• 제목/요약/키워드: low temperature reduction

검색결과 1,037건 처리시간 0.031초

저온 플라즈마 및 암모니아 선택적 환원공정을 활용한 저온 탈질공정의 특성(I) (Characteristics of Low Temperature De-NOx Process with Non-thermal Plasma and NH3 Selective Catalytic Reduction (I))

  • 이재옥;송영훈
    • 공업화학
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    • 제17권4호
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    • pp.409-413
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    • 2006
  • $150{\sim}200^{\circ}C$의 저온조건에 적용하기 위한 탈질공정으로서 저온 플라즈마 및 암모니아 SCR 공정을 복합시킨 탈질공정에 대한 실험적인 연구가 수행되었다. 실험결과 저온조건에서 일반적인 SCR 반응에 비해 매우 빠른 반응속도를 갖는 fast SCR 반응의 가능성을 확인할 수 있었으며, 효과적인 fast SCR 반응을 위해서는 SCR 반응기에 투입되는 $NO_{2}/NO_{x}$의 비가 0.3~0.5 범위에 있음을 알 수 있었다. 본 연구에서는 저온운전에 따른 암모늄염의 발생문제, 배기가스에 포함되어 있는 탄화수소가 공정에 미치는 영향, 유사한 공정과의 운전전력 비교 등 해당기술을 활용하기 위해 기본적으로 필요한 자료를 제공하고 있다.

GWAS analysis and selection of useful resources for direct-seeding related mesocotyl elongation in rice

  • Park, So-Yeon;Lee, Ah-Rim;Wang, Heng;Son, Tae-Soo;Ryu, SuNoh;Kwon, Soon-Wook
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2017년도 9th Asian Crop Science Association conference
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    • pp.151-151
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    • 2017
  • In Asia, rice production has some difficulties with reduction of farm household population and increase of elderly population. As a result, it has resulted in inefficiency and we needs to reduce labor force and improve labor productivity. Direct-seeding in rice could reduce labor and production costs, the area of direct seeding is increasing in japonica rice production in Asia. In direct seedling cultivation competition against weeds is one of most important concern. So, low temperature germinability and mesocotyl elongation should be considered. In this study, we evaluated the mesocotyl length and low temperature germination conducted association analysis using 137 korea core collections. An average length of mesocotyl among 137 core collections was skewed range from 0mm to 43mm. we searched candidate gene around target SNP. Such related traits, genome-wide association study (GWAS) analysis was carried out using GAPIT. Also, average mesocotyl length of 394 korea landrace cultivars was measured ranging from minimum 0 mm to maximum 34mm. 30 out of 394 Korea landrace cultivar conducted re-sequencing, and haplotype analysis of candidate gene. we searched these related resources, which including germination of low temperature and mesocotyl elongation. This could be used for the development of direct-seeding cultivars. The valiated accession of core collection and landrace cultivars will be used development of direct-seedling cultivar in the future.

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마이크로 금형 부품을 위한 마이크로 절삭가공 기술 (Micro cutting process technology for micro molds parts)

  • 하석재;박정연;김건희;윤길상
    • Design & Manufacturing
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    • 제13권1호
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    • pp.5-12
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    • 2019
  • In this paper, we studied the micro tool deflection, micro cutting with low temperature, and deformation of micro ribs caused by cutting forces. First, we performed an integrated machining error compensation method based on captured images of tool deflection shapes in micro cutting process. In micro cutting process, micro tool deflection generates very serious problems in contrast to macro tool deflection. To get the real images of micro tool deflection, it is possible to estimate tool deflection in cutting conditions modeled and to compensate for machining errors using an iterative algorithm correcting tool path. Second, in macro cutting fields, the cryogenic cutting process has been applied to cut the refractory metal but, the serious problem may be generated in micro cutting fields by the cryogenic environment. However, if the proper low temperature is applied to micro cutting area, the cooling effect of cutting heat is expected. Such effect can make the reduction of tool wear and burr formation. For verifying this passibility, the micro cutting experiment at low temperature was performed and SEM images were analyzed. Third, the micro pattern was deformed by the cutting forces and the shape error occurred in the sidewall multi-step cutting process were minimized. As the results, the relationship between the cutting conditions and the deformation of micro-structure during micro cutting process was investigated.

