• 한국환경보건학회지
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• 제19권2호
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• pp.46-54
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• 1993

This study was carried out on the stabilized/solidified treatment for the reducing leachability of hazardous heavy metals copper, lead, chromium and cadmium in the hazardous sludge which treated to be unleached heavy metals by sodium diethyl dithiocarbamate. Cement matrix was analyzed for the leachability of 24 hrs and dynamic leaching test, structure and the optimum condition for the stabilization and solidification of the hazardous sludge. In 28 days of curing time the unconfined compressive strength was 21.5 kg/cm$^2$ at the ratio of portland cement (0.5)+fly ash (0.25) and 23.5 kg/cmz at the ratio of portland cement (0.5)+fly ash (0.25) + cake (0.25). High concentration of Pb, Cr and Cd in the sea water and Cu in the distilled water were leached at the dynamic leaching test. The concentration of leaching heavy metals for specimens which were tested 24 hrs were found low leachability with decreasing pH of leachant. According to dynamic leaching test, the low level of copper, lead, cadmium and chromium were leached in the cement matrix with sodium diethyl dithiocarbamate. But the effective diffusion coefficient of unleached cement matrix which was treated sodium diethyl dithiocarbamate was decreased above 2 times than that of cement matrix. The relation of leachant renewal period (Y) and cumulative fraction ion leached (X) was the following regression equations. Solidification with unleached agent. Y$_{Cu}$ = 1413752X + 247, Y$_{Pb}$ = 223501IX + 214, Y$_{Cr}$ = 8310601X - 472, Y$_{Cd}$ = 168787X + 1061 The structure of' solidified matrix with X-ray diffraction analysis was composed more Ca(OH)$_2$, Si, Mg(OH)$_2$ and Al in the unleached cement matrix than those in cement matrix.

• 한국지반공학회논문집
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• 제26권1호
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• pp.75-83
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• 2010

저강도고유동화재는 다짐이 필요 없고 유동성이 큰 물질로 일반적으로 시멘트, 비회, 잔골재, 물, 혼화제 등을 혼합하여 만들어진다. 기존의 CLSM은 잔골재로 모래를 사용하고 있으나 때문에 모래가 점점 구하기 어려워지는 현재 우리나라 실정에서는 그대로 사용하기 곤란하다. 본 연구에서는 모래대신 매립회를 이용하여 매립회, 비회, 시멘트, 물의 혼합물로 만들어진 CLSM의 강도특성을 조사하여 사용가능성을 제시하고자 한다. 일축압축강도실험결과 기준 일축압축강도(0.5MPa~1.0MPa)를 만족하는 배합비는 매립회와 비회의 혼합비 0:100~70:30, 시멘트비 3.0~5.0%, 함수비 31~34%로 나타났다. 플로우시험 결과 매립회와 비회를 혼합하여 사용하는 모든 경우(매립회와 비회의 비 30:70~70:30)에서 기준 플로우값(0.2m)를 만족하였다.

• Geomechanics and Engineering
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• 제33권3호
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• pp.261-269
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• 2023

In this study, the compressive strength of cement stabilized soil was predicted using the electrical resistivity measurement. The effects of the water to cement (w/c) ratio and recovered Carbon Black (rCB) contents were examined. A series of electrical resistivity and compressive strength tests were conducted on two types of stabilized soil after 28 days of curing. Multiple nonlinear regression (MNLR) analysis was used to evaluate the relationship between the compressive strength and the electrical resistivity in terms of the rCB, C_u (uniformity coefficient), and w/c ratio. The results showed that the w/c ratio and C_u have a strong influence on the compressive strength and electrical resistivity of the cement stabilized soil compared to the rCB content. The use of a small amount of rCB led to a decrease in the void space in the specimen and was attributed to the increase strength and decrease electrical resistivity. A high w/c ratio also induced a low electrical resistivity and compressive strength, whereas 3% rCB in the cemented soil provided the optimum strength for all w/c ratios. Finally, a prediction equation for the compressive strength using the electrical resistivity measurement was suggested based on its reliability, time effectiveness, non-destructiveness, and cost-effectiveness.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 봄 학술논문 발표대회
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• pp.193-194
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• 2020

Recently, as the use of high-performance concrete has become common, various problems related to high-performance concrete have become an issue. Among them, self-shrinkage of cement paste due to low water cement ratio is known to cause problems in the volume stability of concrete. To improve this, studies related to the mixing technology of cement-based materials and nano materials have been actively conducted. Looking at the results of prior research related to nano material mixing technology, generally, research results have been reported in which nano materials are incorporated into cement-based materials to improve material properties1). Among them, it was shown that the mechanical performance and various types of functionality of the cement composite are expressed. Among nano materials, carbon nanotubes (hereinafter referred to as CNTs) and graphenes are used in a mixture with cement-based materials. Accordingly, this study intends to compare the mechanical properties by incorporating various CNTs and graphene into cement paste.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 봄 학술발표회 논문집
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• pp.315-322
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• 1997

This paper describes an experimental study on the seawater resistance of steel fiber reinforced concrete. The test method adopted for this study may be devided into long-term immersion test and accelerated test by wetting and drying. Test were carried out to evaluate the procedure in which reduction in dynamic modulus, length change and compressive strength to nine months were measured. Resistance indicators are the water - cement ratio, the content of steel fiber, the immersion water(artificial seawater or freshwater). The conditions of intervals of immersing in artificial seawater and drying, low water-cement ratio, and non-steel fiber became most deteriorated.

