• Title/Summary/Keyword: low-temperature fuel cell

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Comparison of Polymer Electrolyte Membrane Fuel Cell performance obtained by 1D and CFD simulations (1D와 CFD(Computational fluid dynamic) 시뮬레이션을 통한 PEMFC(Polymer Electrolyte Membrane Fuel Cell) 성능 비교)

  • Wonwoo Jeon;Sehyeon An;Jaewan Yang;Jiwon Lee;Hyunbin jo;Eunseop Yeom
    • Journal of the Korean Society of Visualization
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    • v.21 no.3
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    • pp.49-56
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    • 2023
  • The Polymer electrolyte membrane fuel cell (PEMFC) operates at ambient temperature as a low-temperature fuel cell. During its operation, voltage losses arise due to factors such as operating conditions and material properties, effecting its performance. Computational simulations of fuel cells can be categorized into 1D simulation and CFD, chosen based on their specific application purposes. In this study, we carried out an analysis validation using 1D geometry and compared its performance with the results from 2D geometry analysis. CFD allows for the representation of pressure, velocity distribution, and fuel mass fraction according to the geometry, enabling the analysis of current density. However, the 1D simulation, simplifying governing equations to reduce time cost, failed to accurately account for fuel distribution and changes in fuel concentration due to fuel cell operations. As a result, it showed unrealistic results in the cell voltage region dominated by concentration loss compared to CFD.

A Study on the Mass Flow Effects to the Performance of PEMFC (고분자 전해질형 연료전지내의 질량유동이 성능에 미치는 영향)

  • Park, Chang-Kwon;Jo, In-Su;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.422-431
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    • 2007
  • Polymer electrolyte membrane fuel cell(PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance and effect of temperature. These problems can be approached to be solved by using mathematical models which are useful tools for analysis and optimization of fuel cell performance and for heat and water management. In this paper, the present work is to develop an electrochemical model to examine the electrochemical process inside PEM fuel cell. A complete set of considerations of mass, momentum, species and charge is developed and solved numerically with proper account of electrochemical kinetics. When depth of gas channel becomes thinner, diffusion of reactant makes well into gas diffusion layer(GDL) and the performance increases. Although at low current region there is little voltage difference between experimental data of PEM fuel cell and numerical data. When the porosity size of gas diffusion layer for PEM fuel cell is bigger, oxygen diffusion occurs well and oxygen mass fraction appears high in catalyst layer.

Thermodynamic Analysis on Hybrid Molten Carbonate Fuel Cell - Turbo Expander System for Natural Gas Pressure Regulation (용융탄산염연료전지와 터보팽창기를 이용한 천연가스 정압기지의 열역학적 분석)

  • Sung, Taehong;Kim, Kyung Chun
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.28-34
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    • 2014
  • In the natural gas pressure regulation station, high pressure natural gas is decompressing using pressure regulation valves. Waste pressure occurred in the pressure regulation process can be recovered through adopting turbo expanders. However, in the waste pressure recovery process, Joule Thompson effect causes below $0^{\circ}C$ and this low temperature freezes outside land of pipeline or generates methane hydrate in the pipeline which can block the pipeline. Therefore, turbo expander systems are accompanying with a boiler for preheating natural gas. Molten carbonate fuel cell (MCFC), one of the high temperature fuel cell, can use natural gas as a direct fuel and is also exhausting low emission gas and generating electricity. In this paper, a thermodynamic analysis on the hybrid MCFC-turbo expander system is conducted. The fuel cell system is analyzed for the base load of the hybrid system.

Research on One Dimensional Dynamic Model in Water Transportation of PEM Fuel Cell

  • Bakhtiar, Agung;You, Jin-Kwang;Park, Jong-Bum;Hong, Boo-Pyo;Choi, Kwang-Hwan
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.382-387
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    • 2012
  • Water balance has a significant impact on the overall fuel cell system performance. Proper water management should provide an adequate membrane hydration and avoidance of water flooding in the catalyst layer and gas diffusion layer. Considering the important of advanced water management in PEM fuel cell, this study proposes a simple one dimensional water transportation model of PEM fuel cell for use in a dynamic condition. The model has been created by assumption that the output is the water liquid saturation difference. The liquid saturation change is the total difference between the additional water and the removal water on the system. The water addition is obtained from fuel cell reaction and the electro osmotic drag. The water removal is obtained from capillary transport and evaporation process. The result shows that the capillary water transport of low temperature fuel cell is high because the evaporation rate is low.

