• Title/Summary/Keyword: magnesia-phosphate composite

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Early-Age Compressive Strength of Magnesia-Phosphate Composite with Phosphate Type (인산염 종류에 따른 마그네시아-인산염 복합체의 초기 압축강도 특성)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.185-186
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    • 2016
  • Four mortar mixes tested to evaluate the early-age compressive strength of magnesia-phosphate composite with phosphate type. Monopotassium phosphate, dipotassium phosphate, ammonium dihydrogen phosphate and diammonium phosphate used as phosphate. Test results show that the compressive strength of mortar used monopotassium phosphate as phosphate was highest, while compressive strength of mortars used dipotassium phosphate and diammonium phosphate as phosphate were not developed.

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The Quality Properties According to the Ratio of Magnesia and Potassium Phosphate of Magnesia Composites for Living Concrete Panel (리빙 콘크리트 패널용 마그네시아 복합체의 마그네시아 및 인산칼륨 비율에 따른 기초 품질 특성)

  • Choi, Yun-Wang;Nam, Eun-Joon;Kim, Cheol-Gyu;Yang, Neung-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.617-624
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    • 2021
  • In this study, the quality properties according to the ratio of magnesia and potassium phosphate of the magnesia composite were evaluated to control the quality of the parent material in terms of materials when designing living concrete panels. The quality properties are 7 levels (30, 35, 40, 45, 50, 55 and 60%) for W/B, 4 levels for P:M (1:0.5, 1:1.0, 1:2.0 and 1:3.0 vol. %) was prepared and evaluated. As a result of evaluating the flow of the magnesia complex, as W/B increased, the flow showed a tendency to increase, and the flow showed a tendency to decrease as the P:M increased. As a result of the evaluation of the compressive strength of the magnesia composite, the strength showed a tendency to decrease as P:M increased. In addition, it was confirmed that an optimal P:M ratio exists.

Effect of Phosphate Types on the Strength and pH of Magnesia-Phosphate Composites (마그네시아 인산염 복합체의 강도 및 pH에 대한 인산염 종류의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.135-140
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    • 2017
  • As an elementary investigation to develop vegetation concrete with a relatively low pH value, magnesia-phosphate composites (MPC) were examined according to the phosphate types including Monoammonium, Monosodium, Monopotassium, Monocalcium, Diammonium, Disodium, Dipotassium, and Diacalcium phosphates. All of the MPC binders, the ratio of magnesia to phosphate was fixed to be 7:3. MPC mortars activated with Disodium, Dipotassium, and Diacalcium phosphates showed no compressive strength gain, even at age of 28 days. Meanwhile, MPC mortars with Monoammonium and Monosodium phosphates developed 28-day compressive strength of more than 34MPa, and showed a relatively low pH value below 9.8. Hence, Monoammonium and Monosodium phosphates have potentials as an activator for producing MPC-based vegetation concrete.

Characteristic of the mixing ratio Magnesia Phosphate Composite (MPC) Exterior Material Artificial Stone According to the Waste Porcelain mixing ratio (폐자기 혼합비율 마그네시아 인산염 복합체(MPC) 외장재 인조석재의 특성)

  • Yoo, Yong-Jin;Jo, Byeong-Nam;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.160-161
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    • 2013
  • Recently, the enviroment problem is serious due to the global warming phenomenon because of the greenhouse gas exhaustion. In addition, the effort to reduce the problem in the situation where the severity of the destruction of environment because of the indiscriminate picking of the that is the raw material of the cement, Accordingly, in the interior of a country, the industrial site using the artificial stone instead of the natural stone is increased. Thus the cement reduction amount of use and substitute material research is the urgent actual condition with the gas emission, which here it is generated in conducting compression molding in the building stone manufacturing process performance degradation phenomenon and fire resistance, and problem of the durability. limestone and aggregate and exhaustion of resource are emphasized is continued. In this research, the fly ash and waste porcelain is applied to the magnesia phosphate composite (MPC) and the characteristic of the artificial stone according to it tries to be looked into.