• 한국구조물진단유지관리공학회 논문집
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• 제22권6호
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• pp.182-188
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• 2018

최근 우수한 전기전도도와 넓은 비표면적을 갖는 탄소나노튜브(CNT)를 활용하여 고강도 및 고내구성 콘크리트의 생산을 위한 연구가 많은 연구자들에 의하여 활발히 이루어지고 있다. CNT의 혼입을 통한 콘크리트의 고강도에 대한 연구가 주를 이루고 있으나, 그 외의 연구는 미흡한 실정이다. 이에, 본 연구에서는 CNT 첨가량에 대한 시멘트 복합체의 역학성능 및 발열성능에 대한 평가를 실시하였다. 낮은 물-바인더 비를 기반으로 하는 시멘트-플라이애시 배합에 대하여, 바인더 중량대비 0.2% 및 0.5%의 CNT 첨가에 따른 재령별 압축강도, 수화특성분석을 위한 미소수화열 분석, 페이스트 내 CNT의 분산 및 주변 수화물과의 관계를 규명하기 위한 SEM분석, 기준전극 삽입을 통한 발열실험 및 열 중량 분석을 실시하였다. CNT 첨가량의 증가에 따라 발열성능은 증가하며, CNT가 첨가되지 않은 기준 배합 CNT가 첨가된 배합의 경우 동등수준의 역학성능을 갖는 것으로 나타났다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2002년도 가을 학술발표회 논문집
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• pp.665-672
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• 2002

In order to expand agricultural lands in the western and southern coasts of Korean Peninsula, coarse soils excavated from hillsides have been used as fill materials for reclamation. In order to tackle with the problems and to confirm availability, research on soil improvement involve mixing cement to the fine wet soils. Required undrained shear strength(c$\sub$u/) for fill material was analyzed to be 0.34∼1.2kg/$\textrm{cm}^2$. It has been known that when cement is added to high water content marine clay, its unconfined compression strength increased to 2kg/$\textrm{cm}^2$. Consolidation results show that pre-consolidation pressure increased to 1.8kg/$\textrm{cm}^2$ and 3.4kg/$\textrm{cm}^2$ with the addition of 3% and 5% of cement respectively. This result shows that low-height embankments could be constructed without significant compression. Since the effectiveness of improvement may be different site by site, the mix design for each site is necessary in order to optimize it. The process is first to determine aimed shear strength and then optimum mix ratio of cement after carrying out a series of tests.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.603-606
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• 2005

Strength development of low heat portland cement(Type IV) concrete according of addition of fly-ash in high strength range is tested. In this study strength development according to water-binder ratio, strength development according to age, effect of fly ash are tested. This study tests effect of low heat portland cement in high strength range concrete and provide guide line concrete mix design for later study and construction.

• 콘크리트학회논문집
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• 제27권2호
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• pp.115-125
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• 2015

본 연구는 물-결합재비 20%를 가지는 고강도 고함량 고로슬래그 혼합 시멘트 페이스트의 유동성, 수화열, 응결시간 그리고 강도 발현 특성, 수화 및 포졸란 반응 특성 등을 실험을 통해 관찰하고, 이를 통해 고로슬래그 미분말의 치환률과 분말도가 수화 및 포졸란 반응에 미치는 영향을 분석하였다. 연구 결과에 따르면 물-결합재비가 낮은 고강도 배합에서는 고로슬래그 미분말로 시멘트를 대체함으로써 시멘트와 결합하는 자유수가 상대적으로 증가하는 dilution effect에 의해 시멘트의 초기 수화가 촉진되어 재령 3일부터 28일까지의 초기 강도는 보통 포틀랜드 시멘트만을 사용한 배합보다 더 높게 나타났다. 반면, 재령이 증가하면서 수화반응속도가 급격히 낮아지고, 고로슬래그 미분말로 시멘트를 대량 치환함에 따라 수산화칼슘이 충분히 공급되지 못하므로 포졸란 반응도가 낮아져 장기강도의 발현이 억제되는 것으로 나타났다. 또한 고로슬래그의 분말도가 높으면 자유수를 더 많이 흡착함으로써 유동성이 저하되고 수화도가 낮아져 강도가 오히려 저하되는 것으로 나타났다. 이와 같은 결과는 보통 강도 콘크리트와는 다른 경향을 나타내는 것으로 향후 콘크리트 배합에 대해 추가 검증이 필요하며, 고로슬래그 미분말을 대량 혼합한 고강도 콘크리트의 개발을 위해서는 장기 강도의 발현율을 더 높일 수 있는 방안에 대한 연구가 필요하다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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• pp.47-52
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• 2000

Recently, it is very necessary the development of the manufacturing techniques for high strength concrete(HSC) for the large-scale size and good quality of civil structure. But, the manufacture and quality control of HSC of which shrinkage, heat of hydration and workability at construction filed are considered, is very difficult due to its low water-cement ratio and high quantity of unit cement content. In the present study, we tried to know and assess the influences of chemical and physical properties of cement on the material properties of HSC. We analyzed basic properties of 4 kinds of cement whose chemical and physical properties are different each other through various tests such as chemical analysis and mortal test. Also, we performed the assessment of the material properties of HSC for each dement by the test for the conditions of same mix design and similar compressive strength. From the results in the study, the assessment of the important quality factors of cement influencing the properties of HSC may be utilized to quality control of applied cement to manufacture the HSC of high quality.