• 제목/요약/키워드: low-molar ratio

검색결과 163건 처리시간 0.024초

교반형 막 반응기를 이용한 재조합 인간 세포의 무혈청 배지에 의한 $\gamma$-Interferon의 생산 (Economic Production of $\gamma$-Interferon from Recombinant Human Cells in Serum Free Medium by a Moving Aeration Membrane Bioreactor)

  • 박영식;김현규;임서규;박경유;이현용
    • 한국미생물·생명공학회지
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    • 제22권4호
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    • pp.389-394
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    • 1994
  • 8 X 10$^{6}$(viable cells/ml) of maximum cell density and 9000(IU/ml) of $\gamma$-IFN production were obtained at 55(ml/hr) of a perfusion rate by cultivating HSF cells using a moving membrane aeration bioreactor. This system proves to be an efficient culture process by maintaning 90% of viable cells during the whole cultivation periods. The metabolic molar quotient of glucose to lactate was 0.81 for overall ranges of glucose consumed while the evolution of ammonia was not linearly related to the consumption of glutamine. Low molar conversion ratio was observed in low consumptions of glutamine and high molar conversion ratio in high comsumptions. It also shows that the glutamolysis plays important role in the steady state conditions by evolving larger quantities of ammonia than lactate. At the above of 50 rpm, which is the optimum agitation speed for this bioreactor, the cell growth was severely affected while the IFN production was less decrea- sed, maintaing 1.5 X 10$^{-3}$(IU/cell/day) specific IFN production rate. The cumulatvie $\gamma$-IFN production was 7.2 X 10$^{8}$(IU) for 70 days of the cultivation, which yields 1 X 10$^{7}$ (IU/day) of IFN production rate. Therefore, a commercial production of $\gamma$-IFN by this culture process can be achievable by maintaining the above IFN productivity in a scaled-up culture system.

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미셀 한외여과(MEUF)를 이용한 질산성 질소와 인산의 동시제거 시 휴믹산의 영향 (Effect of Humic Substances on the Simultaneous Removal of Nitrate and Phosphate in a Micellar-Enhanced Ultrafiltration (MEUF))

  • 김보경;백기태;김호정;양지원
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제8권3호
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    • pp.30-36
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    • 2003
  • 본 연구에서는 미셀 한외여과(Micellar-enhanced ultrafiltration, MEUF)공정으로 질산성 질소와 인산을 동시에 제거할 때 휴믹산이 공정에 미치는 영향을 살펴보았다. 계면활성제/오염물의 몰 비가 1인 경우, 질산성 질소는 미셀 표면에 휴믹산과 경쟁적으로 결합을 하기 때문에 그 제거율이 50%로 감소하지만, 몰 비 3 이상의 계면활성제를 첨가하였을 때에는 80% 이상의 제거율을 유지하였다. 반면 인산의 경우에는, 몰 비 1 이상의 CPC 농도에서 질산성 질소와는 달리 휴믹산이 존재하지 않는 경우와 비슷한 수준인 80% 이상의 제거율을 보였으며, 이때 CPC와 휴믹산의 제거율은 거의 99% 이상 이었다. 또한 100 ppm농도의 휴믹산은 MEUF공정에서 플럭스 감소에 영향을 미치지 않고 오히려 조금 증가시켰으며, 이는 막에 흡착한 휴믹산이 막의 친수성을 증가시켜 투과율을 높이기 때문인 것으로 판단된다. 이를 통해 휴믹산은 질산성 질소 및 인산을 동시 제거하는 MEUF 공정에서 제거효율을 저하시키지 않음을 확인하였다.

역-마이셀 공정에 의한 NiAl2O4 무기안료 나노 분말의 합성 및 특성 (Synthesis and Characterization of NiAl2O4 Inorganic Pigment Nanoparticles by a Reverse Micelle Processing)

  • 손정훈;배동식
    • 한국재료학회지
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    • 제25권2호
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    • pp.95-99
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    • 2015
  • $NiAl_2O_4$ nanoparticle was synthesized by a reverse micelle processing for inorganic pigment. $Ni(NO_3)_2{\cdot}6H_2O$ and $Al(NO_3)_3{\cdot}9H_2O$ were used for the precursor in order to synthesize $NiAl_2O_4$ nanoparticles. The aqueous solution, which consisted of a mixing molar ratio of Ni/Al, was 1:2 and heat treated at $800{\sim}1100^{\circ}C$ for 2h. The average size and distribution of synthesized $NiAl_2O_4$ powders are in the range of 10-20 nm and narrow, respectively. The average size of the synthesized $NiAl_2O_4$ powders increased with an increasing water-to-surfactant molar ratio and heating temperature. The crystallinity of synthesized $NiAl_2O_4$ powder increased with an increasing heating temperature. The synthesized $NiAl_2O_4$ powders were characterized by X-ray diffraction analysis(XRD), a field emission scanning electron microscopy(FE-SEM), and a color spectrophotometer. The properties of synthesized powders were affected as a function such as a molar ratio and heating temperature. Results indicate that synthesis using a reverse miclle processing is a favorable process to obtain $NiAl_2O_4$ spinels at low temperatures. The procedure performed suggests that this new synthesis route for producing these oxides has the advantage of being fast and simple. Colorimetric coordinates indicate that the pigments obtained exhibit blue colors.

