• 한국세라믹학회지
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• 제34권7호
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• pp.677-684
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• 1997

The effects of fluxes on MgO coating materials for tundish were investigated. As the number of charge in continuous casting was increased, the basicity of tundish slag was decreased due to the increase of silica formed by dissolution from rice hull. As a result, the wear of magnesia lining was increased. In aggregates of MgO coating materials, magnesioferrite was formed by the reaction between magnesia and ferric oxide formed by the oxidation of molten steel, while matrix parts of MgO coating materials were worn by CaO-Al2O3-SiO2 compounds. Silica in rice hull extracted to the molten slag reduced basicity of slag and formed forsterite in the result of its reaction with magnesia lining. Also, fayalite was formed from the reaction between silica and ferric oxide and it caused the increment of magnesia lining's wear. The wear of magnesia lining by flux of CaO-SiO2 was larger than that of Cao-Al2O3 and calcia in the flux increased the wear of magnesia lining through the formation of rankinite.

• 한국지반공학회논문집
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• 제39권11호
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• pp.33-40
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• 2023

본 연구에서는 산화마그네슘계 내화물(Magnesium oxide-based refractory)을 함유한 팽창성 지반에서의 말뚝기초 거동을 분석하였다. 고정단 말뚝이 설치된 모형토조에 용융마그네시아(Fused magnesia, FM)를 활용하여 지반의 융기를 유도하였으며, FM함유량(FM_c = 30%, 50%, 70%)을 변화하여 시간에 따른 깊이별 융기량과 말뚝의 축력을 분석하였다. FM_c가 증가할수록 더 큰 융기량이 측정되었으며, 시료의 표면으로 갈수록 융기량이 누적되어 깊이에 따라 융기량이 감소하였다. 그러나 깊이별 융기율의 차이와 그에 따른 팽창압의 차이로 인하여 FM_c = 30%와 50%일때 말뚝에 뚜렷한 압축력과 인장력이 발현되었으며, FM_c = 70%일 때에는 말뚝 전체에 인장력만이 발현되었다. 이런한 결과는 산화마그네슘계 내화물이 포함된 혼합토 내의 말뚝거동을 분석하는데 중요한 자료로 활용할 수 있을 것으로 판단된다.

• 한국재료학회지
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• 제18권9호
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• pp.470-474
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• 2008

Composites of gadolinium-doped ceria/magnesia(CGO/MgO) were synthesized and characterized for the electrolytes of intermediate temperature solid oxide fuel cells. XRD and SEM results revealed that composite electrolytes consisted of their own phases after sintering at $1400^{\circ}C$ without noticeable solid solution of Mg into CGO. As the MgO content increased, the total electrical conductivity decreased, which might be attributed to the decrease of grain boundary conductivity, possibly due to the lowering of the continuity of the CGO grains and blocking effects of the insulating MgO phase. The space charge effect may not be a significant factor to affect the electrical conductivity of the CGO/MgO composites.

• The Korean Journal of Ceramics
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• 제3권4호
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• pp.269-273
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• 1997

Chemical composition of cement powder influences the setting time and early compressive strength development. The setting time increases as the amounts of zinc oxide and magnesium oxide are increased. For one day compressive strength development, a cement powder with a composition 90% ZnO, 8% MgO and 2% silica resulted in the highest strength (greater than 1, 090 kg/$\textrm{cm}^2$). Cement-forming liquids also need to be buffered, with both aluminum and zinc ions, for a good consistency and a higher strength of the zinc phosphate cement. These liquids control the setting reactions.

• 대한화학회지
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• 제9권1호
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• pp.49-54
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• 1965

One of the difficult and time consuming problems in the production of magnesia from sea water is a settling rate of magnesium hydroxide. In this experiments, authors attempted to accelerate its settling rate by addition of various sedimenting agents as C.M.C., Separan and Starch, and sought for optimum calcination temperature for domestic dolomite, as alkali source, mole ratio of dolomite milk to bittern. It is observed through experiments that the small amounts of sedimenting agents, C.M.C., Separan, starch, 20 mg/l, 40 mg/l, 400mg/l, respectively increase the settling rate of magnesium hydroxide by 8 times or more. The following conditions resulted in good yield of magnesium hydroxide from sea water with relatively tolerable calcium oxide contaminated for the magnesium clinker. Calcinating temperature, $1,100{\sim}1,200^{\circ}C$, mole ratio of 10% dolomite milk to magnesium salts in sea water or bittern, 1. 2 : 1.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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• pp.34-35
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• 2016