Ammonium Chloride Solution Leaching of Crude Zinc Oxide Recovered from Reduction of EAF′s Dust

  • Youn, Ki-Byoung
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.365-369
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    • 2001
  • EAF's dust has been treated mainly by pyrometallurgical reduction process in rotary kiln furnace to recover valuable metal elements such as Zn and to avoid the disposal of hazardous materials to waste. Recently, hydrometallurgical eletrowinning of zinc from a zinc-amino chloride solution obtained by the leaching of EAF's dust was developed to recover high grade zinc metal from EAF’s dust. But there are some disadvantages in each process such as difficulty of operation condition control and sticking problem in kiln process and low extractability and recovery of zinc owing to insoluble zinc-ferrite in electrowinning process. We propose a new combined process of pyrometallurgical one and hydrometallurgical one to treat EAF's dust efficiently and economically. In this study, ammonium chloride solution leaching of crude zinc oxide recovered from reduction of EAF's dust was carried out to find out the efficiency of zinc extraction from it and the possibility for performance of eletrowinning in the proposed process. Effects of various leaching variables ruck as leaching temperature, concentration of leaching solution and leaching time were investigated. And the leaching results of the crude zinc oxide were compared with those of EAF's dust. The extraction percents of zinc in ammonium chloride solution leaching of the crude zinc oxide recovered from reduction of EAF's dust were above 80% after 60 minutes of leaching under the leaching condition of 4M NH$_4$CI concentration and above leaching temperature of 7$0^{\circ}C$. And the concentrations of zinc in the leached solution were obtained above 50g/$\ell$. The activation energy calculated for zinc extraction in NH$_4$CI leaching was 58.1 KJ/㏖ for EAF's dust and 15.8 KJ/㏖ for the crude zinc oxide recovered from reduction of EAF's dust.

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1-propanol 첨가에 따른 이산화타이타늄(TiO2) 광 촉매의 비표면적 향상 및 이산화탄소 환원 효율 향상 (Improvement of Carbon Dioxide Reduction Efficiency of Titanium Dioxide Photocatalyst Using 1-propanol)

  • 하윤태;권진범;안희경;정대웅
    • 센서학회지
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    • 제31권5호
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    • pp.343-347
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    • 2022
  • Recently, the problem of global warming caused by greenhouse gases is getting serious due to the development of industry and the increase in transportation means. Accordingly, the need for a technology to reduce carbon dioxide, which accounts for most of the greenhouse gas, is increasing. Among them, a catalyst for converting carbon dioxide into fuel is being actively studied. Catalysts for reducing carbon dioxide are classified into thermal catalysts and photocatalysts. In particular, the photocatalyst has the advantage that carbon dioxide can be reduced only by irradiating ultraviolet rays at room temperature without high temperature or additional gas. TiO2 is widely used as a photocatalyst because it is non-toxic and has high stability, but has a disadvantage of low carbon dioxide reduction efficiency. To increase the reduction efficiency, 1-propanol was used in the synthesis process. This prevents agglomeration of the catalyst and increases the specific surface area and pores of TiO2, thereby increasing the surface area in contact with carbon dioxide. As a result of measuring the CO2 reduction efficiency, it was confirmed that the efficiency of TiO2 with 1-propanol and TiO2 without 1-propanol was 19% and 12.3%, respectively, and the former showed a 1.5 times improved efficiency.

A Study on the Recovery of Zn from Electric Arc Furnace Dust by Carbon Reduction

  • Joo, Sung-Min;Kim, Hyung-Seok;Ahn, Ji-Whan;Kim, Hwan;Lee, Kyung-Hoon;Sung, Ghee-Woong;Kim, Jang-Su;Lee, Park-Seok
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.398-403
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    • 2001
  • There is a potential usability of electric arc furnace(EAF) dust produced during the iron manufacturing process as a recycled resource, because valuable materials such as Zn, Pb and Fe are contained in it. In this study, metallic Zn was recycled from the fine electric arc furnace dust by a solid state reduction method using carbon at relatively low temperature. It was possible to recover metallic zinc by using of high vapour pressure of zinc with this reduction method. The feasibility of recycled zinc for cold bonded pellet(CBP) was investigated. The main composition of EAF dust were franklinite(ZnFe$_2$O$_4$), magnetite(Fe$_3$O$_4$) and zincite(ZnO), and Pb and Cl were completely removed by a heat treatment in oxidation environment. The reduction ratio increased as the solid carbon content increased, and it increased with decreasing of dust particle size and increasing of compaction pressure due to a increase of contact area.

