA(hydroxyapatite) formation.

Performance Analysis of Friction Pendulum System using PVDF/MgO Friction Material (PVDF/MgO 마찰재를 이용한 마찰면진장치의 성능 분석)

  • Kim, Sung-Jo;Kim, Ji-Su;Han, Tong-Seok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.213-219
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    • 2021
  • Polytetrafluoroethylene (PTFE) is a commercialized friction material in friction pendulum systems used for earthquake hazard mitigation in structures, and it has excellent chemical resistance and frictional performance. However, PTFE has a relatively low wear resistance for the friction pendulum systems in service. As an alternative to PTFE, a cost-effective frictional material, polyvinylidene fluoride (PVDF) strengthened by magnesium oxide (MgO), with enhanced wear resistance performance is proposed in this study. The frictional performance of the developed PVDF/MgO was evaluated through experiments and compared with that of PTFE. Accordingly, a friction pendulum system was designed using the measured friction coefficient. The performance of this friction pendulum system was evaluated via nonlinear time history analyses of bridges. Subsequently, the plausibility of using PVDF/MgO as an alternative to PTFE as a friction material for friction pendulum systems was discussed.