• Clean Technology
• /
• v.18 no.2
• /
• pp.170-176
• /
• 2012

A series of acrylic copolymers containing perfluoroalkyl acrylate were synthesized by 2-step emulsion polymerization of variety of acrylate monomers (ethyl acrylate, butyl acrylate or methyl methacrylate) with perfluoroalkyl ethyl acrylate (PFA) and glycidyl methacrylate (GMA) monomers. This study focused on effects of monomer compositions (the kind of acrylate monomer, contents of PFA and GMA) and composition of surfactants [(sodium dodecyl sulphate/nonylphenol 10mole ethoxylate (NP-10)] and initiator content on the contact angles and surface free energy. It was found that the copolymer having an optimum composition (BA : 87 wt%, GMA : 8.7 wt% and PFA : 4.3 wt%) was shown to be quite surface active [surface free energy : 19.89 mN/m and contact angles : $103.5^{\circ}$ (water) and $78.7^{\circ}$ (methylene iodide)] in the solid state. This result suggests that the optimal copolymer containing fluorinated monomer synthesized in this study have high potential as a low surface energy material, which may have high oil- and water-repellent surface and have been proposed as acrylic syntan for leather and also as soil-resistant/oil and water repellent coating for textiles and wood etc.

• Journal of the Korean Wood Science and Technology
• /
• v.27 no.3
• /
• pp.82-90
• /
• 1999

The buddhistic painting of Song-Kwang temple in Seungjoo-gun, Chonnam, Korea is not known in chronicle, but it could be estimated to works in the early 19th century through it's remaining records and qualities of materials. And it was analysed the qualities of materials consisting of pigment layer, silken-ground layer and support layer in order to preserve buddhistic painting, made back-adherent paper of the support layer proper to it, tested its compatibility, and then concluded as follows. 1. The section structures of buddhistic painting is consisted of the pigment layer, silken-ground layer of silk and the support layer of Korean hand made paper, it could be recognized that buddhistic painting in 19th century was basically composed of the pigment layer, the silken-ground layer and the support layer. Moreover the pigment layer and the silken-ground layer got adhered with glue, and sheets of support layers got back adhered with paste. 2. The support layer of buddhistic painting consisted of 5 layers and two kinds of paper were used for them. The first and second layers were composed of Korean hand made paper made of pure paper mulberry bast fibers, and the rest of them of paper that paper mulberry bast fibers were mixed into recycled hemp fibers. Though it is difficult to assert without the security of more data, finding out the then situation through the qualities of materials, it was presumed that the society in 19th century was suffered from economical difficulties and the operation of the paper industry of temples was rather difficult and so low-qualitative recycled hemp fibers might used for back-adherent paper. 3. Considering tension between silken-ground layers and support layers of this materials, newly made back-adherent paper was used for repair, and then I could conform that it was proper to back-adherent paper for repair.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.7 no.3
• /
• pp.19-31
• /
• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Journal of the Korea Concrete Institute
• /
• v.14 no.4
• /
• pp.521-529
• /
• 2002

A restraint coefficient for creep and dry shrinkage deformation of concrete in a composite section was derived to calculate the residual stress, and an equation for the loss rate of the pre-compression force was proposed. The derived restraint coefficient was computed by using the transformed section properties for the age-adjusted effective modulus of elasticity. The long-term behavior of complicate composite sections could be analyzed easily with the restraint coefficient. The articles of the current design code was examined for PSC and steel composite sections. The dry shrinkage strains of $150 ~ 200$\times$10^{-6}$ for the computations of the statically indeterminate force and the expansion joint could be under-estimated for less restrained sections such as the reinforced concrete. The dry shrinkage strain of $180$\times$10^{-6}$ for the computation of residual stress in the steel composite section was unreasonably less value. The loss rate of 16.3% of the design code for the PSC composite section in this study was conservative for the long-term deformation of the ACI 205 but could not be used safely for that of the Eurocode 2. For pre-compressed concrete slab in the steel composite section, the loss rate of prestressed force with low strength reinforcement was much larger than that with high strength tendon. The loss rate of concrete pre-compression increased, while that of pre-tension decreased due to the restraint of the steel girder.

