• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.11a
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• pp.143-146
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• 1994

In older to investigate the properties of electric conduction in low density polyethylene(LDPE) for power cable, the thickness of specimen was the 30, 100($\mu\textrm{m}$) of LDPE. The experimental condition for conductive properties was measured until the breakdown occurs at temperature ranges from 30 to 110[$^{\circ}C$] and in the electric field of 1 to 5 ${\times}$10$^2$[Mv/m]. As for increase of temperature, the current density of LDPE was increased with constant ratio in low field, but changes with exponential function in high field. The tunnel current of pre-breakdown region is shifted toward low field as much as thermal excitation energy.

• Elastomers and Composites
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• v.36 no.3
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• pp.195-200
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• 2001

Ultraviolet photografting of acrylic acid onto low density polyethylene was characterized using XPS and contact angle measurement. Effects of surface modification at LDPE and aluminum on LDPE/Al laminate were also investigated. Contact angle decreased significantly at initial state arid tends to level off with increasing UV irradiation time. The improvement of hydrophilicity was due to the presence of acrylic acid on LDPE surface. Graft of acrylic acid onto LDPE was also identified from O1s/C1s ratios in XPS spectrum. Adhesion strength of LDPE-g-AAc/Al laminate showed about 30 times higher than LDPE/A1 system and it could be attributed to the increase of polarity of LDPE surface. Chemical treatment of Al surface using sulfuric acid/sodium dichromate also increased the adhesion strength of LDPE/Al laminate. Adhesion strength of LDPE/Al laminate decreased significantly under acetic acid.

• Food Science and Preservation
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• v.10 no.2
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• pp.131-135
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• 2003

Bell pepper was packed with several plastic films, and investigated the quality Characteristics such as gas composition, weight loss, microbial load, soluble solid content, ascorbic acid and color during storage at 10$^{\circ}C$. Cast polypropylene (CPP), low density Polyethylene (LDPE), Polyolefin (MPD, PD961) and linear low density polyethylene (LLDPE) were used for this purpose. Oxygen concentration inside packages generally showed a 10∼14% after 1∼2 weeks, but package with CPP maintained above 15％ throughout the storage. Carbon dioxide concentration of CPP was above 2%, but other treatments showed below 2%. Weight loss of all treatments was below 3.0% after 5 weeks. Total microbial count showed a similar pattern compared to yeast and mold, and CPP maintained the highest microbial load after 3 weeks. Yellowness (b value) of bell pepper was generally increased throughout the storage, and MPD and PD961 were higher than other treatments.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.120-126
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• 1997

The thermal decomposition of low density polyethylene(LDPE) and $25\%{\~}48\%$ chlorinated polyethylene(CPE) were studied using a dynamic thermogravimetry in the stream of nitrogen gas with 20ml/min. The mathematic method, differential (Friedman) and Integral (Ozawa) method were used to obtain value of activation energy of decomposition energy on the reaction. The activation energies evaluated by the above methods agree with each other very well. The maximum average activation energy calculated was 71.71kcal/mol. The thermal decomposition of LDPE and CPE were considered to be carried out by main chain scission and the thermogravimetric trace curve agree with the theoretical equation.

• Advances in materials Research
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• v.1 no.4
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• pp.245-268
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• 2012

Results of isothermal torsional oscillation tests are reported on melts of linear low density polyethylene and isotactic polypropylene. Prior to rheological tests, specimens were annealed at various temperatures ranging from $T_a$ = 180 to $310^{\circ}C$ for various amounts of time (from 30 to 120 min). Thermal treatment induced degradation of the melts and caused pronounced decreases in their molecular weights. With reference to the concept of transient networks, constitutive equations are developed for the viscoelastic response of polymer melts. A melt is treated as an equivalent network of strands bridged by junctions (entanglements and physical cross-links). The time-dependent response of the network is modelled as separation of active strands from and merging of dangling strands with temporary nodes. The stress-strain relations involve three adjustable parameters (the instantaneous shear modulus, the average activation energy for detachment of active strands, and the standard deviation of activation energies) that are determined by matching the dependencies of storage and loss moduli on frequency of oscillations. Good agreement is demonstrated between the experimental data and the results of numerical simulation. The study focuses on the effect of molecular weight of polymer melts on the material constants in the constitutive equations.

