• Title/Summary/Keyword: low-temperature recovery

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Selection of Working fluid for the Organic Rankine Cycle to Utilize Low-Temperature Waste Heat (저온 폐열을 이용하기 위한 유기랭킨 사이클의 작동유체 선정에 관한 연구)

  • Cho, Soo-Yong;Cho, Chong-Hyun
    • New & Renewable Energy
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    • v.10 no.4
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    • pp.36-46
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    • 2014
  • Low-grade heats are wasted even though an amount of their energy is huge. In the small and medium industrial complex sites, large amount of low-grade thermal energy generated during the manufacturing process is wasted if it is not used directly for building heating or air-conditioning. In order to utilize this waste thermal energy more efficiently, organic Rankine cycle (ORC) was adopted. The range of operating temperature of ORC was set to $60^{\circ}C$ from $30^{\circ}C$ applicable low-temperature waste heat. A study was conducted to select an appropriate organic working fluid based on these operating conditions. More than 60 working fluids were screened. Eleven working fluids were selected based on the requirements as working fluid for ORC such as environmentally friendly, safety, and good operation on the expander. Finally, six working fluids were selected by considering the operating temperature ranges. Then, a cycle analysis was conducted with these six working fluids. As a results, R-245fa and R-134a appeared as appropriate working fluids for ORC operating at low-temperature condition based on the system efficiency and the turbine output power.

Physicochemical Properties of Non-Formaldehyde Resin Finished Rayon Fabric and Their Optimal Treatment Condition (비포름알데하이드계 수지 가공제 처리한 레이온직물의 물리화학적 특성 변화와 최적 처리 조건에 관한 연구)

  • Kim, Han-Gi;Yoon, Nam-Sik;Huh, Man-Woo;Jeon, Sung-Ki
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.221-231
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    • 2012
  • Rayon fabrics were treated with some commercial non-formaldehyde and low-formaldehyde resins, and then their effect on the physicochemical properties of fabrics, including formaldehyde release, tear strength, shrinkage, and wrinkle recovery, were investigated respectively. Rayons treated with non-formaldehyde resin, little formaldehyde release was observed. Considering other factors, the optimal concentration of non-formaldehyde resin was shown to be 11-13%, and curing temperature was $170{\sim}175^{\circ}C$. In case of low-formaldehyde type, 9-11% resin concentration and curing temperature of $170{\sim}180^{\circ}C$ were recommended for optimal finishing condition. The choice and combination of resins and catalysts were also important factors, and preliminary considerations before resin-finishing of rayon are also important to get much better results.

Experimental Study on Thermal Characteristics of Heat Exchanger Modules for Multi Burner Boiler (멀티버너 보일러용 열교환기 모듈 특성 시험 - 모듈 순서에 따른 특성결과 -)

  • Kang, Sae-Byul;Kim, Jong-Jin;Ahn, Joon
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3053-3058
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    • 2008
  • We develop a heat exchanger modules for a multi-burner boiler. The heat exchanger module is kind of a heat recovery steam generator (HRSG). This heat recovery system has 4 heat exchanger modules. The 1st module consists of 27 bare tubes due to high temperature exhaust gas and the others consist of 27 finned tubes. The maximum steam pressure of each module is 1 MPa and tested steam pressure is 0.7 MPa. In order to test these heat exchanger modules, we make a 0.5t/h flue tube boiler (LNG, $40\;Nm^3/h$). We tested the heat exchanger module with changing the position of each heat exchanger module. We measured the inlet and outlet temperature of each heat exchanger module and calculated the heat exchange rate. The results show that if module C is placed at second stage (the 1st stage is always module O, bare tube module), there is no need to attach an additional heat exchanger module. In this case the exit temperature of module C is low enough to enter an economizer which is more effective in heat recovery than a heat exchanger module.