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Thermal catalytic de-NOX 공정에서 첨가제가 촉매의 활성에 미치는 영향에 관한 연구 (Effect of Additives on Catalytic Activity in Thermal Catalytic De-NOx Process)

  • 이진구;김태원;최재순;김정호;이재수;장경욱;박해경
    • 한국대기환경학회지
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    • 제15권3호
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    • pp.249-255
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    • 1999
  • We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

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Buckling and vibration behavior of a non-uniformly heated isotropic cylindrical panel

  • Bhagata, Vinod S.;Pitchaimani, Jeyaraj;Murigendrappa, S.M.
    • Structural Engineering and Mechanics
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    • 제57권3호
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    • pp.543-567
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    • 2016
  • This study attempts to address the buckling and free vibration characteristics of an isotropic cylindrical panel subjected to non-uniform temperature rise using numerical approach. Finite element analysis has been used in the present study. The approach involves three parts, in the first part non-uniform temperature field is obtained using heat transfer analysis, in the second part, the stress field is computed under the thermal load using static condition and, the last part, the buckling and pre-stressed modal analysis are carried out to compute critical buckling temperature as well as natural frequencies and associated mode shapes. In the present study, the effect of non-uniform temperature field, heat sink temperatures and in-plane boundary constraints are considered. The relation between buckling temperature under uniform and non-uniform temperature fields has been established. Results revealed that decrease (Case (ii)) type temperature variation field influences the fundamental buckling mode shape significantly. Further, it is observed that natural frequencies under free vibration state, decreases as temperature increases. However, the reduction is significantly higher for the lowest natural frequency. It is also found that, with an increase in temperature, nodal and anti-nodal positions of free vibration mode shapes is shifting towards the location where the intensity of the heat source is high and structural stiffness is low.

도로변 가로녹지 유형이 기상에 미치는 영향 (A Study on the Temperature Reduction Effect of Street Green Area)

  • 김정호;최원준;윤용한
    • 한국환경과학회지
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    • 제26권12호
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    • pp.1363-1374
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    • 2017
  • Global climate change caused by industrialization has caused abnormal weather conditions such as urban temperatures and tropical nights, urban heat waves, heat waves, and heavy rains. Therefore, the study tried to analyze climate conditions and weather conditions in the streets and analyze climate factors and meteorological factors that lead to inconvenience to citizens. In the case of trees, the overall temperature, surface temperature, solar irradiance, and net radiation were measured low, and the temperature was lower in the Pedestrian road than in roads. The dry bulb temperature, the black bulb temperature, and the wet bulb temperature for the thermal evaluation showed the same tendency. In the case of thermal evaluation, there was a similar tendency to temperature in WBGT, MRT, and UTCI, and varied differences between types. Although the correlation between the meteorological environment and the thermal environment showed a statistically significant significance, the difference between the measured items was not significant. The study found that the trees were generally pleasant to weather and thermal climate in the form of trees, and the differences were mostly documented.

저주파수 배기소음 저감을 위한 배기계 배치의 최적화 (Optimal layout of exhaust systems for the reduction of low-frequency noise)

  • 장승호;이정권;채성수;김정태
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2001년도 춘계학술대회논문집
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    • pp.623-627
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    • 2001
  • Suppression of very low-frequency noise from an automobile exhaust system is difficult due mainly to its large wave length. Therefore, the configuration of total exhaust system, i,e., piping and muffler layout, is important at low frequencies. In this paper, an optimal layout technique of exhaust systems has been developed for reducing low-frequency exhaust noise. For this purpose, system insertion loss and virtual attenuation coefficient have been defined by considering the effects of mean flow and temperature gradient in the pipe. The applicability of present method is investigated with an actual automobile exhaust system and an optimized layout of pipes and mufflers is suggested.

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