• Journal of Korean Academy of Nursing
• /
• v.23 no.3
• /
• pp.339-355
• /
• 1993

The purpose of this correlational study was to offer strategies for nursing intervention to improve compliance with prenatal care. This study was designed to investigate degree of tardiness, correlation between hardiness and compliance with prenatal care. In research, the characteristic of hardiness has 1 teen demonstrated in resolving stressful situaltions and in adapting to overcome physical and psycho-logical tension. pregnancy is normal crisis process. Therefore, it is necessary to investigate degree of hardiness in normal pregnant woman and I think that concept of hardiness is able to become a new, important concept for prenatal care imtervention. The subjects were 388 normal pregnant woman over five months, who were selected from five university hospitals and two health centers in Taegu. Data were obtained using a convenience sample technique. Data collection was done from March 6 to June 18, 1992. The instruments used for this study were the Health Related Hardiness Scale developed by Pollock(1984) and compliance with a prenatal care scale developed by the author on the basis of results of a literature review. Data were analyzed using the SAS program for t - test, ANOVA, Scheffe test, Pearson correlation and stepwise multiple regression. The results are as follows : 1. The scores on the hardiness scale ranged from 35 to 210 with mean of 88.89. 2. The scores on the compliance with prenatal care scale ranged from 28 to 140 with a mean of 111.49. 3. There were significant differences between hardiness and obstetrical characteristic factors, duration of pregnancy, frequency of pregnancy, frequency of abortion(P .05). 4. There were significant differences between compliance with prenatal care and general and obstetircal characteristic factors, education and frequency of pregnancy(P .05). 5. Correlations between hardiness and compliance with prenatal care were all negative and significant(r=-.2276~ -.2930, P .000). Challenge of hardiness components was the low est (r= -.2814). 6. Significant differences between hardiness and compliance with prenatal care by group were as follows : Group 1 was the high est, whereas Group 8 was the lowest(F=5.47, P .0000). 7. Factors influencing compliance with prenatal care were : 1) Challenge was the main variable and accounted for 7.92% of the total variance. 2) Education and frequency of pregnancy accounted for an additional 2.74% of the total variance. From the above findings, this study suggests the following : 1) Considering the lack of empirical support, the theroy of hardiness needs to be evaluated. 2) A valid, reliable and culturally appropriate instrument needs to be developed for Health Related Hardiness Scale. 3) There is a need for further study of hardiness in a broad variety of populations. 4) There is a need for comparative study correlation between hardiness and compliance with prenatal care in woman with normal and abnormal pregnancies

• Journal of the Korea Concrete Institute
• /
• v.20 no.2
• /
• pp.131-138
• /
• 2008

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio. Internal humidity change and shrinkage strain were about 10%, 4% and $320\times10^{-6}$, $120\times10^{-6}$ respectively on concrete with water binder ratio 0.3, 0.4 and from the results, humidity change and shrinkage represented the strong linear relation regardless of mixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20 nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• The Korean Journal of Physiology
• /
• v.20 no.1
• /
• pp.31-41
• /
• 1986

The sufficient myoplasmic $Ca^{++}$ to react with the contractile proteins is necessary to induce contraction of a cardiac muscle. These $Ca^{++}$ for the production of muscle contraction are supplied from the three recognized $Ca^{++}$ sources; internal $Ca^{++}$ release via the sarcoplasmic reticulum(SR), $Ca^{++}$ influx through a gated Ca-channel in the membrane as a Isi, and $Ca^{++}$ transport by the mechanism of Na/ca exchange. However, it is still controversial which $Ca^{++}$ sources act as a main contributor for myoplasmic $Ca^{++}$, Therefore, this study was undertaken in order to examine the $Ca^{++}$ sources for the contraction of frog ventricle. There is evidence that the SR is sparse in frog ventricular fibers, and that T-tubules are absent. Isolated ventricular strips of frog, Rana nigromaculata, were used in this experiment. Isometric tension was recorded by force transducer, and membrane potentials of ventricular muscles were measured through the intracellular glass microelectrodes, which were filled with 3M KCI and had resistance of $30{\pm}50M{\Omega}$. All experiments were performed at room temperature in a tris·buffered Ringer solution which was aerated with 100% $O_2$. Isotonic high K, low Na solution was used to induce K-contracture, K-contracture appeared at the concentration of 20 to 30mM-KCI and was potentiated in parallel with the increase in KCI concentration. The contracture had two components: an initial rapid phasic and a subsequent slow tonic contractile responses. Membrane Potentials measured at normal Ringer solution(2.5mM KCI) was -90 to -100 mV, and decreased linearly as the KCI concentration increased; -55mV at 20mM.KCI, -45mV at 30 mM.KCI, -30 mY at 50 mM.KCI, and -12 mV at 100 mM.KCI. K-contracture was evoked firstly at the membrane potential of -45 mV. The contracture was potentiated by the increase of bathing extracellular $Ca^{++}$ concentration. However, in the absence of $Ca^{++}$ the contracture was almost not induced by 50 mM.KCI solution. Caffeine(20mM) in normal Ringer solution, which is known to release $Ca^{++}$ from SR without substantial effects on the $Ca^{++}$ fluxes across the surface membrane, did not affect membrane potential and also not initiate contracture, but the caffeine in 20 mM-KCI Ringer solution produced a contracture. Above results suggest that the main $Ca^{++}$ source for the K·contracture of frog ventricle is $Ca^{++}$ influx through the voltage-dependent Ca-channel, and that in the K-contracture at the concentration of 100 mM-KCI, the mechanism of Na/ca exchange also partly contributs, in addition to the $Ca^{++}$ influx.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.24 no.4
• /
• pp.422-429
• /
• 2018

