• Title/Summary/Keyword: lubricity

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Characterization of Cr-P-C/MoS2 composite plating electro-deposited from trivalent chromium

  • Park, Jong-Kyu;Seo, Sun-Kyo;Byoun, Young-Min;Lee, Chi-Hwan
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.445-449
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    • 2018
  • Chromium plating is a common surface treatment technique extensively applied in industry due its excellent properties which include substantial hardness, abrasion resistance, corrosion resistance, surface color, and luster. In this study, the effect of $MoS_2$ particles of the composite coating was investigated. To improve the lubrication of mold, $Cr-P-C/MoS_2$ composite plating was studied by varying the $MoS_2$ content. The current efficiency of the composite plating incorporated $MoS_2$ particles was increased at $MoS_2$ contents of 0.5 and 1.0 g/l due to the incorporation of fine particles. On the other hand, when the content of $MoS_2$ is 1.0 g/l or more, the current efficiency is lowered due to an increase in impact on the cathode surface. In order to evaluate the mechanical properties of Scratch test were conducted. Scratch test confirmed the lubricity and abrasion resistance characteristics revealed that the composite plating with added $MoS_2$ had relatively low surface roughness and uniform surface modification to improve its properties.

Optimum Hydraulic Oil Viscosity Based on Slipper Model Simulation for Swashplate Axial Piston Pumps/Motors

  • Kazama, Toshiharu
    • Journal of Drive and Control
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    • v.18 no.4
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    • pp.84-90
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    • 2021
  • Viscosity of hydraulic oils decreases due to loss reduction and efficiency increase of fluid power systems. However, low viscosity is not always appropriate due to the induction of large leakage and small lubricity. Therefore, a detailed study on the optimum viscosity of hydraulic oils is necessary. In this study, based on the thermohydrodynamic lubrication theory, numerical simulation was conducted using the slipper model of swashplate-type axial piston pumps and motors. The viscosity grades' (VG) effects of oils on power losses are mainly discussed numerically in fluid film lubrication, including changes in temperature and viscosity. The simulation results reveal that the flow rate increases and the friction torque decreases as VG decreases. The film temperature and power loss were minimised for a specific oil with a VG. The minimum conditions regarding the temperature and loss were different and closed. Under various operating conditions, the film temperature and power loss were minimised, suggesting that an optimum hydraulic oil with a specific VG could be selected for given operating conditions of pressure and speed. Otherwise, a preferable operating condition must be established to determine a specific VG oil.

A Study on Biodiesel Fuel of Engine Performance and Emission Characteristics in Diesel Engine (디젤엔진 성능에 미치는 바이오디젤 연료에 관한 연구)

  • Chen, Lei;Cheng, Yukun;Kim, Jaeduk;Song, Kyukeun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.5
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    • pp.59-65
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    • 2014
  • Diesel engines have the superior combustion efficiency and fuel economy that they are widely used for industry, heavyduty vehicles, etc. However, its exhaust emissions have become the major concerns due to their environmental impacts. Moreover, the depletion of fossil fuels is the main issue. Therefore, it is important to look for alternative sources of energy. Bio-diesel is one of the ideal energy which has proved to be ecofriendly for more than fossil fuels. The experimental tests analysed the engine performance and emission characteristics of a diesel engine using diesel and biodiesel blended of BD25, BD45 and BD65, in order to study the use of clean fuel to meet the increasingly stringent emission regulations. The engine performance was examined by using engine dynamometer while an exhaust gas analyzer was used to examine the emission characteristics. The effect of biodiesel on engine performance were lower to diesel through comparing their HP and torque but fuel consumption was slightly increased because of biodiesel has lower heating value and higher density than diesel. However, due to the better lubricity, the brake thermal efficiency of biodiesel was higher than diesel. The emission characteristics were strongly affected by the blending ratio of diesel and biodiesel. The results showed that the smoke opacity, hydrocarbons (HC) and carbon monoxide (CO) emissions decreased while the nitrogen oxides (NOX) slightly increased.

Trend on Development of Polymeric Organosilicone Surfactants (고분자 유기실리콘 계면활성제의 개발 동향)

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.546-567
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    • 2015
  • Silicone-based surfactants consist of a hydrophobic organosilicone group coupled to one or more hydrophilic polar groups, while the hydrophobic groups of hydrocarbon surfactants are hydrocarbons. Silicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability. A wide range of silicone surfactant structures are required to provide the functional diversity for reflecting the necessities in the various applications. This review covers the basic properties and the synthetic schemes of polydimethylsiloxane and reactive polysiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive polysiloxanes to hydrophilic groups, and the synthetic schemes of the main polysiloxane surfactants including polyether-, ionic-, carbohydrate-type surfactants.