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Fundamental Properties of Magnesia-Prosphate Composite Considering Mix Conditions and Curing Temperature (배합조건 및 양생온도에 따른 마그네시아 인산염 복합체의 기초물성 평가)

  • Cho, Hyun Woo;Kang, Su Tae;Shin, Hyun Seop;Lee, Jang Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.163-170
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    • 2012
  • With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

Tests on Magnesium Phosphate Composite Mortar Mixtures with Different Molar Ratios of MgO-to-KH2PO4 (MgO-KH2PO4 몰비 변화에 따른 마그네시아-인산염 모르타르의 배합실험)

  • Yoon, Hyun-Sub;Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.211-217
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    • 2017
  • The objective of this study is to seek a reliable mixture proportion for magnesium potassium phosphate composite(MKPC) mortars with a near-neutral pH value (below 9.5) and a relatively good compressive strength exceeding 30MPa. The main parameter selected was the molar ratios($M_{mp}$) of $MgO-to-KH_2PO_4$ which varied from 30.4 to 3.4. The setting time of the MKPC mortars tended to shorten with a decrease in $M_{mp}$ value. With regard to the strength development ratio normalized by the 28-day strength, the ranges measured in the mortars with an $M_{mp}$ below 7.9 were 50~61% at 1 day and 60~73% at 3 days, indicating a highly rapid early-strength development. With a decrease in $M_{mp}$, the formation of struvite-K crystal identified as a primary hydration product increased, which led to the decrease of the macro-capillary pores in micro-structures. For achieving the targeted requirements for pH value and compressive strength, the $M_{mp}$ needs to be selected as below 5.1.

A Hardening and Strength Properties of Magnesium Phosphate Mortars for Rapid Repair Materials (급속 보수용 마그네슘 인산염 모르타르의 경화 및 강도특성)

  • Oh, Hongseob;Lee, Inhee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.103-110
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    • 2019
  • Damage to the pavement system due to various causes will be required rapid repair work for reopening the vehicle traffic. The magnesium oxide phosphate composite(MPC) has a short curing time and is capable of early compressive strength development, is suitable for rapid repair materials. The aim of this study was to evaluate the hardening and compressive strength characteristics of MPC according to the water-binder (W / B) ratio and magnesium-phosphate(M / P) ratio in order to develop repair materials consisted with light burned magnesia and potassium dihydrogen phosphate. In order to ensure the workability in the field application, the difference of mechanical properties according to standard sand and ordinary sand and performance of retards were evaluated. The mix proportion with W/B ratio was about 35% and the M/P ratio was about 1.0 ~ 1.2 has a superior perfomance with strength and hardening condition. Especially, the strength of composite at only 1 day curing with W/B ratio of 0.35 and the M/P ratio of 1.2 was shown the higher than 25.0 MPa. Boric acid as a retarder was found to be suitable for ensuring the working time, and the purity of magnesium oxide was about 90 ~ 95%, which is effective for ensuring curing time and strength.

Physical Properties of Artificial Interior stone Using Waste Resources (폐자원을 활용한 내장용 인조석재의 물리적 특성)

  • Yoo, Yong-Jin;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.237-243
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    • 2014
  • The environmental problem is serious due to global warming In a concrete industry, the effort to reduce the problem of the destruction of environment arising from the indiscriminate use of limestone that is the raw material of cement and aggregate and the exhaustion of resources are continually emphasized In this research, the waste porcelain and waste glass that are the natural aggregate substitute materials were mixed and were applied. In addition, the magnesia phosphate composite and fly ash are mixed with a cement substitute material and the properties of the artificial stone was examined. Density, water absorption, rate of aggregate on the surface, compressive strength, and flexural strength were performed. As a result of the test, it is that waste glass with 60% and waste porcelain with 70% are the most excellent mix to produce the artificial stone.