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Electrochemical Performance of the Solid Oxide Fuel Cell with Different Thicknesses of BSCF-based Cathode (BSCF계 혼합전도성 공기극의 두께에 따른 고체산화물 연료전지의 전기화학적 특성)

  • Jeong, Jaewon;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.186-192
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    • 2013
  • In order to reduce the costs and to improve the durability of solid oxide fuel cell (SOFC), the operating temperature should be decreased while the power density is maintained as much as possible. However, lowering the operating temperature increases the cathode interfacial polarization resistances dramatically, limiting the performance of low-temperature SOFC at especially purely electronic conducting cathode. To improve cathode performance at low temperature, the number of reaction sites for the oxygen reduction should be increased by using a mixed ionic and electronic conducting (MIEC) material. In this study, anode-supported fuel cells with two different thicknesses of the MIEC cathode were fabricated and tested at various operating temperatures. The anode supported cell with $32.5{\mu}m$-thick BSCFZn-LSCF cathode layer showed much lower polarization resistance than that with $3.2{\mu}m$ thick cahtode and higher power density especially at low temperature. The effects of cathode layer thickness on the electrochemical performance are discussed with analysis of impedance spectra.

The effect of PEMFC stack performance at air supply condition (공기공급 조건이 스택성능에 미치는 영향)

  • Park, Chang-Kwon;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.3
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    • pp.232-238
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    • 2008
  • Research has been proceeded on fuel cell which is fueled by hydrogen. Polymer electrolyte membrane fuel cell (PEMFC) is promising power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, temperature dependent performance. These problems could be solved by experiment which is useful for analysis and optimization of fuel cell performance and heat management. In this paper, when hydrogen flows constantly at the stoichiometry of ${\xi}=1.6$, the performance of the fuel cell stack was increased and the voltage difference between each cells was decreased according to the increase of air stoichiometry by 2.0, 2.5, 3.0. Therefore, the control of air flow rate in the same gas channel is important to get higher performance. Purpose of this research is to expect operation temperature, flow rate, performance and mass transportation through experiment and to help actual manufacture of PEM fuel cell stack.

Research Trend and Analysis of Altitude and Endurance for Fuel Cell Unmanned Aerial Vehicles (연료전지 무인항공기의 고도와 체공시간에 대한 특성 분석 및 최신 연구동향)

  • Cho, Seonghyun;Kim, Minjin;Son, Youngjun;Yang, Taehyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.393-404
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    • 2014
  • Unmanned aerial vehicles (UAVs) have been applied to not only military missions like surveillance and reconnaissance but also commercial missions like meteorological observation, aerial photograph, communication relay, internet network build and disaster observation. Fuel cells make UAVs eco-friendly by using hydrogen. Proton exchange membrane fuel cells (PEMFCs) show low operation temperature, high efficiency, low noise and high energy density and those characterisitcs are well fitted with UAVs. Thus Fuel cell based UAVs have been actively developed in the world. Recently, fuel cell UAVs have started to develope for high altitude UAVs because target altitude of UAVs is expanded upto stratosphere altitude. Long endurance of UAVs is essential to improve effects of the missions. Improvement of UAV endurance time could be fulfilled by developing a hydrogen fuel storage system with high energy density and reducing the weight of UAVs. In this paper, research trend and analysis of fuel cell UAVs are introduced in terms of their altitude and endurance time and then the prospect of fuel cell UAVs are shown.

OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Study of Antifreeze Coolant for Fuel Cell System using the vehicle (연료전지 시스템 자동차용 부동 냉각액 연구)

  • Jo, Chang-Ryeol;Lee, Hong-Ki;Jeong, Jae-Hoon;Lee, Mi-Ji
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.205-208
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    • 2007
  • We aim to develop antifreezing coolant used to in the 200kW Fuel Cell system that is possible to starting at low temperature and that must not to be freezed under $-30^{\circ}C$, have high coductivity, excellent system protection ability and durability.

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