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Study on the Recovery Silver and Nanoparticles Synthesis from LTCC By-products of Lowly Concentrated Silver (저농도 은이 함유된 LTCC 전극공정부산물로부터 은 회수 및 나노입자 제조 연구)

  • Joo, Soyeong;Ahn, Nak-Kyoon;Lee, Chan Gi;Yoon, Jin-Ho
    • Journal of Powder Materials
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    • v.25 no.3
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    • pp.232-239
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    • 2018
  • In this paper, the recovery and nanoparticle synthesis of Ag from low temperature co-fired ceramic (LTCC) by-products are studied. The effect of reaction behavior on Ag leaching conditions from the LTCC by-products is confirmed. The optimum leaching conditions are determined to be: 5 M $HNO_3$, a reaction temperature of $75^{\circ}C$, and a pulp density of 50 g/L at 60 min. For the selective recovery of Ag, the [Cl]/[Ag] equivalence ratio experiment is performed using added HCl; most of the Ag (more than 99%) is recovered. The XRD and MP-AES results confirm that the powder is AgCl and that impurities are at less than 1%. Ag nanoparticles are synthesized using a chemical reduction process for recycling, $NaBH_4$ and PVP are used as reducing agents and dispersion stabilizers. UV-vis and FE-SEM results show that AgCl powder is precipitated and that Ag nanoparticles are synthesized. Ag nanoparticles of 100% Ag are obtained under the chemical reaction conditions.

Operating Parameters for Glutamic Acid Crystallization in Displacement Ion Exchange Chromatography

  • Lee, Kisay
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.117-121
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    • 1997
  • Glutamic acid can be crystallized inside cation exchange column when displacer NaOH concentration is high enough to concentrate displaced glutamic acid beyond its solubility limit. Resulting crystal layer of glutamic acid was moved with liquid phase through the column, and thus could be eluted from the column and recovered in fraction collector. For the purpose of enhancing crystal recovery, effects of operating parameters on the crystal formation were investigated. The increase in the degree of crosslinking of resin favored crystal recovery because of its low degree of swelling. Higher concentration of displacer NaOH was advantageous. If NaOH concentration is too high, however, crystal recovery was lowered due to the solubility-enhancing effects of high pH and ionic strength. The decrease of mobile phase flow rate enhanced crystal recovery because enough time to attain local equilibrium could be provided, but film diffusion would control the overall crystal formation with extremely low flow rate. Lower temperature reduced solubility of glutamic acid and thus favored crystal formation unless the rate of ion exchange was severely reduced. The ion exchange operated by displacement mode coupled with crystallization was advantageous in reducing the burden of further purification steps and in preventing purity-loss resulted from overlapping between adjacent bands.

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Effect of Low Temperature Plasma and DCCA treatment on the Dimensional Stability and Hand of Wool Fabric (DCCA 처리와 산소 저온플라즈마 처리가 양모직물의 형태안정성과 태에 미치는 영향)

  • Jung, Young-Jin
    • Textile Coloration and Finishing
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    • v.20 no.4
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    • pp.43-52
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    • 2008
  • Wool fabric was treated with oxygen low-temperature plasma (LTP) and dichloroisocyanuric acid. The effect of dimensional stability (relaxation shrinkage, hygral expansion, felting shrinkage), tensile strength and elongation, crease recovery, and hand of wool fabric between LTP, DCCA treated wool fabrics and control wool fabric were investigated. SEM photograph showed that a little micro crack was formed on the fiber surface by plasma treatment with hard condition and epicuticle scale was damaged by DCCA treatment. Felting shrinkage, tensile strength and total hand value were much different in each samples.

Study on the Thermal Characteristics of Organic Rankine Cycles for Use of Low-Temperature Heat Source (저온열원 활용을 위한 유기랭킨사이클의 열적 특성에 관한 연구)

  • Jin, Jae-Young;Kim, Kyoung-Hoon
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.191-194
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    • 2011
  • Low-grade waste heat has generally been discarded in industry due to lack of efficient recovery methods. In recent years, organic Rankine cycle(ORC) has become a field of intense research and appears as a promising technology for conversion of heat into useful work of electricity. In this work thermodynamic performance of ORC with superheating of vapor is comparatively assessed for various working fluids. Special attention is paid to the effects of system parameters such as the evaporating temperature on the characteristics of the system such as maximum possible work extraction from the given source, volumetric flow rate per 1 kW of net work and quality of the working fluid at turbine exit as well as thermal efficiency.