To make students recognize the danger of fire smoke that may occur in ships and to improve the response capability, spaces for safety educ ation were built inside the training ship, and scenarios were developed. This study is an analysis of the movement characteristics of the students acquire d under each scenario. Followings are the summary of the analysis results. In the non-smoke environments, there was no difference in the velocity of escape movement between the case of without block on the familiar route and the case of with unexpected block. However, when the indoor was filled with smoke, the visibility became very low because of the smoke density and the average velocity was 62.5 % slower than the case where it was not. Regardless of the scenarios, the average equivalent velocity on the complex path was faster than the simple straight path, and the standard deviation was smaller. Under the smoke-fullfilled environment, although the relative velocity probability distributions of the complex passage and the entire passag e are very similar, the inter-individual fluctuation of the relative velocity ratio of the complex passage to that of the entire passage was very large. On the other hand, equivalent velocity could be expressed by the logarithmic function of the visibility. Also, as the tension of the students increased, the equivalent velocities were accelerated on all scenarios.

• Korean Chemical Engineering Research
• /
• v.57 no.5
• /
• pp.620-627
• /
• 2019

In this study, ignition delay characteristics of various bio aviation fuels (Bio-ADD, Bio-6308, Bio-7720) produced by HEFA process using different raw materials were compared and analyzed. In order to confirm the feasibility of applying bio aviation fuel to actual system, ignition delay characteristics of petroleum-based aviation fuel (Jet A-1) and blended aviation fuel (50:50, v:v) also analyzed. Ignition delay time of each aviation fuel was measured by using CRU, surface tension measurement and GC/MS and GC/FID analysis were performed to interpret the results. As a result, ignition delay time of Jet A-1 was the longest at all temperature because it contains aromatic compounds about 22.8%. The aromatic compounds can produce benzyl radical which is thermally stable and has low reactivity with oxygen during decomposition process. In the case of bio aviation fuels, ignition delay times were measured similarly because the ratio of n-paraffin/iso-paraffin constituting each aviation fuel is similar (about 0.12) and the composition ratio of cycloparaffin also has no difference. In addition, ignition delay times of blended aviation fuels (50:50, v:v) were measured close to the mean value those of each fuel so it was confirmed that it can be applied without any changing or improving of existing system.

• Geophysics and Geophysical Exploration
• /
• v.22 no.1
• /
• pp.21-28
• /
• 2019

We perform a 3D tomographic inversion using surface wave dispersion curves to obtain S-velocity model and radial anisotropy beneath Saudi Arabia. The Arabian Peninsula is geologically and topographically divided into a shield and a platform. We used event data with magnitudes larger than 5.5 and epicentral distances shorter than $40^{\circ}$ during 2008 ~ 2014 from the Saudi Geological Survey. We obtained dispersion curves by using the multiple filtering technique after preprocessing the event data. We constructed SH- and SV-velocity models and consequently radial anisotropy model at 10 ~ 60 km depths by inverting Love and Rayleigh group velocity dispersion curves with period ranges of 5 ~ 140 s, respectively. We observe high-velocity anomalies beneath the Arabian shield at 10 ~ 30 km depths and low-velocity anomalies beneath the Arabian platform at 10 km depth in the SV-velocity model. This discrepancy may be caused by the difference between the Arabian shield and the Arabian platform, that is, the Arabian shield was formed in Proterozoic thereby old and cold, while the Arabian platform is covered by predominant Paleozoic, Mesozoic, and Cenozoic sedimentary layers. Also we obtained radial anisotropy by estimating the differences between SH- and SV-velocity models. Positive anisotropy is observed, which may be generated by lateral tension due to the slab pull of subducting slabs along the Zagros belt.