• Title/Summary/Keyword: mPHR

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Effects of Compatibilizer on Mechanical, Morphological, and Rheological Properties of Polypropylene/Poly(acrylonitrile-butadiene-styrene) Blends

  • Kum, Chong-K.;Sung, Yu-Taek;Kim, Yong-Su;Lee, Hyung-Gon;Kim, Woo-Nyon;Lee, Heon-Sang;Yoon, Ho-Gyu
    • Macromolecular Research
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    • v.15 no.4
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    • pp.308-314
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    • 2007
  • The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

Effect of 3-Amino-1,2,4-triazole on Microstructure and Properties of Maleated HDPE/Maleated EPDM Blend (3-Amino-1,2,4-triazole이 Maleated HDPE/Maleated EPDM 블렌드의 미세구조 및 물성에 미치는 영향)

  • Kim, Tae Hyun;Chang, Young-Wook;Lee, Yong Woo;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.24-30
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    • 2014
  • 3-Amino-1,2,4-triazole (ATA) (2.5 and 5.0 phr) was incorporated into a immiscible maleated ethylene propylene diene rubber(mEPDM)/maleated high density polyethylene(mHDPE) (50 wt%/50 wt%) blend by melt mixing. Effects of the ATA on structure, mechanical and rheological properties of the blend was investigated. FT-IR and DMA results revealed that supramolecular hydrogen bonding interactions between the polymer chains occur by reaction of ATA with maleic anhydride grafted onto the component polymers in the blend, which induces the physical crosslinks in the blend. FE-SEM analysis showed that mEPDM forms a dispersed phase in continuous mHDPE matrix, and the blend with the ATA has finer phase morphology as compared to the blend without the ATA. By the addition of ATA in the blend, there were significant increases in tensile strength, modulus and elongation-at-break as well as elastic recoverability. Melt rheology studies revealed that ATA induced substantial increase in storage modulus and complex viscosity of the blend at the melt state.

Cure Kinetcs of DGEBA/MDA/GN/HQ System by DSC Analysis (DSC 분석에 의한 DGEBA/MDA/GN/HQ계의 경화반응 속도론)

  • Lee, J.Y.;Shim, M.J.;Kim, S.W.
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.904-909
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    • 1994
  • Cure kinetics of DGEBA(diglycidyl ether of bisphenol A)/MDA(4,4'-methylene dianiline)/GN(glutaronitrile) system with and without HQ(hydroquinone) as a catalyst was studied by Kissinger equation and Fractional life method. The activation energy of the system with HQ was somewhat lower and the pre-exponential factor of that was higher by about 30% than those of the system without HQ. As 1.25phr of HQ was added, reaction rates increased about 1.8 times.

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Thermal and Mechanical Properties of Elastic Epoxies (탄성형 에폭시의 열적특성과 기계적 특성)

  • Lee, K.W.;Choi, Y.H.;Shin, E.M.;Sohn, H.S.;Park, D.H.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1436-1438
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    • 2003
  • In this paper thermal and mechanical properties of elastic epoxy for applying high voltage products were investigated. Glass transition temperature(Tg) of elastic epoxies can't find form room temperature to $200^{\circ}$ by DSC. It occurred weight reduce on $285^{\circ}$ and $451^{\circ}$ by thermo-gravimeter. The first temperature was effected on addictives and the other was epoxy's character. Max, tensile strain showed $28.3kgf/cm^2$ at 20% of mechanical stress in addictives 35phr. SEM micrograph of the fracture surface observed in void and tearing of elastic epoxy at addictives 35phr. The other side, SEM micrograph of rigid epoxy showed the trace which broke.

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Development of Mobile Healthcare App for Diabetes (당뇨 관리용 모바일 헬스케어 앱 개발)

  • Im, Jura;Shin, Moon-Sun;Seo, Sung-Bo
    • Proceedings of the Korea Information Processing Society Conference
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    • 2015.10a
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    • pp.1722-1725
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    • 2015
  • 최근 스마트 폰의 보급이 빠른 속도로 확산되면서 전 세계는 스마트 서비스 시대에 진입하게 되었다. 스마트 폰을 활용한 모바일 헬스케어 서비스는 고령화 사회에서 지속적인 건강관리에 효과적으로 이용될 수 있다. 본 논문에서는 지속적인 관리가 필요한 당뇨 환자들의 식이관리 및 운동관리를 위해 당뇨 관리용 모바일 헬스케어 앱을 구현하였다. 개발된 당뇨PHR은 스마트 폰을 통해 일상생활의 라이프 로그를 입력하여 식이 관리와 운동 관리를 도와주는 기능을 수행한다. 구현된 당뇨 PHR은 사용자의 건강관리뿐 만 아니라 맞춤형 건강 정보 제공을 통해 헬스케어의 일상 구현에 기여 할 수 있다.