• Fire Science and Engineering
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• v.14 no.1
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• pp.1-7
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• 2000

Internal insulators give rise to partial discharge(PD), which cause local breakdown and even entire insulation breakdown. Treeing due to PD is one of the main causes of breakdown of the insulating materials and reduction of the insulation life. Therefore the necessity for establishing a method to diagnose the aging of insulation materials and to predict the breakdown of insulation has become important. From this viewpoint, we have studied on Electric Field dependence of tree shape in Low Density Polyethylene about treeing phenomena occurring on the high electrical field. As the result, under the reasoning that the growing of tree supposing when the inner part of tree is either dielectrec or conductor has the intermediate characteristics between dielectrec and conductor, theoretically investicated results well according with the experimental results.

• Journal of the Korean Society of Safety
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• v.6 no.2
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• pp.15-20
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• 1991

In this paper, we have investigated the effect of organic additives and prestressed D C. voltage on the impulse tree initiation in low density polyethylene. The five klnds of organic compounds was selected for the purpose of inhibiting tree initiation and 10 wt % of each additive was mixed in low density polyethylene. The positive or negative impulse voltage was applied after prestressed D.C. voltage was applied in order to investigate the effect of the space charge influenced on tree initiation. The lengths of tree initiation in case of belng same polarity between prestressed D.C. voltage and impulse voltage were longer than those in case of being different polarity between prestressed D.C. voltage and impulse voltage. When the polarity prestressed D.C. voltage was the different plarity of impulse voltage, the length of tree initiation increased with increasing the prestressed D.C. voltage and decreasing the rest time Among the organic additives used in this paper, the m-cresol can be shown to be the most effective inhibiter to tree initiation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.215-218
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• 1998

XLPE/VLDPE (Crosslinked polyethylene/very low density polyethylene) blends were prepared by a twin screw extruder and their electrical properties such as water tree and breakdown characteristic were measured. it was found that both water tree and breakdown characteristics of XLPE were improved by the addition of VLDPE to polyethylene. It was also found that the extent of improvement of electrical properties by the addition of VLDPE to polyethylene depends on the type and concentration of VLDPE.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.8
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• pp.455-461
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• 2000

The inhibiting effects of electrical treeing and insulation properties of LDPE contained with treeing inhibitors was studied under radiation environment. Barbituric acid and its derivatives were selected as treeing inhibitors. The inception voltage and growth of tree, AC breakdown strength, volume resistivity, high frequency capacitance, and dissipation factor were observed as a function of dose(up to 1000 kGy). And also, measurements of thermo-luminescence(TL), and gel content were carried out. Crosslinked low density polyethylene(XLPE) contained with treeing inhibitors shows better insulation characteristics such as electrical tree propagation, AC breakdown strength, and volume resistivity than those of pure LDPE. The most effective treeing inhibitor was found on the barbituric acid contained XLPE.

• Macromolecular Research
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• v.10 no.3
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• pp.168-173
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• 2002

Unstabilized low-density polyethylene (LDPE) films and films formulated with hindered amine light stabilizer (HALS) were exposed to UV-radiation; and the physicochemical changes during photooxidation processes have been investigated using tensile, FTIR spectre-photometric and thermal analytical (DSC) techniques. The dependence of tensile properties (elongation- and stress-at-break), carboxyl index and heat of fusion on UV-irradiation time have been discussed. The use of HALS is found to be effective in maintaining the UV-mechanical properties of the LDPE films. The experimental results showed that there exists no correlation between mechanical properties and carbonyl index, whereas crystallinity correlates well with carbonyl index in unstabilized and stabilized films for irradiation times greater than 100 h. The rate of formation of carbonyl groups is found to be dependent on UV exposure time. Crystallinity of the film samples is strongly influenced by both exposure time and presence of HALS.