A Basic Study on Selection of Refrigeration Oils for R-134a Refrigerant (R-134a 냉매용 냉동기유 선정을 위한 기초 연구)

  • Na, B.C.;An, Y.J.;Han, D.C.;Chun, K.J.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.439-452
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    • 1994
  • One of the chlorofluorocarbon compounds. R-12 deplete atmospheric ozone. It leads to international agreement to reduce CFC production. R-134a has similar thermodynamic properties to CFC-12. It has zero ODP(Ozone Depletion Potential). This Paper focuses on the lubricating oils for using with R-134a PAGs(Polyalkylene Glycol's) and esters are primary lubricants that are now being tested for use with R-134a Because of extreme polarity of R-134a. there are many problems in the selection of lubricating oil. This investigation analyzes compressor working conditions and calculates wear parts friction for simulation testing. Miscibility and material compatibility is proved by sealed glass tests. Friction was tested on the closed type pin on disk wear tester. This equipment simulates actual refrigerating compressor. Environment controlled test made more reliable result than field test Conventional oils(mineral oils, Alkylbenzene, PAO(Polyalpha Olefin) are immiscible with R-134a. PAGs and ester oils are miscible with R-134a. Friction coefficient is similar to conventional system(mineral oil/R-12 systems) at operating condition. At start & stop condition, PAGs/R-134a system has high friction coefficient. It provide reliable result on the lubricity, miscibility, material compatibility of R-134a with these new lubricants. It suggests proper selection of refrigeration oil that may improve compressor durability of performance.

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Characteristic Analysis of GTL Fuel as an Automobile Diesel (자동차용 경유로서 GTL의 연료특성분석)

  • Lim, Young-Kwan;Shin, Seong-Cheol;Kim, Jong-Ryeol;Yim, Eui-Soon;Song, Hung-Og;Kim, Dongkil
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.617-623
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    • 2008
  • GTL (gas-to-liquid) fuel produced by the Fischer-Tropsch reaction of carbon monoxide (CO) and hydrogen ($H_2$) is expected to be one of the environmental friendly biomass based alternatives and blended to petrodiesel. In this study, the characteristic of the fuel was analyzed by its concentration differences after blending petrodiesel in domestic market with different amounts of GTL fuel which produced from Shell. Gas chromatography shows that GTL fuel consists of longer paraffin chain than common diesel. GTL fuel showed a high flash point, distillation, kinematic viscosity, and derived cetane number. In addition, GTL fuel showed lower lubricity due to low sulfur content.

Quantitative Analysis of Fuel in Engine Oil (엔진오일 내 연료성분 정량분석)

  • Lim, Young-Kwan;Kim, Jiyeon;Na, Yong-Gyu;Kim, Jong-Ryeol
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.714-719
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    • 2017
  • The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

Well Trajectory Modelling Considering Torque and Drag (토크와 드래그를 고려한 시추궤도 모델링 연구)

  • Jihoon Kim;Junhyung Choi;Doyoung Kim;Taeil Park;Daesung Lee
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.1
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    • pp.51-60
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    • 2023
  • Unlike the vertical drilling in the directional drilling should be minimized torque and drag in the well trajectory that avoided problems such as drillstring transformation, casing wear and key-seating. These torque and drag magnitude is determined by variations such as the well trajectory geometry, drilling mud, drillstring type and kick-off point. Therefore, it is essential to consider these variations for designing directional well trajectory. In this study, it was selected well trajectory by the most common build-hold type well and calculated torque and drag on each section by Analytical friction model. Analysis indicates that torque and drag could be minimized by using high lubricity drilling mud, kick-off point appropriate according to the well geometry and possible minimize dogleg severity. The results of this study is useful to minimize torque and drag from directional well trajectory design.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part 1) (저분자 유기실리콘 계면활성제의 개발 동향 (제1보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.66-82
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    • 2017
  • Organosilicone-based surfactants consist of hydrophobic organosilicone groups coupled to hydrophilic polar groups. Organosilicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, trisiloxane surfactants, having low molecular weight organosilicone as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of trisiloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review covers the synthetic schemes of reactive trisiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive trisiloxanes to hydrophilic groups, and the synthetic schemes of the main trisiloxane surfactants including polyether-, carbohydrate-, gemini-, bolaform-, double trisiloxane-type surfactants.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part II) (저분자 유기실리콘 계면활성제의 개발 동향 (제2보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.461-477
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    • 2017
  • Organosilicone-based surfactants, consisting of hydrophobic organosilicone groups coupled to hydrophilic polar groups, have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, organosiloxane surfactants, having low molecular weight siloxane as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of low molecular weight siloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review includes the synthetic schemes of reactive tetrasiloxanes and disiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive tetrasiloxanes or disiloxanes to hydrophilic groups, and the main synthetic schemes of the tetra- and di-siloxane surfactants having polyether-, carbohydrate-, gemini-, bola-type surfactant structures.