Effect of Compatibilizer Types on the Properties of Linear PPS/PET Blends (상용화제의 종류가 선형 PPS/PET 블렌드의 물성에 미치는 영향)

  • Kim, Sungki;Hong, In-Kwon;Lee, Sangmook
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.500-506
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    • 2013
  • The effect of compatibilizer types on the properties of polyphenylene sulfide (PPS)/polyethylene terephthalate (PET) blends was investigated. The blends were extruded by a single screw extruder attached with a Maddock mixing zone and their molded properties were examined. As a basic blend composition, a linear PPS/PET (40/60) blend was selected based on cost efficiency. Three types of compatibilizer, SEBS, modified SEBS, and modified PS were added to the basic blend to improve the properties. The thermal, rheological, mechanical properties and the morphology of the ternary blends were analyzed. The maximum mechanical properties of blends was found at 1 phr of m-SEBS or m-PS content, whose values were almost the same as the theoretical values of miscible blend system. It seemed to by the case that the partial reaction between compatibilizer and the basic blend caused the enhancement of compatibility between linear PPS and PET phases. These ternary blends would be applicable as economic linear PPS alloys.

Modifications of mechanical, thermal, and electrical characteristics of epoxy through dispersion of multi-walled carbon nanotubes in supercritical carbon dioxide

  • Zaidi, M.G.H.;Joshi, S.K.;Kumar, M.;Sharma, D.;Kumar, A.;Alam, S.;Sah, P.L.
    • Carbon letters
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    • v.14 no.4
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    • pp.218-227
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    • 2013
  • A supercritical carbon dioxide (SCC) process of dispersion of multi-walled carbon nanotubes (MWCNTs) into epoxy resin has been developed to achieve MWCNT/epoxy composites (CECs) with improved mechanical, thermal, and electrical properties. The synthesis of CECs has been executed at a MWCNT (phr) concentration ranging from 0.1 to 0.3 into epoxy resin (0.1 mol) at 1800 psi, $90^{\circ}C$, and 1500 rpm over 1 h followed by curing of the MWCNT/epoxy formulations with triethylene tetramine (15 phr). The effect of SCC treatment on the qualitative dispersion of MWCNTs at various concentrations into the epoxy has been investigated through spectra analyses and microscopy. The developed SCC assisted process provides a good dispersion of MWCNTs into the epoxy up to a MWCNT concentration of 0.2. The effects of SCC assisted dispersion at various concentrations of MWCNTs on modification of mechanical, thermal, dynamic mechanical thermal, and tribological properties and the electrical conductivity of CECs have been investigated.

A pin type current probe using Planar Hall Resistance magnetic sensor (PHR 자기센서를 적용한 탐침형 전류 프로브)

  • Lee, Dae-Sung;Lee, Nam-Young;Hong, Sung-Min;Kim, CheolGi
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.342-348
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    • 2021
  • For the characterization or failure analysis of electronic devices such as PCB (printed circuit boards), the most common method is the measurement of voltage waveforms with an oscilloscope. However, because there are many types of problems that cannot be detected by voltage waveform analysis, several other methods such as X-ray transmission, infrared imaging, or eddy current measurement have been applied for these analyses. However, these methods have also been limited to general analyses because they are partially useful in detecting physical defects, such as disconnections or short circuits. Fundamentally current waveform measurements during the operation of electronic devices need to be performed, however, commercially available current sensors have not yet been developed, particularly for applications in highly integrated PCB products with sub-millimeter fine pitch. In this study, we developed a highly sensitive PHR (planar hall resistance) magnetic sensor for application in highly integrated PCBs. The developed magnetic sensor exhibited sufficient features of an ultra-small size of less than 340 ㎛, magnetic field resolution of 10 nT, and current resolution of 1 mA, which can be applicable for PCB analyses. In this work, we introduce the development process of the magnetic sensing probe and its characteristic results in detail, and aim to extend this pin-type current probe to applications such as current distribution imaging of PCBs.

Mutator effects of plasmid pKM101 and pSL4 to E. coli DNA repair (E. coli DNA 회복에 미치는 플라스미드 pKM101과 pSL4의 mutator 기능)

  • 전홍기;이상률;백형석
    • Korean Journal of Microbiology
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    • v.28 no.2
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    • pp.109-113
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    • 1990
  • The mutagenesis-enhancing plasmid pKM101 and its mutant pSL4 were introduced into Escherichia coli B/r strains possessing different DNA repair capacities ($phr^{-}, recA^{-}, uvrA^{-}, uvrB^{-}$) and determined the protection effect and mutagenecity for UV and MNNG. The mutability and protection effect of plasmid pKM101 and pSL4 were affected by different DNA repair capacity. The mutagenecity and resistance of two plasmids were increased against UV and MNNG, and plasmid pSL4 had a higher effect than pKM101. We suggest that the functional differences between pKM101 and pSL4 is due to the variety of mutator gene.

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A Study on the Thermal Properties of Epoxy/Micro-Nano Alumina Composites, as Mixture of Surface Modified Nano Alumina (표면개질된 나노알루미나를 혼합한, 에폭시/마이크로-나노알루미나 콤포지트의 열적특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1504-1510
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    • 2016
  • The aim of this study is to improve properties both glass transition temperature($T_g$) and coefficient of thermal expansion(CTE) using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40, 50, 60wt%)+surface modified nano alumina(1_phr) composites. 20 kinds specimen were prepared with containing micro, nano alumina and GDE as a micro composites(10, 20, 30, 40, 50, 60, 70wt%) or a nano/micro alumina composites(1phr/40, 50, 60wt%). Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The glass transition temperature and coefficients of thermal expansion was evaluated by DSC and TMA. The glass transition temperature decreased and coefficients of thermal expansion become smaller with filled contents of epoxy/micro alumina composites. On the other hand, $T_g$ and CTE as GDE addition variation(1,2,3,5g) of epoxy/micro-nano alumina composites decreased and increased respectively.