저압나노여과에 의한 각종 중금속의 제거 특성 (Rejection Characteristics of Various Heavy Metals by Low-pressure Nanofiltration)

  • 오정익;김한승;김충환
    • 상하수도학회지
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    • 제18권4호
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    • pp.493-499
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    • 2004
  • Rejection characteristics of heavy metals by nanofiltration membranes were investigated. Nanofiltration membranes rejected heavy metals much better than chloride, sulfate and TOC, of which concentration in synthetic wastewater was higher than that of heavy metals. To consider rejection characteristics of various metals by nanofiltration membranes, separation coefficient, which is the ratio of the metal permeation rate to the chloride ion or TOC permeation rate, was introduced. In spite of different materials and different nominal salt rejection of nanofiltration membrane used, the separation coefficients of metals were nearly the same. In particular, the separation coefficient of arsenic against chloride ion and TOC was larger than any other separation coefficient of heavy metals. These phenomena were observed in the relationship between the molar conductivity and the separation coefficient for heavy metals.

Effects of Ga Composition Ratio and Annealing Temperature on the Electrical Characteristics of Solution-processed IGZO Thin-film Transistors

  • Lee, Dong-Hee;Park, Sung-Min;Kim, Dae-Kuk;Lim, Yoo-Sung;Yi, Moonsuk
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제14권2호
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    • pp.163-168
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    • 2014
  • Bottom gate thin-film transistors were fabricated using solution processed IGZO channel layers with various gallium composition ratios that were annealed on a hot plate. Increasing the gallium ratio from 0.1 to 0.6 induced a threshold voltage shift in the electrical characteristics, whereas the molar ratio of In:Zn was fixed to 1:1. Among the devices, the IGZO-TFTs with gallium ratios of 0.4 and 0.5 exhibited suitable switching characteristics with low off-current and low SS values. The IGZO-TFTs prepared from IGZO films with a gallium ratio of 0.4 showed a mobility, on/off current ratio, threshold voltage, and subthreshold swing value of $0.1135cm^2/V{\cdot}s$, ${\sim}10^6$, 0.8 V, and 0.69 V/dec, respectively. IGZO-TFTs annealed at $300^{\circ}C$, $350^{\circ}C$, and $400^{\circ}C$ were also fabricated. Annealing at lower temperatures induced a positive shift in the threshold voltage and produced inferior electrical properties.

Struvite 결정화를 이용한 반도체 폐수처리 시 불소제거를 위한 최적 조건 (Optimum Condition for Fluoride Removal Prior to the Application of Struvite Crystallization in Treating Semiconductor Wastewater)

  • 안명기;우귀남;김진형;강민구;류홍덕;이상일
    • 한국물환경학회지
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    • 제25권6호
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    • pp.916-921
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    • 2009
  • This study was aimed to both enhance the fluoride removal and to reduce the phosphorus removal in treating semiconductor wastewater using $Ca(OH)_2$ at low pH so as to facilitate struvite crystallization reaction. The struvite crystallization could be introduced after fluoride removal by retaining the phosphorus source. As the results, the method applied in this study achieved high fluoride removal efficiency (about 91%) with retardation of phosphorus removal at pH 4, compared to conventional methods where the removal of fluoride and phosphorus were done at pH 11. Therefore, the fluoride removal at low pH would contribute to the enhancement of nitrogen and phosphorus removals in a consecutive struvite crystallization reactor. Treatment of semiconductor wastewater at low pH using $Ca(OH)_2$ also had lower (about 20%) water content of precipitated sludge compared to conventional method. As the molar ratio of Ca to F increased the removal efficiencies of fluoride and phosphorus increased. Although the amount of seed dosage didn't affect the removal of fluoride and phosphorus, its increase reduced the water content of precipitated matter. Finally, considering consecutive struvite reaction, the optimum condition for the removal of fluoride and phosphorus was as follow: pH: 4, the molar ratio of Ca:F: 1:1.

