• 제목/요약/키워드: low temperature reduction

검색결과 1,041건 처리시간 0.023초

Fabrication of YSZ/GDC Bilayer Electrolyte Thin Film for Solid Oxide Fuel Cells

  • Yang, Seon-Ho;Choi, Hyung-Wook
    • Transactions on Electrical and Electronic Materials
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    • 제15권4호
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    • pp.189-192
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    • 2014
  • Yttria-stablized zirconia (YSZ) is the most commonly used electrolyte material, but the reduction in working temperature leads to insufficient ionic conductivity. Ceria based electrolytes (GDC) are more attractive in terms of conductivity at low temperature, but these materials are well known to be reducible at very low oxygen partial pressure. The reduction of electrolyte resistivity is necessary to overcome cell performance losses. So, thin YSZ/GDC bilayer technology seems suitable for decreasing the electrolyte resistance at lower operating temperatures. Bilayer electrolytes composed of a galdolinium-doped $CeO_2$ ($Ce_{0.9}Gd_{0.1}O_{1.95}$, GDC) layer and yttria-stabilized $ZrO_2$ (YSZ) layer with various thicknesses were deposited by RF sputtering and E-beam evaporation. The bilayer electrolytes were deposited between porous Ni-GDC anode and LSM cathode for anode-supported single cells. Thin film structure and surface morphology were investigated by X-ray diffraction (XRD), using $CuK{\alpha}$-radiation in the range of 2ce morphol$^{\circ}C$. The XRD patterns exhibit a well-formed cubic fluorite structure, and sharp lines of XRD peaks can be observed, which indicate a single solid solution. The morphology and size of the prepared particles were investigated by field-emission scanning electron microscopy (FE-SEM). The performance of the cells was evaluated over $500{\sim}800^{\circ}C$, using humidified hydrogen as fuel, and air as oxidant.

Development of Minimally Invasive Mid-infrared Lipolysis Laser System for Effective Fat Reduction

  • Lee, Ji-Young;Ryu, Han Young;Seo, Young-Seok
    • Medical Lasers
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    • 제10권2호
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    • pp.82-89
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    • 2021
  • Background and Objectives Due to changes in diet and lifestyle, the number of obese people worldwide is steadily increasing. Obesity has an adverse effect on a healthy life, so it needs treatment and improvement. Research related to this is continuously being conducted. Materials and Methods The laser system to compact designed using 808 nm laser diode and Neodymium Yttrium orthovanadate generates a 1064 nm wavelength, the periodically polarized nonlinear crystal pumping laser beam. The pulsed 1064 nm wavelength beam passing through the AO Q-switch is used as the pumping light of the nonlinear optical crystal and is irradiated to the periodic polarized nonlinear optical crystal with a quasi-phase matching period. Nonlinear optical crystals use an oven to control the temperature to generate the desired 1980 nm and 2300 nm wavelengths. Results The 1980 nm and 2300 nm wavelengths generated by temperature control of nonlinear optical crystals are effective for lipolysis. A fiber catheter was used so that the laser could be directly irradiated to the fat cells. In particular, the new wavelength (1980 nm, 2300 nm) can increase the fat reduction effect with low energy (1.3 W). When a laser with a combination wavelength of 1980 nm and 2300 nm was used, an average lipolysis effect of 20% was obtained. Conclusion A mid-infrared lipolysis laser system with excellent absorption of fat and water has been developed. We conducted a princlinical study to confirm the efficacy and safety of the lipolysis laser system, and obtained good results for lipolysis with low energy.

강가공에 의한 Nb함유 저탄소강의 오스테나이트 재결정과 페라이트 미세화 (Austenite Recrystallization and Ferrite Refinement of a Nb Bearing Low Carbon Steel by Heavy Hot Deformation)