Most of the construction adhesive may contain harmful component to the human body with an organic adhesive. In addition, when the adhesive caused hydroquinone, alkyl benzophenone, etc, also it raises the skin diseases to workers. Therefore, the inorganic adhesive development is necessary. This study was a study to know adhesive strength properties that adhesive using a magnesium oxide according to the addition ratio of the retarder. It has experiments to two types of magnesium oxide and type and ratio of retarder differently.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 추계 학술논문 발표대회
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• pp.64-65
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• 2016

This study that prevent cancer using absorbent to inflow Radon gas in the room existing soil and rock is making board to absorb the Radon gas as a fundamental study. So, we use bentonite as a absorbent. So, we use bentonite as a absorbent. Bentonite is a 'clay mineral' composed to montmorillonite of main component that volcanic ash denatured to a clay mineral. Bentonite has fine microparticle of nano level, abundant mineral 66 of kinds, adsorbability, swelling, a positive ion(heavy metal adsorption reaction) as a bentonite's property. Using magnesia cement for oxide of magnesiuma and magnesium chloride as a main binder, we measure Radon gas absorbent efficiency and thermal conductivity.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.79-80
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• 2018

Recently, the interest in remodeling of new and old buildings is increasing worldwide. As a result, the frequency of use of architectural adhesives has increased. Currently, adhesives used in buildings are made of organic materials in most cases, and epoxy resin adhesives are most widely used. However, epoxy resin adhesives contain formaldehyde and VOCs in the room during construction, which can cause sick house syndrome. In case of building fire, it may cause damage due to carbon monoxide generated from organic materials. It is urgent to study the problem of epoxy fill adhesive made of such organic materials. Therefore, the purpose of this study is to investigate the effect of the adhesion of epoxy resin adhesive, which is a problem of epoxy resin adhesive, which is an existing organic adhesive by using inorganic materials such as magnesia and phosphate, And the inorganic adhesive which does not emit the release amount as an inorganic material.

• 한국주조공학회지
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• 제35권5호
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• pp.114-119
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• 2015

This paper reports the effect of a refractory crucible type on the microstructure of duplex stainless steel (DSS) cast with the addition of gadolinium using air-induction melting. Grade 4A DSSs with 1 wt% of gadolinium (Gd) were fabricated in various crucibles including alumina ($Al_2O_3$), magnesia (MgO), calcia (CaO) coated with yttria ($Y_2O_3$) and graphite. The standard free energies of the formation of calcium and yttrium oxide were lower than those of gadolinium oxide and other crucible elements based oxide. The yield of Gd in DSS using $Al_2O_3$, MgO, CaO-coated $Y_2O_3$ and graphite was 5, 19, 83 and 96%, respectively. As Gd yield increased, the amount of Gd-based inclusions increased, the size of the inclusions were reduced, and the inclusions became evenly distributed.

• 한국세라믹학회지
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• 제16권1호
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• pp.31-37
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• 1979

The middle point of composition within the system $MgO-Al_2O_3-SiO_2$ has been studied for applicability as ceramics dielectrics. A Kyul Sung Tale of high purity, magnesia clinker of Sam-wha chemical company, C.P. aluminium oxide, calcium carbonate, red lead, barium carbonate which was made into frit were used the raw materials. A number of steatite ceramics were prepared under carefully controlled condition and the water absorption, linear shrinkage, power factor, dielectric constant and dielectric loss were measured at elevated temperature. When we used magnesia clinker as flux, the quantity of this flux was 0.05mole, sintering temperature was continued for 2 hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose power factor was 0.142%, water absorption was zero, linear shrinkage was 8.76%, dielectric constant was 5.63, dielectric loss was 0.00799. When we used red lead as flux, the quantity of this flux was 0.033mole and 0.066mole, sintering temperature was continued for 2hrs. at 1, 26$0^{\circ}C$. From this conditions, we could get the data whose water absorption was zero, linear shrinkage was 8.03%, and 8.48%, power factor was 0.136% and 0.062%, dielectric loss was 0.0072 and 0.0037. When we used barium carbonate made into frit as flux, the quantity of this flux was 0.02mole, sintering temperature was continued for 2hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose water absoption was zero, linear shrinkage was 8.44%, power factor was 0.138%, dielectric constant was 5.69, dielectric loss was 0.0074.