• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.10a
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• pp.63-64
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• 2008

본 연구에서는 최근 염색성 향상에 관해 많은 연구가 이루어지고 있는 m-aramid를 사용하여 film으로 제조한 뒤, 표면적 증가에 따른 염색성 및 기타 다른 특성의 차이를 측정하여 비교하였다. DMAc를 용매로 하여 제조한 m-aramid 용액을 film으로 제조한 결과, 응고욕의 종류별로 염색성 및 기타 특성에 대해 상이한 결과를 보였다.

• Textile Coloration and Finishing
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• v.21 no.4
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• pp.63-67
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• 2009

m-Aramid dissolved in N,N-dimethylacetamide (DMAc), were coagulated in different coagulants such as water, methanol, ethanol, propanol and butanol. Various concentrations and temperatures of the coagulants were also used to evaluate dyeing properties of coagulated m-aramid films. Field emission scanning electron microscopy (FE-SEM) was employed to investigate the surface morphology of m-aramid films. Wide angle X-ray diffraction (WAXD) was conducted in order to measure crystallinity change of mcaramid fibers and films. WAXD patterns showed that crystallinity of m-aramid fibers was reduced after film formation. In addition, color depth (K/S value) was measured and the results revealed that the film coagulated in water possessed fairly enhanced color depth.

• Textile Coloration and Finishing
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• v.35 no.4
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• pp.221-230
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• 2023

Meta-aramid and polyamic acid were separated and the manufactured films were analyzed for their integration and logarithmic properties. The miscibility of meta-aramid and polyamic acid was analyzed by Fourier transform infrared spectroscopy and scanning electron microscopy. Using calorimetric analysis and differential scanning calorimetry, the storage of meta-aramid and polyamic acid, indicated on the right side of the column, was analyzed. It was confirmed that the initial thermal resistance occurs because the polyamic acid is accounted for in the meta-aramid, and the glass transition temperature and persistence phenomenon are explained.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.9
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• pp.1661-1668
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• 2001

본고는 지뢰 방호복을 개발, 국산화하기 위해 먼저 방탄소재 구성방법에 관하여 실험한 결과이다. 기존의 여러 겹의 파라-아라미드(Para-aramid)나 단순히 파라-아라미드와 폴리 에틸렌 필름(Polyethlene film)을 조합한 소재구성과는 달리 케블라 파이버(Kevlar fiber)로 만들어진 펠트(felt)를 첨가하여 방탄원리 및 특성을 고려한 구성으로 방호복의 중량을 줄이면서 착용자로 하여금 유연성과 동작성을 향상시켜 임무수행과 안전성을 높일 수 있는 방호복을 개발하고자 하였다. 1) Para-aramid(내 충격열) + Flex-felt(충격 에너지 흡수) + Para-aramid(backface Polyethylene film(에너지 분산 극대)+Para-aramid(내 마찰열, backface순으로 소재를 배열함으로써 기존의 Para-aramed 36겹에 대하여 Para-aramid13겹, Polyethylene film 13겹, 그리고 펠트 1겹으로 동일한 방호성능을 얻었다. 2) 새로운 소재 구성 방법 에 의 한 방탄소재는 동일한 방호성능을 갖는 기존의 소재 구성 방법 에 따른 방탄소재 보다 중량에서 34-l9% ,더 가벼운 것으로 나타나 방호복 구성시 유연성이나 동작성에 유리 할 것으로 사료된다. 3) NIJ-STD-0101.03에서 의 Armor type II에 해당하는 시편 I의 방호한계속도로 구한 운동 에너지량은 154.4J Armor type III-A에 해 당하는 시편II의 방호한계속도로 구한 운동 에너지 량은 183.0J로 나타나 두 시편 모두 5m의 거리에서 M16Al지뢰의 0.032~0.044g사이 의 파편에 대해서 50%의 관통확률을 갖는 것으로 나타났다.

• Polymer(Korea)
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• v.34 no.3
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• pp.202-209
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• 2010

Aromatic copolyamides were prepared and their applicability to proton exchange membrane wasstudied. The copolymer contains thermally stable and mechanically strong poly(m-phenylene isophthalamide) segments, and easily processable and good film forming polysulfone segments. For the copolymer, amineterminated sulfonated ether sulfone monomer, m-phenylene diamine, and isophthaloyl chloride were reacted, and the obtained copolymer was transformed into crosslinkable prepolymer by the reaction with acryloyl chloride. The prepolymer was thermally cured and converted into proton exchange membranes for fuel cell application. Each reaction step and the molecular characteristics of precursor copolymers were monitored and confirmed by $^1H$ NMR, FTIR, and titration. The performance of the membranes was measured in terms of water uptake, proton conductivity, and thermal stability. The water uptake, ion exchange capacity (IEC), and proton conductivity of the membranes increased with the increase of sulfonated ether sulfone segment content. Membrane containing 30 mol% sulfonic acid sulfone segment showed 1.57 meq/g IEC value. Water uptake was limited less than 44 wt% and the highest proton conductivity up to $3.93{\times}10^{-2}S/cm$ ($25^{\circ}C$, RH= 100%) was observed.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.4
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• pp.707-718
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• 2001

The purpose of this study is to evaluate a newly developed protective suit with the fragments of grenade. The protection efficiency should be strengthened upon the degree of wound. The fragment weight of the used grenade was measured and the kinetic energy of the maximum speed of the fragments in the field test was 137.7J and this could be the protective efficiency test by the multitude fragments in less than 0.031g of the M16A1. The panel inserted to the new demining suit has protection rate of 100% within the distance of 1m and sample II has protection rate of 100% only beyond the distance of 5m. The test showed that the protection rate on the protective suit of the existing garment was comparatively high, however, the protection rate of the sleeve part was very low. The new demining suit through the research demand some complementary measures to lower the temperatures in ear, average skin temperatures, and the temperatures-humidity inside the clothing for summer climate condition, It showed that 30 minutes of rest on the clothing was difficult to go back to the original condition. But in winter climate condition, there was no problem in the temperature, humidity, and comfort to go back to the original condition during the rest and was better in warmth.

• Fire Science and Engineering
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• v.24 no.2
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• pp.21-30
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• 2010

We have test chemical resistance and flame retardant properties of chemical protective clothing Fabrics by the ASTM and ISO standard methods. The flame retardant test results show that polyethylene is poor in flame resistance but fluoroelastomer add to decabrom is excellent in flame resistance. Especially, nowadays heat protective clothing for firefighters, which is aluminized film layers laminated to aramid fabric, show the excellent flame resistance. However, the chemical resistance test results show that aluminium is high corrosive in 4M NaOH solution alone. The problem of corrosion can be overcome by employing multiple barrier film. Also, based on the result of flame retardant test, duel skin of polymer barrier film add to aluminum film and single skin of fluorinated rubber with flame retardant materials seems to be fit for the chemical protective clothing. Also the thermal protection and heat transfer test results show that TPP and HTI is increased assured that the continued study on fire risk assessment & chemical resistance of chemical protective clothing fabrics will contribute to the upgrade the performances of chemical protective clothing fabrics.