Solution-Processed Indium Oxide Transistors

  • Facchetti, Antonio;Kim, Hyun-Sung;Byrne, Paul D.;Marks, Tobin J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.995-997
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    • 2009
  • $In_2O_3$ thin-film transistors (TFTs) were fabricated on various dielectrics [$SiO_2$ and self-assembled nanodielectrics (SANDs)] by spin-coating a $In_2O_3$ film precursor solution consisting of methoxyethanol (solvent), ethanolamine (EAA, base), and $InCl_3$ as the $In^{3+}$ source. Importantly, an optimized film microstructure characterized by the high-mobility $In_2O_3$ 004 phase, is obtained only within a well-defined base: $In^{3+}$ molar ratio. The greatest electron mobilities of ~ 44 $cm^2$, for EAA:$In^{3+}$ molar ratio = 10, $V^{-1}s^{-1}$, is measured for $n^+$-Si/SAND/$In_2O_3$/Au devices. This result combined with the high $I_{on}:I_{off}$ ratios of ~ $10^6$ and very low operating voltages (< 5 V) is encouraging for high-speed applications.

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Metal-Organic Decomposition법에 의한 강유전성 $YMnO_3$ 박막의 제조 및 특성 (Preparation of Ferroelectric $YMnO_3$ Thin Films by Metal-Organic Decomposition Process and their Characterization)

  • 김제헌;강승구;김응수;김유택;심광보
    • 한국세라믹학회지
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    • 제37권7호
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    • pp.665-672
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    • 2000
  • The ferroelectric YMnO3 thin films were prepared by MOD(metal-organic decomposition) method with Y- and Mn-acetylacetonate as starting materials. Thin films were grown on various substrates by spin-coating technique. The crystalline phases of the thin films were identified by X-ray diffractometer as a function of heat-treatment temperature, pH of coating solution and substrate. In addition, the effect of Mn/Y molar ratio(0.8~1.2) on the formation of hexagonal-YMnO3 phase was investigated. In forming highly c-axisoriented hexagonal-YMnO3 single phase, the Pt coated Si substrate was more effective than the bare Si substrate, and the optimum heat-treatment condition was at 82$0^{\circ}C$ for 30 min. Higher Mn/Y molar ratio within 0.8~1.2 and pH of YMnO3 precursor solution within 0.5~2.5 favored formation of ferroelectric hexagonal phase rather than orthorhombic phase. Leakage current density of the hexagonal-YMnO3 thin film formed on Pt(111)/TiO2/SiO2/Si substrate was low enough as 0.4~4.0$\times$10-8(A/$\textrm{cm}^2$) at 5 V and its remanent polarization(Pr), calculated from the P-E hysteresis loop, was 3 nC/$\textrm{cm}^2$.

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국내산 납석을 이용한 저팽창성 Machinable Ceramics의 제조 (Fabrication of Low TEC Machinable Ceramics using Domestic Pyrophillite)

  • 김재국;양삼열;정창주
    • 한국세라믹학회지
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    • 제28권9호
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    • pp.730-738
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    • 1991
  • Machinable ceramics containing ${\beta}$-spodumene crystal was fabricated by melting method using domestic pyrophyllite. Raw materials were batched by molar ratio of 8:2, 7:3, 6:4, and 5:5 for fluorophlogopite and ${\beta}$-spodumene. These compounds were melted at 1450$^{\circ}C$ for 1 hr and formed in graphite mold. Base glasses were heat-treated according to 2-step schedule which was determined from DTA, XRD analysis and SEM observation. Fabricated machinable ceramics have excellent themal, chemical properties and machinability.

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공단 인접지역 산림토양용액의 특성 (Characteristics of Soil Solution Extracted from Forest Soils Adjacent to Heavy Industrial Complexes)

  • 이위영;양재의;박창진;장용선;옥용식
    • 한국토양비료학회지
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    • 제37권3호
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    • pp.184-191
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    • 2004
  • Forest soils were collected from various sites adjacent to the heavy industrial complexes and soil solutions were extracted to characterize the chemical properties and to find factors affecting forest decline by acid deposition. Concentrations of $NO_3{^-}$, $SO{_4}^{2-}$, $F^-$ and Al in the soil solutions collected from industrial complexes were 2-33 times higher than those from the non-industrial areas. pH and Al concentrations were significantly correlated with $NO_3{^-}$ and $SO{_4}^{2-}$ concentrations. Forest soils from Onsan and Ulsan regions had very low Ca and Mg concentrations in the soil solutions. In these sites, the molar ratios of Ca/Al and Mg/Al were also lower than 2 and 1, respectively. Aluminum concentrations in the A and B horizons were 547 and $683mg\;kg^{-1}$, respectively, which were considered to be high enough to inhibit tree growth. Magnesium deficiency in A horizon and high concentrations of Al and Mn in B horizon were considered as the major limiting factors for tree growth by inhibiting the uptake of Ca and Mg and causing the imbalance of nutrients in both soil solution and trees.