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Stabilization of photosynthetic machinery against low-temperature photoinhibition by fatty acid unsaturation of membrane lipids in plants

  • Moon, Byoung-Yong
    • Proceedings of the Botanical Society of Korea Conference
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    • 1999.08a
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    • pp.68-82
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    • 1999
  • CHilling tolereance of plants are closely correlated with the degree of fatty acid unsaturation of membrane lipids. We studied the effects of low-temperature photoinhibition on the photochemical efficiency of photosystem II in terms of fatty acid unsaturation of thylakoid membranes lipids isolated from chilling -sensitive plants and chilling -resistant ones. To directly test the chilling tolerance of photosynthetic machinery in relation to membrane lipids, we further compared wild type tobacco plants with that of transgenic tobacco plants, in which the sensitivity to chilling had been enhanced by genetic modification of fatty acid unsaturation of chloroplast membrane lipids. The transgenic tobacco plants were found to contain reduced levels of unsaturated membrane fatty acids after being transformed with cDNA for glycerol-3-phophate acyltransferase from squash. The functional integrity of photosystem II during and recovery of photosynthesis from low-temperature photoinhibition will be discussed in connection with the degree of fatty acid unsaturation of chlorophast membranes lipids.

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The Heavy Metals Recovery from Carbonized CCA Treated Wood (CCA방부목재의 탄화가 중금속 회수에 미치는 영향)

  • Son, Dong-won;Cheon, Seon-Hae;Lee, Myung Jae;Lee, Dong-heub
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.95-100
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    • 2005
  • The using amount of preservative-treated wood equipments has been increased. Specially, chromate copper arsenate (CCA) has been widely used to exterior wood. We are faced to the disposal problem after service period of CCA treated wood due to its toxic heavy metals. For the disposal of end-used treated wood, land-filling and incinerating methods are mainly applied. The essential problem of incinerating is an arsenic release into atmosphere. Low pyrolysis is suggested as the methods of protecting arsenic release during incineration. The heavy metals were recovered after combustion of the treated wood at the low temperature which arsenic can not released. The recovery amounts of effectiveness compounds was determined in various solvents (citric acid, nitric acid, sulfuric acid, acetic acid, phosphoric acid) and different temperature (300, 400, $500^{\circ}C$). The higher temperature was applied, the more copper was recovered. The chromium was difficult to be recovered on the carbonized CCA treated wood at 0.5% acid concentration. The recovery mass of arsenic decreased on the higher combustion treated wood. The recovery of chromium was difficult due to the chemical change of the chromium arsenate during pyrolysis.

EXHAUST GAS HEAT RECOVERY SYSTEM FOR PLANT BED HEATING IN GREENHOUSE PRODUCTION

  • Kim, Y.J.;Ryou, Y.S.;Rhee, K.J.;Kang, G.C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.639-646
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    • 2000
  • Hot air heater with light oil combustion is the most common heater for greenhouse heating in the winter season in Korea. However, since the heat efficiency of the heater is about 80%, considerable unused heat in the form of exhaust gas heat discharges to atmosphere. In order to capture this exhaust gas heat a heat recovery system for plant bed heating in the greenhouse was built and tested in the hot air heating system of greenhouse. The system consists of a heat exchanger made of copper pipes, ${\phi}\;12.7{\times}0.7t$ located inside the rectangular column of $330{\times}330{\times}900mm$, a water circulation pump, circulation plastic pipe and a water tame The total heat exchanger area is $1.5m^2$, calculated considering the heat exchange amount between flue gas and water circulated in the copper pipes. The system was attached to the exhaust gas path. The heat recovery system was designed as to even recapture the latent heat of flue gas when exposing to low temperature water in the heat exchanger. According to performance test it can recover 45,200 to 51,000kJ/hr depending on the water circulation rates of 330 to $690{\ell}$/hr from the waste heat discharged. The exhaust gas temperature left from the heat exchanger dropped to $100^{circ}C$ from $270^{circ}C$ by the heat exchange between the water and the flue gas, while water gained the difference and temperature increased to $38^{circ}C$ from $21^{circ}C$ at the water flow rate of $690{\ell}$/hr. And, the condensed water amount varies from 16 to $43m{\ell}$ at the same water circulation rates. This condensing heat recovery system can reduce boiler fuel consumption amount in a day by 34% according to the feasibility study of the actual mimitomato greenhouse. No combustion load was observed in the hot air heater.

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