  • 이상우
    • 열처리공학회지
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    • 제18권1호
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    • pp.3-11
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    • 2005
  • Using various thermo-mechanical schedules characterized by varying reheating temperature, deformation temperature and strain, the austenite recrystallization and ferrite refinement of a Nb bearing low carbon steel(0.15C-0.25Si-1.11Mn-0.04Nb) were investigated. For single pass heavy deformations at $800^{\circ}C$, the 40% deformed austenite was not recrystallized while the 80% deformed one was fully recrystallized. Ferrite grains formed in the 80% deformed specimen was not very small compared with those in the 40% deformed specimen, which implied the recrystallized austenite was not more beneficial to ferrite refinement than the non-recrystallized one. In case of deformation in low temperature austenite region, a multi-pass deformation made finer ferrites than a single-pass deformation, as the total reduction was the same, due to more ferrite nucleation sites in the non-recrystallization of austenite for multi-pass deformation. When specimen was deformed at $775^{\circ}C$ that was $10^{\circ}C$ higher than $Ar_3$, the ferrite of about $1{\mu}m$ was formed through deformation induced ferrite transformation(DIFT), and the amount of ferrite was increased with increasing reduction. Dislocation density was very high and no carbides were observed in DIFT ferrites, presumably due to supersaturated carbon solution. By deformation in two phase(50% austenite+50% ferrite) region the very refined ferrite grains of less than $1{\mu}m$ were formed certainly by recovery and recrystallization of deformed ferrites and, a large portion of ferrites were divided by subgrain boundaries with misorientation angles smaller than 10 degrees.

냉각 시스템 제어에 따른 디젤 엔진의 배기가스 저감에 관한 연구 (A study on the reduction of emission by controlled cooling system in a diesel engine)

  • 최경욱;조원준;이기형
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.3294-3299
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    • 2007
  • These days the exhaustion of petroleum resources and environmental problems are getting serious. Many researchers are focused on low emission and high performance vehicles. Therefore, we should concern about emission regulation when we design a new car. In this study, we investigated the characteristics of the traditional mechanical engine cooling systems which control the engine temperature using engine speed and wax type thermostat. This experiment used three components which are Radiator fan, water pump and water valve controlled by an electronic system based on the engine status (load, speed). We elucidated how different between traditional mechanical cooling system and electronic cooling system which control coolant temperature and coolant flow rate in a DI diesel engine in this paper. The results revealed a fuel saving and an emission (CO, HC) reduction on NEDC cycle.

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Electrochemical Approach in Plasma Display Panel Glass Melts doped with Sulfate and Sulfide II. Square Wave Voltammetry

  • Kim, Ki-Dong
    • 한국세라믹학회지
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    • 제45권7호
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    • pp.375-379
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    • 2008
  • Redox behavior was observed in alkali alkaline earth silicate PDP (Plasma Display Panel) glass melts doped with sulfate and sulfide by square wave voltammetry (SWV). According to voltammograms produced at a temperature range of 1100 to $1400^{\circ}C$ and frequency range of 5 to 1000 Hz, both melts showed the same behavior in which there is one reduction peak at low frequency but another peak at an increase of frequency. Based on the frequency dependence of the peak current, self diffusivity of $S^{4+}$ was determined. Based on the temperature dependence of the peak potential, standard enthalpy (${\Delta}H^0$) and standard entropy (${\Delta}S^0$) for the reduction of $S^{4+}$ to $S^0$ were calculated.

Electrochemical extraction of uranium on the gallium and cadmium reactive electrodes in molten salt

  • Valeri Smolenski;Alena Novoselova
    • Nuclear Engineering and Technology
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    • 제56권1호
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    • pp.42-47
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    • 2024
  • The electrochemical extraction of uranium in ternary low melting LiCl-KCl-CsCl eutectic on inert and reactive electrodes via different electrochemical techniques was investigated. It was established that the electrochemical reduction process of U(III) ions on the inert W electrode was irreversible and proceeded in one stage. On reactive liquid Ga and liquid Cd electrodes the reduction of uranium ions took place with the considerable depolarization with the formation of UGa2, UGa3 and UCd11 intermetallic compounds. Thermodynamic characteristics of uranium compounds and alloys were calculated. The conditions for the extraction of uranium from the electrolyte in the form of alloys on both liquid reactive electrodes via potentiostatic electrolysis were found.

승용디젤엔진의 운전 조건 및 분사 조건 변경에 따른 Urea-SCR 시스템의 NOx 전환효율에 관한 연구 (Investigation on the DeNOx Efficiency in Urea-SCR System at Various Operating Conditions and Injection Characteristics for a Passenger Diesel Engine)

  • 홍길화;황인구;명차리;박심수
    • 대한기계학회논문집B
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    • 제33권12호
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    • pp.952-960
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    • 2009
  • Selective Catalytic Reduction (SCR) system is a high-effective NOx reduction technology in diesel engines. As the emission standard of diesel engines is more stringent, vehicle manufactures makes efforts on emission technologies. This paper discusses the performance of Urea-SCR system according to the engine operating conditions in a passenger diesel engine. Engine test results in this paper show that it is important to consider the catalyst temperature and space velocity to obtain high NOx conversion efficiency. In condition of high catalyst temperature, over 90% NOx conversion efficiency is indicated. However, when catalyst temperature is low, NOx conversion efficiency was decreased. Also, it was shown that space velocity mainly effects on the DeNOx performance under 220 degree celsius of SCR catalyst temperature. As the urea injection pressure was decreased, NOx conversion efficiency was declined. It is concerned about urea droplet atomization. This work shown in this paper can lead to improved overall NOx conversion efficiency.

삼원 촉매의 열적 내구 성능 평가 (A Estimation of Thermal Fatigue Performance in Three-way Catalyst)

  • 이성룡;조석수
    • 한국산학기술학회논문지
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    • 제14권1호
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    • pp.13-19
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    • 2013
  • 국내 승용차용 삼원촉매의 경우 열적 내구성을 만족시키지 못하고 조기 파손되는 사례가 증가하고 있다. 이것은 차량의 배기가스 정화장치의 신뢰성에 치명적 손상을 유발시키므로 삼원촉매의 내구성 평가 모델을 파악할 필요가 있다. 따라서 본 연구에서는 세라믹 모노리스 담체에서 발생되는 열응력을 구한 뒤 강도저하계수모델과 파손확률을 기초로 삼원촉매의 열적 내구성을 평가하였다.

이중버블시트를 이용한 단열양생공법의 한중콘크리트 현장적용 (Field Application of Insulation Curing Method with Double Bubble Sheets Subject to Cold Weather)

  • 홍석민;이일선;백대현;김종;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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    • pp.25-28
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    • 2009
  • This study investigated the results of insulation heat curing method using double layer bubble sheet in slab concrete in cold weather environment. First of all, when double bubble sheets are applied, it was shown that slab concrete was protected from early freezing by remaining between 5 and $l0^{\circ}C$ even in case outside temperature drops $-11^{\circ}C$ below zero until the 4nd day from piling. The insulation heat preservation curing method using the double bubble sheet applied in this field prevented early freezing owing to stable curing temperature management, deterring concrete strength development delay at low temperature, and obtained the needed strength. Also, it was proven that the method is highly effective and economic for cold weather concrete quality maintenance through curing cost reduction like construction period shortening and labor cost reduction, etc by reducing the process of temporary equipment installation and disassembling.

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공정 온도에 따른 사면체 비정질 카본 (ta-C) 코팅의 트라이볼로지적 특성연구 (Effects of Process Temperature on the Tribological Properties of Tetrahedral Amorphous Carbon (ta-C) Coating)

  • 강용진;김도현;류호준;김종국;장영준
    • Tribology and Lubricants
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    • 제35권6호
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    • pp.362-368
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    • 2019
  • In this study, mechanical and tribological properties were investigated by varying the process temperature (50, 100, 125 and 150℃) to reduce internal stress. The internal stress reduction by thermal dissociation ta-C coating film with increasing temperature is confirmed through the curvature radius of the ta-C coating according to the temperature of the SUS plate. As the coating temperature increased, the mechanical properties (hardness, modulus, toughness) deteriorated, which is in agreement with the Raman analysis results. As the temperature increased, the sp2 phase ratio increased owing to the dissociation of the sp3 phase. The friction and wear properties are related to the process temperature during ta-C coating. Low friction and wear properties are observed in high hardness samples manufactured at 50℃, and wear resistance properties decreased with increasing temperature. The contact area is expected to increase owing to the decrease of hardness(72 GPa to 39 GPa) and fracture toughness with increasing temperature which accelerated wear because of the debris generated. It was confirmed that at process temperature of over than 100℃, the bond structure of the carbon film changed, and the effect of excellent internal stress was reduced. However, the wear resistance simultaneously decreased owing to the reduction in fracture toughness. Therefore, in order to increase industrial utilization, optimum temperature conditions that reduce internal stress and retain mechanical properties.